ASTM D 6228 : 2019
Current
The latest, up-to-date edition.
Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Flame Photometric Detection
Hardcopy , PDF
English
05-12-2023
This test method covers the determination of individual volatile sulfur-containing compounds in gaseous fuels by gas chromatography (GC) with a flame photometric detector (FPD) or a pulsed flame photometric detector (PFPD). The detection range for sulfur compounds is from 20 to 20 000 picograms (pg) of sulfur.
Committee |
D 03
|
DocumentType |
Test Method
|
Pages |
9
|
ProductNote |
THIS STANDARD ALSO REFERES TO : EPA–15,EPA–16
|
PublisherName |
American Society for Testing and Materials
|
Status |
Current
|
Supersedes |
1.1This test method covers the determination of individual volatile sulfur-containing compounds in gaseous fuels by gas chromatography (GC) with a flame photometric detector (FPD) or a pulsed flame photometric detector (PFPD). The detection range for sulfur compounds is from 20 to 20 000 picograms (pg) of sulfur. This is equivalent to 0.02 to 20 mg/m3 or 0.014 to 14 ppmv of sulfur based upon the analysis of a 1 mL sample.
1.2This test method describes a GC method using capillary column chromatography with either an FPD or PFPD.
1.3This test method does not intend to identify all individual sulfur species. Total sulfur content of samples can be estimated from the total of the individual compounds determined. Unknown compounds are calculated as monosulfur-containing compounds.
1.4The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.
1.5This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D 6968 : 2003 : R2015 | Standard Test Method for Simultaneous Measurement of Sulfur Compounds and Minor Hydrocarbons in Natural Gas and Gaseous Fuels by Gas Chromatography and Atomic Emission Detection (Withdrawn 2024) |
ASTM D 7551 : 2010 : R2015 | Standard Test Method for Determination of Total Volatile Sulfur in Gaseous Hydrocarbons and Liquefied Petroleum Gases and Natural Gas by Ultraviolet Fluorescence (Withdrawn 2024) |
ASTM D 7800/D7800M : 2014 | Standard Test Method for Determination of Elemental Sulfur in Natural Gas (Withdrawn 2023) |
ASTM D 7165 : 2010 : R2015 | Standard Practice for Gas Chromatograph Based On-line/At-line Analysis for Sulfur Content of Gaseous Fuels |
ASTM D 7165 : 2022 | Standard Practice for Gas Chromatograph Based On-line/At-line Analysis for Sulfur Content of Gaseous Fuels |
ASTM D 7493 : 2022 | Standard Test Method for Online Measurement of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatograph and Electrochemical Detection |
ASTM D 8487 : 2023 | Standard Specification for Natural Gas, Hydrogen Blends for Use as a Motor Vehicle Fuel |
ASTM D 7800/D7800M : 2023 | Standard Test Method for Determination of Elemental Sulfur in Natural Gas |
ASTM D 8080 : 2021 | Standard Specification for Compressed Natural Gas (CNG) and Liquefied Natural Gas (LNG) Used as a Motor Vehicle Fuel |
ASTM D 8488 : 2022 | Standard Test Method for Determination of Hydrogen Sulfide (H<inf>2</inf>S) in Natural Gas by Tunable Diode Laser Spectroscopy (TDLAS) |
ASTM D 1265 : 1997 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method) |
ASTM D 3609 : 2000 : R2014 | Standard Practice for Calibration Techniques Using Permeation Tubes |
ASTM D 4468 : 1985 : R2015 | Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and<brk/> Rateometric Colorimetry |
ASTM D 4468 : 1985 : R2000 | Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and Rateometric Colorimetry |
ASTM D 5287 : 1997 | Standard Practice for Automatic Sampling of Gaseous Fuels |
ASTM D 1945 : 1996 : EDT 1 | Standard Test Method for Analysis of Natural Gas by Gas Chromatography |
ASTM D 1265 : 2023 : REV A | Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method |
ASTM D 1945 : 1996 : R2001 | Standard Test Method for Analysis of Natural Gas by Gas Chromatography |
ASTM D 4626 : 1995 : R2005 | Standard Practice for Calculation of Gas Chromatographic Response Factors |
ASTM D 3609 : 2000 : R2005 | Standard Practice for Calibration Techniques Using Permeation Tubes |
ASTM D 5504 : 2008 | Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence |
ASTM D 5287 : 2008 | Standard Practice for Automatic Sampling of Gaseous Fuels |
ASTM D 3609 : 2000 : R2010 | Standard Practice for Calibration Techniques Using Permeation Tubes |
ASTM D 3609 : 2022 | Standard Practice for Calibration Techniques Using Permeation Tubes |
ASTM D 3609 : 2000 | Standard Practice for Calibration Techniques Using Permeation Tubes |
ASTM D 5287 : 2008 : R2015 | Standard Practice for Automatic Sampling of Gaseous Fuels (Withdrawn 2024) |
ASTM D 4626 : 1995 : R2019 | Standard Practice for Calculation of Gas Chromatographic Response Factors |
ASTM D 1265 : 2004 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method) |
ASTM D 1945 : 2003 : R2010 | Standard Test Method for Analysis of Natural Gas by Gas Chromatography |
ASTM D 5504 : 1998 | Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence |
ASTM D 1945 : 2014 : R2019 | Standard Test Method for Analysis of Natural Gas by Gas Chromatography |
ASTM D 4468 : 1985 : R2011 | Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and<br> Rateometric Colorimetry |
ASTM D 1265 : 2011 : R2017 : EDT 1 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method |
ASTM D 1945 : 2003 | Standard Test Method for Analysis of Natural Gas by Gas Chromatography |
ASTM D 4468 : 1985 : R2006 | Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and Rateometric Colorimetry |
ASTM D 4626 : 2023 | Standard Practice for Calculation of Gas Chromatographic Response Factors |
ASTM E 840 : 1995 : R2013 | Standard Practice for Using Flame Photometric Detectors in Gas Chromatography |
ASTM D 4626 : 1995 : R2015 | Standard Practice for Calculation of Gas Chromatographic Response Factors |
ASTM D 5504 : 2001 | Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence |
ASTM D 1265 : 2005 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method) |
ASTM D 5504 : 2001 : R2006 | Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence |
ASTM D 4626 : 1995 : R2000 | Standard Practice for Calculation of Gas Chromatographic Response Factors |
ASTM D 5504 : 2012 | Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence |
ASTM D 1265 : 2004 : REV A | Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method) |
ASTM D 1265 : 2011 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method |
ASTM D 5504 : 2020 | Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence |
ASTM D 1265 : 2023 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method |
ASTM D 4626 : 1995 : R2010 | Standard Practice for Calculation of Gas Chromatographic Response Factors |
ASTM D 4468 : 2023 | Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and<brk/> Rateometric Colorimetry |
ASTM D 1945 : 2014 | Standard Test Method for Analysis of Natural Gas by Gas Chromatography |
ASTM D 1265 : 2022 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method |
ASTM E 840 : 1995 : R2021 : EDT 1 | Standard Practice for Using Flame Photometric Detectors in Gas Chromatography |
ASTM D 1945 : 1991 | Standard Test Method for Analysis of Natural Gas by Gas Chromatography |
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