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Standard Specification for Seamless Ferritic and Austenitic Alloy-Steel Boiler, Superheater, and Heat-Exchanger Tubes

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11-11-2014

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ASTM A 213/A213M : 2014

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01-04-2013

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American Society for Testing and Materials

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Committee	A 01
DocumentType	Standard
Pages	14
PublisherName	American Society for Testing and Materials
Status	Superseded
SupersededBy	ASTM A 213/A213M : 2014
Supersedes	ASTM A 213/A213M : 2011 : REV A

1.1This specification² covers seamless ferritic and austenitic steel boiler, superheater, and heat-exchanger tubes, designated Grades T5, TP304, etc. These steels are listed in Tables 1 and 2.

TABLE 1 Chemical Composition Limits, %^A, for Low Alloy Steel

Grade	UNS Designation	Composition, %
		Carbon	Manga- nese	Phospho- rus	Sul- fur	Silicon	Nickel	Chromium	Molybdenum	Vana- dium	Boron	Niobium	Nitrogen	Aluminum	Tungsten	Other Elements
T2	K11547	0.10–0.20	0.30–0.61	0.025	0.025^B	0.10–0.30	...	0.50–0.81	0.44–0.65	...	...	...	...	...	...	...
T5	K41545	0.15	0.30–0.60	0.025	0.025	0.50	...	4.00–6.00	0.45–0.65	...	...	...	...	...	...	...
T5b	K51545	0.15	0.30–0.60	0.025	0.025	1.00–2.00	...	4.00–6.00	0.45–0.65	...	...	...	...	...	...	...
T5c	K41245	0.12	0.30–0.60	0.025	0.025	0.50	...	4.00–6.00	0.45–0.65	...	...	...	...	...	...	Ti 4xC–0.70
T9	K90941	0.15	0.30–0.60	0.025	0.025	0.25–1.00	...	8.00–10.00	0.90–1.10	...	...	...	...	...	...	...
T11	K11597	0.05–0.15	0.30–0.60	0.025	0.025	0.50–1.00	...	1.00–1.50	0.44–0.65	...	...	...	...	...	...	...
T12	K11562	0.05–0.15	0.30–0.61	0.025	0.025^B	0.50	...	0.80–1.25	0.44–0.65	...	...	...	...	...	...	...
T17	K12047	0.15–0.25	0.30–0.61	0.025	0.025	0.15–0.35	...	0.80–1.25	...	0.15	...	...	...	...	...	...
T21	K31545	0.05–0.15	0.30–0.60	0.025	0.025	0.50–1.00	...	2.65–3.35	0.80–1.06	...	...	...	...	...	...	...
T22	K21590	0.05–0.15	0.30–0.60	0.025	0.025	0.50	...	1.90–2.60	0.87–1.13	...	...	...	...	...	...	...
T23	K40712	0.04–0.10	0.10–0.60	0.030	0.010	0.50	0.40	1.90–2.60	0.05–0.30	0.20–0.30	0.0010– 0.006	0.02–0.08	0.015	0.030	1.45–1.75	Ti 0.005–0.060 Ti/N ≥ 3.5^C
T24	K30736	0.05–0.10	0.30–0.70	0.020	0.010	0.15–0.45	...	2.20–2.60	0.90–1.10	0.20–0.30	0.0015– 0.007	...	0.012	0.02	...	Ti 0.06–0.10
T36	K21001	0.10–0.17	0.80–1.20	0.030	0.025	0.25–0.50	1.00–1.30	0.30	0.25–0.50	0.02	...	0.015–0.045	0.02	0.050	...	Cu 0.50–0.80
T91	K90901	0.07–0.14	0.30–0.60	0.020	0.010	0.20–0.50	0.40	8.0–9.5	0.85–1.05	0.18–0.25	...	0.06–0.10	0.030– 0.070	0.02	...	Ti 0.01 Zr 0.01
T92	K92460	0.07–0.13	0.30–0.60	0.020	0.010	0.50	0.40	8.5–9.5	0.30–0.60	0.15–0.25	0.001– 0.006	0.04–0.09	0.030– 0.070	0.02	1.5–2.00	Ti 0.01 Zr 0.01
T122	K91271	0.07–0.14	0.70	0.020	0.010	0.50	0.50	10.0–11.5	0.25–0.60	0.15–0.30	0.0005– 0.005	0.04–0.10	0.040– 0.100	0.02	1.50–2.50	Cu 0.30–1.70 Ti 0.01 Zr 0.01
T911	K91061	0.09–0.13	0.30–0.60	0.020	0.010	0.10–0.50	0.40	8.5–9.5	0.90–1.10	0.18–0.25	0.0003– 0.006	0.06–0.10	0.040– 0.090	0.02	0.90–1.10	Ti 0.01 Zr 0.01

