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ASTM D 4128 : 2018

Current

Current

The latest, up-to-date edition.

Standard Guide for Identification and Quantitation of Organic Compounds in Water by Combined Gas Chromatography and Electron Impact Mass Spectrometry

Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

01-01-2019

€56.53
Excluding VAT

Committee
D 19
DocumentType
Guide
Pages
8
PublisherName
American Society for Testing and Materials
Status
Current
Supersedes

1.1This guide covers the identification and quantitation of organic compounds by gas chromatography/mass spectrometry (GC-MS) (electron impact) that are present or extracted from water and are capable of passing through a gas chromatograph without alteration. This guide can be used to provide tentative identifications of volatile and semi-volatile organics, but is restricted to (a) compounds for which reference spectra can be obtained and (b) compounds that can be separated by gas chromatography (GC). These restrictions are imposed on the guide, but are not a limitation of the technique. The guide is written for analysis using automated data acquisition and handling.

1.2Guidelines have been included for quantitation using ASTM Test Methods D3871, D3973, and other GC-MS volatile/semivolatile procedures used for environmental analysis2. The actual detection limits for each component must be determined in each laboratory. Actual detection amounts will vary with the complexity of the matrix, the kind and condition of the GC-MS system, the sample preparation technique chosen, and the application of cleanup techniques to the sample extract, if any. Lower levels of detection can be achieved using modern sensitive instruments or with selected ion monitoring (SIM). To determine the interlaboratory detection estimate (IDE) and the interlaboratory quantitation estimate (IQE), follow Practices D6091 and D6512.

1.3The guide is applicable to the identification of many organic constituents of natural and treated waters. It includes all modes of sample introduction, including injection of organic extracts, direct aqueous injection, and purge and trap techniques.

1.4The guide is applicable to capillary column gas chromatography.

1.5The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.7This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D 5175 : 1991 : R2017 : EDT 1 Standard Test Method for Organohalide Pesticides and Polychlorinated Biphenyls in Water by Microextraction and Gas Chromatography
ASTM D 7100 : 2011 Standard Test Method for Hydraulic Conductivity Compatibility Testing of Soils with Aqueous Solutions

ASTM D 5175 : 1991 : R2024 Standard Test Method for Organohalide Pesticides and Polychlorinated Biphenyls in Water by Microextraction and Gas Chromatography
ASTM D 1129 : 2013 : R2020 Standard Terminology Relating to Water
ASTM D 3694 : 1996 Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents
ASTM D 1129 : 2013 : R2020 : EDT 2 Standard Terminology Relating to Water
ASTM D 3973 : 1985 : R2024 Standard Test Method for Low-Molecular Weight Halogenated Hydrocarbons in Water
ASTM D 1066 : 2018 Standard Practice for Sampling Steam
ASTM D 3871 : 1984 : R2017 Standard Test Method for Purgeable Organic Compounds in Water Using Headspace Sampling
ASTM D 1066 : 2018 : EDT 1 Standard Practice for Sampling Steam
ASTM D 2908 : 1991 : R2017 Standard Practice for Measuring Volatile Organic Matter in Water by Aqueous-Injection Gas Chromatography
ASTM D 3694 : 1996 : R2017 Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents
ASTM D 1129 : 2013 : R2020 : EDT 1 Standard Terminology Relating to Water
ASTM D 1129 : 1999 : REV A Standard Terminology Relating to Water
ASTM D 2908 : 1974 : R1980 : EDT 1 Standard Practice for Measuring Volatile Organic Matter in Water by Aqueous-Injection Gas Chromatography
ASTM D 1066 : 1997 : R2001 Standard Practice for Sampling Steam
ASTM E 355 : 1996 : R2021 : EDT 1 Standard Practice for Gas Chromatography Terms and Relationships
ASTM D 3973 : 1985 : R1995 : EDT 1 Standard Test Method for Low-Molecular Weight Halogenated Hydrocarbons in Water
ASTM D 3871 : 1984 : R2024 Standard Test Method for Purgeable Organic Compounds in Water Using Headspace Sampling
ASTM D 3973 : 1985 : R2017 Standard Test Method for Low-Molecular Weight Halogenated Hydrocarbons in Water
ASTM D 5317 : 1998 Standard Test Method for Determination of Chlorinated Organic Acid Compounds in Water by Gas Chromatography with an Electron Capture Detector
ASTM D 2908 : 1991 : R2024 Standard Practice for Measuring Volatile Organic Matter in Water by Aqueous-Injection Gas Chromatography
ASTM D 1192 : 1998 Standard Guide for Equipment for Sampling Water and Steam in Closed Conduits (Withdrawn 2003)
ASTM D 5316 : 1998 : R2017 Standard Test Method for 1,2-Dibromoethane and 1,2-Dibromo-3-Chloropropane in Water by Microextraction and Gas Chromatography
ASTM D 5316 : 1998 : R2024 Standard Test Method for 1,2-Dibromoethane and 1,2-Dibromo-3-Chloropropane in Water by Microextraction and Gas Chromatography
ASTM D 6091 : 2007 : R2014 Standard Practice for 99 %/95 % Interlaboratory Detection Estimate (IDE) for Analytical Methods with Negligible Calibration Error (Withdrawn 2023)
ASTM D 5175 : 1991 : R1996 : EDT 1 Standard Test Method for Organohalide Pesticides and Polychlorinated Biphenyls in Water by Microextraction and Gas Chromatography
ASTM D 5316 : 1998 Standard Test Method for 1,2-Dibromoethane and 1,2-Dibromo-3-Chloropropane in Water by Microextraction and Gas Chromatography
ASTM D 3370 : 1976 Standard Practices for Sampling Water
ASTM D 1193 : 1970 Standard Specification For Reagent Water
ASTM E 355 : 1996 : R2014 Standard Practice for Gas Chromatography Terms and Relationships
ASTM D 3871 : 1984 : R1995 : EDT 1 Standard Test Method for Purgeable Organic Compounds in Water Using Headspace Sampling
ASTM D 3694 : 1996 : R2024 Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents
ASTM D 6512 : 2000 Standard Practice for Interlaboratory Quantitation Estimate
ASTM D 5317 : 2020 Standard Test Method for Determination of Chlorinated Organic Acid Compounds in Water by Gas Chromatography with an Electron Capture Detector
ASTM D 6091 : 1997 Standard Practice for 99 %/95 % Interlaboratory Detection Estimate (IDE) for Analytical Methods with Negligible Calibration Error
ASTM D 6512 : 2007 : R2014 Standard Practice for Interlaboratory Quantitation Estimate (Withdrawn 2023)

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