ASTM C 759 : 2018
Current
The latest, up-to-date edition.
Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Plutonium Nitrate Solutions
Hardcopy , PDF
English
01-09-2018
Important note : Users cannot be edited or removed once added to your Multi user PDF.1.1These test methods cover procedures for the chemical, mass spectrometric, spectrochemical, nuclear, and radiochemical analysis of nuclear-grade plutonium nitrate solutions to determine compliance with specifications.
| Committee |
C 26
|
| DocumentType |
Test Method
|
| Pages |
18
|
| ProductNote |
THIS STANDARD ALSO REFERS ASTMC1108, ASTM C 1156, ASTM C1165, ASTM C 1297, ASTM C 1415
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Current
|
| Supersedes |
1.1These test methods cover procedures for the chemical, mass spectrometric, spectrochemical, nuclear, and radiochemical analysis of nuclear-grade plutonium nitrate solutions to determine compliance with specifications.
1.2The analytical procedures appear in the following order:
| Sections | |
| Plutonium by Controlled-Potential Coulometry | 2 |
| Plutonium by Amperometric Titration with Iron(II) | 2 |
| Plutonium by Diode Array Spectrophotometry | |
| Free Acid by Titration in an Oxalate Solution | 8 to 15 |
| Free Acid by Iodate Precipitation-Potentiometric Titration | 16 to 22 |
| Uranium by Arsenazo I Spectrophotometric Test Method | 23 to 33 |
| Thorium by Thorin Spectrophotometric Test Method | 34 to 42 |
| Iron by 1,10-Phenanthroline Spectrophotometric Test Method | 43 to 50 |
| Impurities by ICP-AES | |
| Chloride by Thiocyanate Spectrophotometric Test Method | 51 to 58 |
| Fluoride by Distillation-Spectrophotometric Test Method | 59 to 66 |
| Sulfate by Barium Sulfate Turbidimetric Test Method | 67 to 74 |
| Isotopic Composition by Mass Spectrometry | 75 to 76 |
| Plutonium-238 Isotopic Abundance by Alpha Spectrometry | |
| Americium-241 by Extraction and Gamma Counting | 77 to 85 |
| Americium-241 by Gamma Counting | 86 to 94 |
| Gamma-Emitting Fission Products, Uranium, and Thorium by Gamma-Ray Spectroscopy | 94 to 102 |
| Rare Earths by Copper Spark Spectrochemical Test Method | 103 to 105 |
| Tungsten, Niobium (Columbium), and Tantalum by Spectro- | 106 to 114 |
| Sample Preparation for Spectrographic Analysis for General | 115 to 118 |
1.3The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific safeguard and safety hazard statements, see Section 6.
1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
| ASTM C 1206 : 2002 : R2010 | Standard Test Method for Plutonium by Iron (II)/Chromium (VI) Amperometric Titration (Withdrawn 2015) |
| ASTM C 1165 : 2023 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<inf>2</inf>SO<inf>4</inf> at a Platinum Working Electrode |
| ASTM C 1009 : 2013 : REV A | Standard Guide for Establishing and Maintaining a Quality Assurance Program for Analytical Laboratories Within the Nuclear Industry |
| ASTM C 1307 : 2015 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 1415 : 2001 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance by Alpha Spectrometry |
| ASTM C 1108 : 2023 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 859 : 2023 | Standard Terminology Relating to Nuclear Materials |
| ASTM C 1210 : 2018 | Standard Guide for Establishing a Measurement System Quality Control Program for Analytical Chemistry Laboratories Within the Nuclear Industry |
| ASTM C 1415 : 1999 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance by Alpha Spectrometry |
| ASTM C 859 : 2014 : REV B | Standard Terminology Relating to Nuclear Materials |
| ASTM C 859 : 2024 | Standard Terminology Relating to Nuclear Materials |
| ASTM C 1128 : 2018 | Standard Guide for Preparation of Working Reference Materials for Use in Analysis of Nuclear Fuel Cycle Materials |
| ASTM D 1193 : 1977 : R1983 : EDT 1 | Standard Specification for Reagent Water |
| ASTM C 1206 : 1991 : R1996 | Standard Test Method for Plutonium by Iron (II)/Chromium (VI) Amperometric Titration |
| ASTM C 1268 : 1994 : R2008 | Standard Test Method for Quantitative Determination of Americium 241 in Plutonium by Gamma-Ray Spectrometry |
| ASTM C 1268 : 2015 | Standard Test Method for Quantitative Determination of <sup>241</sup>Am in Plutonium by Gamma-Ray Spectrometry |
| ASTM C 1009 : 1996 : EDT 1 | Standard Guide for Establishing a Quality Assurance Program for Analytical Chemistry Laboratories Within the Nuclear Industry (Withdrawn 2005) |
| ASTM C 1235 : 1999 | Standard Test Method for Plutonium by Titanium(III)/Cerium(IV) Titration (Withdrawn 2005) |
| ASTM C 1210 : 1996 : EDT 1 | Standard Guide for Establishing a Measurement System Quality Control Program for Analytical Chemistry Laboratories Within the Nuclear Industry (Withdrawn 2005) |
| ASTM C 1210 : 2021 | Standard Guide for Establishing a Measurement System Quality Control Program for Analytical Chemistry Laboratories Within Nuclear Industry |
| ASTM C 1165 : 1990 : R2005 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<sub>2</sub>SO<sub>4</sub> at a Platinum Working Electrode |
| ASTM C 1128 : 1995 : EDT 1 | Standard Guide for Preparation of Working Reference Materials for Use in the Analysis of Nuclear Fuel Cycle Materials |
| ASTM C 1068 : 1996 : EDT 1 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1165 : 2022 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<inf>2</inf>SO<inf>4</inf> at a Platinum Working Electrode |
| ASTM C 1108 : 2017 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 1156 : 2003 : R2011 | Standard Guide for Establishing Calibration for a Measurement Method Used to Analyze Nuclear Fuel Cycle Materials |