^A Maximum, unless range or minimum is indicated. Where ellipses (...) appear in this table, there is no requirement, and analysis for the element need not be determined or reported.

^B It is permissible to order T2 and T12 with a sulfur content of 0.045 max. See 16.3.

^CAlternatively, in lieu of this ratio minimum, the material shall have a minimum hardness of 275 HV in the hardened condition, defined as after austenitizing and cooling to room temperature but prior to tempering. Hardness testing shall be performed at mid-thickness of the product. Hardness test frequency shall be two samples of product per heat treatment lot and the hardness testing results shall be reported on the material test report.

TABLE 2 Chemical Composition Limits, %^A, for Austenitic and Ferritic Stainless Steel

Grade	UNS Designation	Composition
Grade	UNS Designation	Carbon	Manga- nese	Phospho- rus	Sulfur	Silicon	Chromium	Nickel	Molybdenum	Nitrogen^B	Niobium	Titanium	Other Elements

TP201	S20100	0.15	5.5–7.5	0.060	0.030	1.00	16.0–18.0	3.5–5.5	...	0.25	...	...	...
TP202	S20200	0.15	7.5–10.0	0.060	0.030	1.00	17.0–19.0	4.0–6.0	...	.025	...	...	...
XM-19	S20910	0.06	4.0–6.0	0.045	0.030	1.00	20.5–23.5	11.5–13.5	1.50–3.00	0.20–0.40	0.10–0.30	...	V 0.10–0.30
^C	S21500	0.06–0.15	5.5–7.0	0.045	0.030	0.20–1.00	14.0–16.0	9.0–11.0	0.80–1.20	...	0.75–1.25	...	B 0.003– 0.009, V 0.15–0.40
^C	S25700	0.02	2.00	0.025	0.010	6.5–8.0	8.0–11.5	22.0–25.0	0.50	...	...	...	...
TP304	S30400	0.08	2.00	0.045	0.030	1.00	18.0–20.0	8.0–11.0	...	...	...	...	...
TP304L	S30403	0.035^D	2.00	0.045	0.030	1.00	18.0–20.0	8.0–12.0	...	...	...	...	...
TP304H	S30409	0.04–0.10	2.00	0.045	0.030	1.00	18.0–20.0	8.0–11.0	...	...	...	...	...
^C	S30432	0.07–0.13	1.00	0.040	0.010	0.30	17.0–19.0	7.5–10.5	...	0.05–0.12	0.30–0.60	...	Al 0.003– 0.030, B 0.001– 0.010, Cu 2.5–3.5
^C	S30434	0.07–0.14	2.00	0.040	0.010	1.00	17.5–19.5	9.0–12.0	...	...	0.10–0.40^E	0.10–0.25^E	B 0.001– 0.004 Cu 2.50– 3.50
TP304N	S30451	0.08	2.00	0.045	0.030	1.00	18.0–20.0	8.0–11.0	...	0.10–0.16	...	...	...
TP304LN	S30453	0.035^D	2.00	0.045	0.030	1.00	18.0–20.0	8.0–11.0	...	0.10–0.16	...	...	...
^C	S30615	0.016–0.24	2.00	0.030	0.030	3.2–4.0	17.0–19.5	13.5–16.0	...	...	...	...	Al 0.8–1.5
^C	S30815	0.05–0.10	0.80	0.040	0.030	1.40–2.00	20.0–22.0	10.0–12.0	...	0.14–0.20	...	...	Ce 0.03–0.08
TP309S	S30908	0.08	2.00	0.045	0.030	1.00	22.0–24.0	12.0–15.0	...	...	...	...	...
TP309H	S30909	0.04–0.10	2.00	0.045	0.030	1.00	22.0–24.0	12.0–15.0	...	...	...	...	...
