• CEN/TS 15410:2006

    Withdrawn A Withdrawn Standard is one, which is removed from sale, and its unique number can no longer be used. The Standard can be withdrawn and not replaced, or it can be withdrawn and replaced by a Standard with a different number.

    Solid recovered fuels - Method for the determination of the content of major elements (Al, Ca, Fe, K, Mg, Na, P, Si, Ti)

    Available format(s): 

    Withdrawn date:  08-03-2023

    Language(s): 

    Published date:  27-09-2006

    Publisher:  Comite Europeen de Normalisation

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    Table of Contents - (Show below) - (Hide below)

    Foreword
    Introduction
    1 Scope
    2 Normative references
    3 Terms and definitions
    4 Safety remarks
    5 Principle
    6 Apparatus
    7 Reagents
    8 Procedure
    9 Digestion procedure
    10 Analysis of the digestion solutions
    11 Expression of results
    12 Quality control
    13 Performance characteristics
    14 Test report
    Annex A (normative) Guidelines - Characteristics of the
                        laboratory sample for chemical analysis
                        of SRF
    Bibliography

    Abstract - (Show below) - (Hide below)

    This Technical Specification specifies three methods of digestion for solid recovered fuels: a)microwave assisted digestion with hydrofluoric, nitric and hydrochloric acid mixture;b)hot water bath digestion of with hydrofluoric, nitric and hydrochloric acid mixture, after ashing of the SRFs sample;c)oven digestion with nitric, perchloric and hydrofluoric acid mixture.Instrumental determination of Si, Al, K, Na, Ca, Mg, Fe, P, and Ti is performed by Inductively Coupled Plasma Spectrometry with optical detection or other suitable spectroscopic techniques such as Flame Atomic Spectroscopy.The effectiveness of the digestion can be verified by qualitative X-ray fluorescence (XRF) analysis on the remaining residue. If necessary an alternative digestion method (among those proposed) needs to be used.XRF can be used for the analysis of Si, Al, K, Na, Ca, Mg, Fe, P, Ti, after ashing (550 °C) of the sample: other elements can be analysed by XRF providing that the concentration levels are above the instrumental detection limits of the XRF instrumentation and after proper preliminary testing.Method a) is recommended for general use, but the amount of the test portion can be very low in case of high concentration of organic matter. Method b) is recommended for SRFs with high organic matter concentration that can be difficult to digest with the other methods. Method c) is recommended for SRFs samples for which the other methods leave a significant insoluble residue.All the listed methods are suitable for the determination of Si, provided that closed containers are used for sample dissolution. XRF is highly recommended for Si, P and Ti analysis.

    General Product Information - (Show below) - (Hide below)

    Committee CEN/TC 343
    Document Type Technical Specification
    Publisher Comite Europeen de Normalisation
    Status Withdrawn
    Superseded By

    Standards Referenced By This Book - (Show below) - (Hide below)

    DD CEN/TS 15407:2006 Solid recovered fuels. Method for the determination of carbon (C), hydrogen (H) and nitrogen (N) content
    PD CEN/TR 15591:2007 Solid recovered fuels. Determination of the biomass content based on the 14C method
    CEN/TS 15407:2006 Solid recovered fuels - Method for the determination of carbon (C), hydrogen (H) and nitrogen (N) content
    CEN/TS 15442:2006 Solid recovered fuels - Methods for sampling
    CEN/TR 15591:2007 Solid recovered fuels - Determination of the biomass content based on the 14C method
    DIN EN 15442:2011-05 Solid recovered fuels - Methods for sampling; German version EN 15442:2011
    UNI CEN/TR 15591 : 2008 SOLID RECOVERED FUELS - DETERMINATION OF THE BIOMASS CONTENT BASED ON THE [14]C METHOD
    I.S. CEN TS 15407:2006 SOLID RECOVERED FUELS - METHOD FOR THE DETERMINATION OF CARBON (C), HYDROGEN (H) AND NITROGEN (N) CONTENT
    DD CEN/TS 15442:2006 Solid recovered fuels. Methods for sampling
    S.R. CEN/TR 15591:2007 SOLID RECOVERED FUELS - DETERMINATION OF THE BIOMASS CONTENT BASED ON THE [14]C METHOD
    I.S. CEN TS 15442:2006 SOLID RECOVERED FUELS - METHODS FOR SAMPLING

    Standards Referencing This Book - (Show below) - (Hide below)

    EN ISO 11885:2009 Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885:2007)
    CEN/TS 15357:2006 Solid recovered fuels - Terminology, definitions and descriptions
    EN ISO 15586 : 2003 WATER QUALITY - DETERMINATION OF TRACE ELEMENTS USING ATOMIC ABSORPTION SPECTROMETRY WITH GRAPHITE FURNACE
    ASTM D 4326 : 2013 : REDLINE Standard Test Method for Major and Minor Elements in Coal and Coke Ash By X-Ray Fluorescence
    ISO 9964-2:1993 Water quality Determination of sodium and potassium Part 2: Determination of potassium by atomic absorption spectrometry
    ISO 9964-3:1993 Water quality Determination of sodium and potassium Part 3: Determination of sodium and potassium by flame emission spectrometry
    ISO 11885:2007 Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES)
    ISO 15586:2003 Water quality Determination of trace elements using atomic absorption spectrometry with graphite furnace
    CEN/TS 15413:2006 Solid recovered fuels - Methods for the preparation of the test sample from the laboratory sample
    ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
    ISO 12020:1997 Water quality — Determination of aluminium — Atomic absorption spectrometric methods
    EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
    EN 13656 : 2002 CHARACTERIZATION OF WASTE - MICROWAVE ASSISTED DIGESTION WITH HYDROFLUORIC (HF), NITRIC (HNO[3]), AND HYDROCHLORIC (HCL) ACID MIXTURE FOR SUBSEQUENT DETERMINATION OF ELEMENTS
    EN ISO 12020 : 2000 WATER QUALITY - DETERMINATION OF ALUMINIUM - ATOMIC ABSORPTION SPECTROMETRIC METHODS (ISO 12020:1997)
    ISO 9964-1:1993 Water quality Determination of sodium and potassium Part 1: Determination of sodium by atomic absorption spectrometry
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