| ASTM C 1307 : 2002 : R2008 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 1210 : 2012 | Standard Guide for Establishing a Measurement System Quality Control Program for Analytical Chemistry Laboratories Within the Nuclear Industry |
| ASTM C 1432 : 2023 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1206 : 2002 | Standard Test Method for Plutonium by Iron (II)/Chromium (VI) Amperometric Titration |
| ASTM C 1165 : 1990 : R2000 : EDT 1 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<sub>2</sub>SO<sub>4</sub> at a Platinum Working Electrode |
| ASTM C 1128 : 2015 | Standard Guide for Preparation of Working Reference Materials for Use in Analysis of Nuclear Fuel Cycle Materials |
| ASTM C 1068 : 2003 : R2011 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1210 : 2006 | Standard Guide for Establishing a Measurement System Quality Control Program for Analytical Chemistry Laboratories Within the Nuclear Industry |
| ASTM C 1432 : 2003 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM D 1193 : 2006 : R2011 | Standard Specification for Reagent Water |
| ASTM C 1108 : 1999 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 1415 : 2014 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance By Alpha Spectrometry |
| ASTM C 1432 : 2003 : R2008 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1068 : 2015 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1415 : 2001 : REV A : R2007 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance by Alpha Spectrometry |
| ASTM C 1307 : 1995 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 1068 : 2021 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1165 : 2012 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<inf>2</inf>SO<inf>4</inf> at a Platinum Working Electrode |
| ASTM C 1432 : 2015 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1297 : 2003 : R2011 | Standard Guide for Qualification of Laboratory Analysts for the Analysis of Nuclear Fuel Cycle Materials |
| ASTM C 1297 : 2003 | Standard Guide for Qualification of Laboratory Analysts for the Analysis of Nuclear Fuel Cycle Materials |
| ASTM C 1268 : 1994 : R2000 | Standard Test Method for Quantitative Determination of Americium 241 in Plutonium by Gamma-Ray Spectrometry |
| ASTM C 859 : 2022 | Standard Terminology Relating to Nuclear Materials |
| ASTM C 859 : 2022 : REV A | Standard Terminology Relating to Nuclear Materials |
| ASTM C 1297 : 1995 : EDT 1 | Standard Guide for Qualification of Laboratory Analysts for the Analysis of Nuclear Fuel Cycle Materials |
| ASTM D 1193 : 1991 | Standard Specification for Reagent Water |
| ASTM C 1156 : 2018 | Standard Guide for Establishing Calibration for a Measurement Method Used to Analyze Nuclear Fuel Cycle Materials |
| ASTM C 1128 : 2023 | Standard Guide for Preparation of Working Reference Materials for Use in Analysis of Nuclear Fuel Cycle Materials |
| ASTM C 1128 : 2001 | Standard Guide for Preparation of Working Reference Materials for Use in the Analysis of Nuclear Fuel Cycle Materials |
| ASTM C 1068 : 2003 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1307 : 2014 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 1268 : 2023 | Standard Test Method for Quantitative Determination of <sup>241</sup>Am in Plutonium by Gamma-Ray Spectrometry |
| ASTM E 50 : 2017 | Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials |
| ASTM C 1307 : 2021 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 1156 : 1995 : EDT 1 | Standard Guide for Establishing Calibration for a Measurement Method Used to Analyze Nuclear Fuel Cycle Materials |
| ASTM E 50 : 2024 | Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials |
| ASTM C 1108 : 2022 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 1108 : 2012 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 1165 : 2017 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<inf>2</inf>SO<inf>4</inf> at a Platinum Working Electrode |
| ASTM C 852/C852M : 2017 : R2022 | Standard Guide for Design Criteria for Plutonium Gloveboxes |
| ASTM D 1193 : 1970 | Standard Specification For Reagent Water |
| ASTM E 115 : 1997 | Standard Practice for Photographic Processing in Optical Emission Spectrographic Analysis (Withdrawn 2002) |
| ASTM D 1193 : 2006 | Standard Specification for Reagent Water |
| ASTM C 1307 : 2002 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM E 50 : 1982 : R1986 | Standard Practices for Apparatus, Reagents, and Safety Precautions for Chemical Analysis of Metals |
| ASTM D 1193 : 1999 | Standard Specification for Reagent Water |
| ASTM C 1432 : 1999 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1009 : 2021 | Standard Guide for Establishing and Maintaining a Quality Assurance Program for Analytical Laboratories Within the Nuclear Industry |
| ASTM C 852/C852M : 2017 | Standard Guide for Design Criteria for Plutonium Gloveboxes |
| ASTM C 1128 : 2001 : R2008 | Standard Guide for Preparation of Working Reference Materials for Use in Analysis of Nuclear Fuel Cycle Materials |
| ASTM C 1415 : 2018 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance By Alpha Spectrometry |
| ASTM C 1009 : 2013 | Standard Guide for Establishing and Maintaining a Quality Assurance Program for Analytical Laboratories Within the Nuclear Industry |
| ASTM D 1193 : 2006 : R2018 | Standard Specification for Reagent Water |
| ASTM C 1156 : 2003 | Standard Guide for Establishing Calibration for a Measurement Method Used to Analyze Nuclear Fuel Cycle Materials |
| ASTM C 1009 : 2006 | Standard Guide for Establishing a Quality Assurance Program for Analytical Chemistry Laboratories Within the Nuclear Industry |
| ASTM C 1297 : 2018 | Standard Guide for Qualification of Laboratory Analysts for the Analysis of Nuclear Fuel Cycle Materials |
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