TP309LMoN	S30925	0.025	2.00	0.040	0.030	0.70	23.0–26.0	13.0–16.0	0.5–1.2	0.25–0.40	...	...	...
TP309Cb	S30940	0.08	2.00	0.045	0.030	1.00	22.0–24.0	12.0–16.0	...	...	10xC–1.10	...	...
TP309HCb	S30941	0.04–0.10	2.00	0.045	0.030	1.00	22.0–24.0	12.0–16.0	...	...	10xC-1.10	...	...
...	S30942	0.03–0.10	2.00	0.040	0.030	1.00	21.0–23.0	14.5–16.5		0.10–0.20	0.50–0.80		B=0.001–0.005
^C	S31002	0.02	2.00	0.020	0.015	0.15	24.0–26.0	19.0–22.0	0.10	0.10	...	...	...
TP310S	S31008	0.08	2.00	0.045	0.030	1.00	24.0–26.0	19.0–22.0	...	...	...	...	...
TP310H	S31009	0.04–0.10	2.00	0.045	0.030	1.00	24.0–26.0	19.0–22.0	...	...	...	...	...
TP310MoCbN	S31025	0.10	1.50	0.030	0.030	1.00	19.5–23.0	23.0–26.0	1.0–2.0	0.10–0.25	0.10–0.40	0.20	B 0.002– 0.010
	S31035	0.04–0.10	0.60	0.030	0.015	0.40	21.5–23.5	23.5–26.5	...	0.15–0.30	0.30–0.60	...	W 2.0–4.0 Co 1.0–2.0 Cu 2.0–3.5 B 0.002– 0.008
TP310Cb	S31040	0.08	2.00	0.045	0.030	1.00	24.0–26.0	19.0–22.0	...	...	10xC-1.10	...	...
TP310HCb	S31041	0.04–0.10	2.00	0.045	0.030	1.00	24.0–26.0	19.0–22.0	...	...	10xC-1.10	...	...
TP310HCbN	S31042	0.04–0.10	2.00	0.045	0.030	1.00	24.0–26.0	19.0–22.0	...	0.15–0.35	0.20–0.60	...	...
TP310MoLN	S31050	0.025	2.00	0.020	0.030	0.40	24.0–26.0	21.0–23.0	2.00–3.00	0.10–0.16	...	...	...
^C	S31060	0.05–0.10	1.00	0.040	0.030	0.50	22.0–24.0	10.0–12.5	...	0.18–0.25	...	...	Ce + La 0.025–0.070 B 0.001–0.010
^C	S31254	0.020	1.00	0.030	0.010	0.80	19.5–20.5	17.5–18.5	6.0–6.5	0.18–0.22	...	...	Cu 0.50–1.00
^C	S31272	0.08–0.12	1.50–2.00	0.030	0.015	0.30–0.70	14.0–16.0	14.0–16.0	1.00–1.40	...	...	0.30–0.60	B 0.004– 0.008
^C	S31277	0.020	3.00	0.030	0.010	0.50	20.5–23.0	26.0–28.0	6.5–8.0	0.30–0.40	...	...	Cu 0.50–1.50
TP316	S31600	0.08	2.00	0.045	0.030	1.00	16.0–18.0	10.0–14.0	2.00–3.00	...	...	...	...
TP316L	S31603	0.035^D	2.00	0.045	0.030	1.00	16.0–18.0	10.0–14.0	2.00–3.00	...	...	...	...
TP316H	S31609	0.04–0.10	2.00	0.045	0.030	1.00	16.0–18.0	11.0–14.0	2.00–3.00	...	...	...	...
TP316Ti	S31635	0.08	2.00	0.045	0.030	0.75	16.0–18.0	10.0–14.0	2.00–3.00	0.10	...	5X (C + N)– 0.70	...
TP316N	S31651	0.08	2.00	0.045	0.030	1.00	16.0–18.0	10.0–13.0	2.00–3.00	0.10–0.16	...	...	...
TP316LN	S31653	0.035^D	2.00	0.045	0.030	1.00	16.0–18.0	10.0–13.0	2.00–3.00	0.10–0.16	...	...	...
TP317	S31700	0.08	2.00	0.045	0.030	1.00	18.0–20.0	11.0–15.0	3.0–4.0	...	...	...	...
TP317L	S31703	0.035	2.00	0.045	0.030	1.00	18.0–20.0	11.0–15.0	3.0–4.0	...	...	...	...
TP317LM	S31725	0.03	2.00	0.045	0.030	1.00	18.0–20.0	13.5–17.5	4.0–5.0	0.20	...	...	Cu 0.75
