• BS EN 62321-3-2:2014

    Current The latest, up-to-date edition.

    Determination of certain substances in electrotechnical products Screening. Total bromine in polymers and electronics by Combustion. Ion Chromatography

    Available format(s):  Hardcopy, PDF

    Language(s):  English

    Published date:  31-05-2014

    Publisher:  British Standards Institution

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    Table of Contents - (Show below) - (Hide below)

    INTRODUCTION
    1 Scope
    2 Normative references
    3 Terms, definitions and abbreviations
    4 Principle
    5 Reagents and materials
    6 Apparatus
    7 Sampling
    8 Procedure
    9 Calculation
    10 Precision
    11 Quality assurance and control
    12 Test report
    Annex A (informative) - Oxygen bomb
            combustion-ion chromatography
    Annex B (informative) - Oxygen flask
            combustion-ion chromatography
    Annex C (informative) - Example of a
            combustion device and IC system
    Annex D (informative) - Results of international
            interlaboratory study #4A (IIS 4A)
    Annex E (informative) - Additional results of
            TG 3-2 test
    Annex F (informative) - Additional validation data
    Annex G (informative) - Additional IC data
    Bibliography
    Annex ZA (normative) - Normative references to international
             Publications with their corresponding
             European publications

    Abstract - (Show below) - (Hide below)

    Defines the screening analysis of the total bromine (Br) in homogeneous materials found in polymers and electronics by using the analytical technique of combustion ion chromatography (C-IC).

    Scope - (Show below) - (Hide below)

    Part 3-2 of IEC 62321 specifies the screening analysis of the total bromine (Br) in homogeneous materials found in polymers and electronics by using the analytical technique of combustion ion chromatography (C-IC). This test method has been evaluated for ABS (acrylonitrile butadiene styrene), EMC (epoxy molding compound), and PE (polyethylene) within the concentration ranges as specified in Table 1. The use of this method for other types of materials or concentration ranges outside those specified below has not been evaluated. Table 1 – Tested concentration ranges for bromine by C-IC in various materials Substance/element Bromine Parameter Unit of measure
    mg/kg Medium/material tested ABS EMC PE Concentration or concentration range tested 124 to 890 195 to 976 96 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

    General Product Information - (Show below) - (Hide below)

    Committee GEL/111
    Development Note Supersedes BS EN 62321, which remains current. Supersedes 10/30229134 DC. (05/2014)
    Document Type Standard
    Publisher British Standards Institution
    Status Current
    Supersedes

    Standards Referencing This Book - (Show below) - (Hide below)

    ISO 5725-1:1994 Accuracy (trueness and precision) of measurement methods and results — Part 1: General principles and definitions
    EN 62321-1:2013 Determination of certain substances in electrotechnical products - Part 1: Introduction and overview
    ASTM D 808 : 2016 : REDLINE Standard Test Method for Chlorine in New and Used Petroleum Products (High Pressure Decomposition Device Method)
    IEC 60754-1:2011 Test on gases evolved during combustion of materials from cables - Part 1: Determination of the halogen acid gas content
    EN 14582:2016 Characterization of waste - Halogen and sulfur content - Oxygen combustion in closed systems and determination methods
    EN 14346:2006 CHARACTERIZATION OF WASTE - CALCULATION OF DRY MATTER BY DETERMINATION OF DRY RESIDUE OR WATER CONTENT
    EN 62321-3-1:2014 Determination of certain substances in electrotechnical products - Part 3-1: Screening - Lead, mercury, cadmium, total chromium and total bromine by X-ray fluorescence spectrometry
    ISO 10304-1:2007 Water quality Determination of dissolved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate
    ISO 5667-1:2006 Water quality Sampling Part 1: Guidance on the design of sampling programmes and sampling techniques
    EN 60754-1:2014 Test on gases evolved during combustion of materials from cables - Part 1: Determination of the halogen acid gas content
    IEC 60754-2:2011 Test on gases evolved during combustion of materials from cables - Part 2: Determination of acidity (by pH measurement) and conductivity
    ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
    ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
    ISO 8466-1:1990 Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the linear calibration function
    EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
    EN 15002:2015 Characterization of waste - Preparation of test portions from the laboratory sample
    ISO 6206:1979 Chemical products for industrial use — Sampling — Vocabulary
    EN 62321-2:2014 Determination of certain substances in electrotechnical products - Part 2: Disassembly, disjointment and mechanical sample preparation
    EN ISO 10304-1:2009 Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (ISO 10304-1:2007)
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