ASTM D 4735 : 2024 : REDLINE

1.1This test method covers the determination of thiophene in refined benzene.

1.2This test method is applicable to samples with thiophene concentrations in the range from 0.80 mg/kg to 1.80 mg/kg for the Flame Photometric Detector (FPD), and from 0.14 mg/kg to 2.61 mg/kg for the Pulsed Flame Photometric Detector (PFPD). For the PFPD, the minimum level of quantitation (LOQ) is 0.14 mg/kg and the minimum level of detection (LOD) is 0.04 mg/kg. With careful analytical technique, and/or replicates, this method can be used to successfully analyze concentrations below the current LOD. The range of the test method may be extended by modifying the sample injection volume, split ratios, calibration range, or sample dilution with thiophene-free solvent.

1.3This test method has been found applicable to benzene characteristic of the type described in Specifications D2359 and D4734 and may be applicable to other types or grades of benzene only after the user has demonstrated that the procedure can completely resolve thiophene from the other organic contaminants contained in the sample.

1.4The following applies for the purposes of determining the conformance to applicable specifications using this test method, results shall be rounded off in accordance the rounding-off method of Practice E29.

1.5The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.

1.7This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.