TP317LMN	S31726	0.03	2.00	0.045	0.030	1.00	17.0–20.0	13.5–17.5	4.0–5.0	0.10–0.20	...	...	Cu 0.75
^C	S32050	0.030	1.50	0.035	0.020	1.00	22.0–24.0	20.0–23.0	6.0–6.8	0.21–0.32	...	...	Cu 0.40
TP321	S32100	0.08	2.00	0.045	0.030	1.00	17.0–19.0	9.0–12.0	...	...	...	5(C + N)– 0.70	...
TP321H	S32109	0.04–0.10	2.00	0.045	0.030	1.00	17.0–19.0	9.0–12.0	...	...	...	4(C + N)– 0.70	...
^C	S32615	0.07	2.00	0.045	0.030	4.8–6.0	16.5–19.5	19.0–22.0	0.30–1.50	...	...	...	Cu 1.50– 2.50
^C	S33228	0.04–0.08	1.00	0.020	0.015	0.30	26.0–28.0	31.0–33.0	...	...	0.60–1.00	...	Ce 0.05– 0.10, Al 0.025
^C	S34565	0.030	5.0–7.0	0.030	0.010	1.00	23.0–25.0	16.0–18.0	4.0–5.0	0.40–0.60	0.10	...	...
TP347	S34700	0.08	2.00	0.045	0.030	1.00	17.0–20.0	9.0–13.0	...	...	10xC–1.10	...	...
TP347W	S34705	0.05	2.00	0.040	0.030	1.00	17.0–20.0	8.00–11.0	...	0.10–0.25	0.25–0.50	...	V 0.20–0.50 W 1.50–2.60
TP347H	S34709	0.04–0.10	2.00	0.045	0.030	1.00	17.0–19.0	9.0–13.0	...	...	8xC–1.10	...	...
TP347HFG	S34710	0.06–0.10	2.00	0.045	0.030	1.00	17.0–19.0	9.0–13.0	...	...	8xC–1.10	...	...
TP347LN	S34751	0.005–0.020	2.00	0.045	0.030	1.00	17.0–19.0	9.0–13.0	...	0.06–0.10	0.20–0.50^F	...	...
TP348	S34800	0.08	2.00	0.045	0.030	1.00	17.0–19.0	9.0–13.0	...	...	^G	...	Co 0.20, Ta 0.10
TP348H	S34809	0.04–0.10	2.00	0.045	0.030	1.00	17.0–19.0	9.0–13.0	...	...	^H	...	Co 0.20, Ta 0.10
...	S35045	0.06–0.10	1.50	0.045	0.015	1.00	25.0–29.0	32.0–37.0	...	...	...	0.15–0.60	Al 0.15–0.60 Cu 0.75
XM-15	S38100	0.08	2.00	0.030	0.030	1.50–2.50	17.0–19.0	17.5–18.5	...	...	...	...	...
...	S38815	0.030	2.00	0.040	0.020	5.5–6.5	13.0–15.0	15.0–17.0	0.75–1.50	...	...	...	Cu 0.75–1.50 Al 0.30
Alloy 20	N08020	0.070	2.00	0.045	0.035	1.00	19.0-21.0	32.0-38.0	2.00-3.00	...	^M	...	Cu 3.00-4.00
^C	N08367	0.030	2.00	0.040	0.030	1.00	20.0-22.0	23.5-25.5	6.00-7.00	0.18-0.25	...	...	Cu 0.75
800	N08800	0.10	1.50	0.045	0.015	1.00	19.0–23.0	30.0–35.0	...	...			Cu 0.75 Al 0.15–0.60 Ti 0.15–0.60 Fe^I 39.5 min
800H	N08810	0.05–0.10	1.50	0.045	0.015	1.00	19.0–23.0	30.0–35.0	...	...			Cu 0.75 Al 0.15–0.60 Ti 0.15–0.60 Fe^I 39.5 min
...	N08811	0.06–0.10	1.50	0.045	0.015	1.00	19.0–23.0	30.0–35.0	...	...			Cu 0.75 Al 0.15–0.60^J Ti 0.15–0.60^J Fe^I 39.5 min
	N08904	0.020	2.00	0.040	0.030	1.00	19.0–23.0	23.0–28.0	4.0–5.0	0.10			Cu 1.00–2.00
...	N08925	0.020	1.00	0.045	0.030	0.50	19.0–21.0	24.0–26.0	6.0–7.0	0.10–0.20	...	...	Cu 0.80–1.50
...	N08926	0.020	2.00	0.030	0.010	0.50	19.0–21.0	24.0–26.0	6.0–7.0	0.15–0.25	...	...	Cu 0.50–1.50
TP444	S44400	0.03	1.00	0.040	0.030	1.00	17.5–19.5	^K	1.75–2.50	0.035	...	^L	...

