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ASTM D 5504 : 1998

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

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Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence

Superseded date

11-11-2014

Superseded by

ASTM D 5504 : 2001

Published date

31-12-2010

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Committee
D 03
DocumentType
Test Method
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy

1.1 This test method is primarily for the determination of speciated volatile sulfur-containing compounds in high methane content gaseous fuels such as natural gas. It has been successfully applied to other types of gaseous samples including air, digester, landfill, and refinery fuel gas. The detection range for sulfur compounds, reported as picograms sulfur, is ten (10) to one million (1 000 000). This is equivalent to 0.01 to 1 000 mg/m3, based upon the analysis of a 1 cc sample.

1.2 This test method does not purport to identify all sulfur species in a sample. Only compounds that are eluted through the selected column under the chromatographic conditions chosen are determined. The detector response to sulfur is equimolar for all sulfur compounds within the scope (1.1) of this test method. Thus, unidentified compounds are determined with equal precision to that of identified substances. Total sulfur content is determined from the total of individually quantified components.

1.3 The values stated in SI units are standard. The values stated in inch-pound units are for information only.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

ASTM D 6021 : 2012 : R2017 Standard Test Method for Measurement of Total Hydrogen Sulfide in Residual Fuels by Multiple Headspace Extraction and Sulfur Specific Detection
ASTM D 6968 : 2003 : R2015 Standard Test Method for Simultaneous Measurement of Sulfur Compounds and Minor Hydrocarbons in Natural Gas and Gaseous Fuels by Gas Chromatography and Atomic Emission Detection (Withdrawn 2024)
ASTM D 5287 : 2008 : R2015 Standard Practice for Automatic Sampling of Gaseous Fuels (Withdrawn 2024)
ASTM D 7166 : 2010 : R2015 Standard Practice for Total Sulfur Analyzer Based On-line/At-line for Sulfur Content of Gaseous Fuels
ASTM D 5623 : 2019 Standard Test Method for Sulfur Compounds in Light Petroleum Liquids by Gas Chromatography and Sulfur Selective Detection
ASTM D 7807 : 2012 Standard Test Method for Determination of Boiling Range Distribution of Hydrocarbon and Sulfur Components of Petroleum Distillates by Gas Chromatography and Chemiluminescence Detection
ASTM D 1835 : 2018 : REV A Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 7551 : 2010 : R2015 Standard Test Method for Determination of Total Volatile Sulfur in Gaseous Hydrocarbons and Liquefied Petroleum Gases and Natural Gas by Ultraviolet Fluorescence (Withdrawn 2024)
ASTM D 6228 : 2019 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Flame Photometric Detection
ASTM D 7800/D7800M : 2014 Standard Test Method for Determination of Elemental Sulfur in Natural Gas (Withdrawn 2023)
ASTM D 7652 : 2011 Standard Test Method for Determination of Trace Hydrogen Sulfide, Carbonyl Sulfide, Methyl Mercaptan, Carbon Disulfide and Total Sulfur in Hydrogen Fuel by Gas Chromatography and Sulfur Chemiluminescence Detection (Withdrawn 2020)
ASTM D 7165 : 2010 : R2015 Standard Practice for Gas Chromatograph Based On-line/At-line Analysis for Sulfur Content of Gaseous Fuels
ASTM D 7807 : 2020 Standard Test Method for Determination of Boiling Range Distribution of Hydrocarbon and Sulfur Components of Petroleum Distillates by Gas Chromatography and Chemiluminescence Detection
ASTM D 1835 : 2020 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 7663 : 2012 : R2018 : EDT 1 Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations
ASTM D 7493 : 2014 : R2018 Standard Test Method for Online Measurement of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatograph and Electrochemical Detection

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