ASTM D 3270 : 2013 : R2021

1.1These test methods describe the semiautomated procedure for the analyses of various types of samples for the purpose of determining total fluoride. Since the test methods incorporate microdistillation of the sample, they may be applied to any fluoride-containing solution where standards of identical composition have been carried through the same sample preparation procedures and have proven to provide quantitative recovery when analyzed by the semiautomated system. Conversely, the methods shall not be applied for analyses until the applicability has been demonstrated.

1.2In normal use, the procedure can detect 0.1 μg/mL of F. The normal range of analysis is from 0.1 to 1.6 μg/mL of F. Higher concentrations can be analyzed by careful dilution of samples with reagent water. If digested samples routinely exceed 1.6 μg/mL of F, the analytical portion of the pump manifold can be modified to reduce sensitivity. However, the best procedure is to analyze a smaller aliquot of the sample. Most accurate results are obtained when the fluoride concentration falls in the middle or upper part of the calibration curve.

1.3The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See 8.3, 10.2.4, and 10.2.5 for additional precautions.

1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.