^AMaximum, unless a range or minimum is indicated. Where ellipses (...) appear in this table, there is no minimum and analysis for the element need not be determined or reported.

^BThe method of analysis for Nitrogen shall be a matter of agreement between the purchaser and the producer.

^CFor these alloys, there is no common grade designation. The UNS number uniquely identifies these alloys.

^DFor small diameter or thin walls, or both, where many drawing passes are required, a carbon maximum of 0.040% is necessary in Grades TP304L, TP304LN, TP316L, and TP316LN.

^EGrade S30434 shall have (Ti + ¹/₂Nb) of not less than 2 times and not more than 4 times the carbon content.

^FGrade TP347LN shall have an Nb content of not less than 15 times the carbon content.

^GGrade TP348 shall have an Nb + Ta content of not less than 10 times the carbon content and not more than 1.10%.

^HGrade TP348H shall have an Nb + Ta content of not less than 8 times the carbon content and not more than 1.10%.

^IIron shall be determined arithmetically by difference of 100 minus the sum of the other specified elements.

^J(Al + Ti) 0.85–1.20.

^KGrade TP444 shall have Ni + Cu = 1.00 max.

^LGrade TP444 shall have Ti + Nb = 0.20 + 4(C + N)–0.80.

^MN08020 shall have an Nb + Ta content of not less than 8 times the carbon content and not more than 1.00%.

1.2Grades containing the letter, H, in their designation, have requirements different from those of similar grades not containing the letter, H. These different requirements provide higher creep-rupture strength than normally achievable in similar grades without these different requirements.

1.3The tubing sizes and thicknesses usually furnished to this specification are ¹/₈in. [3.2 mm] in inside diameter to 5 in. [127 mm] in outside diameter and 0.015 to 0.500 in. [0.4 to 12.7 mm], inclusive, in minimum wall thickness or, if specified in the order, average wall thickness. Tubing having other diameters may be furnished, provided such tubes comply with all other requirements of this specification.

1.4The values stated in either SI units or inch-pound units are to be regarded separately as standard. Within the text, the SI units are shown in brackets. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard. The inch-pound units shall apply unless the “M” designation of this specification is specified in the order.

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ASTM A 213/A213M : 2013

Standard Specification for Seamless Ferritic and Austenitic Alloy-Steel Boiler, Superheater, and Heat-Exchanger Tubes

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