ASTM D 6238 : 1998 : R2024

1.1This test method covers the determination of total oxygen demand in the range from 100 mg/L to 100 000 mg/L, in water and wastewater including brackish waters and brines (see 6.5). Larger concentrations, or samples with high suspended solids, or both, may be determined by suitable dilution of the sample.

1.2This test method is applicable to all oxygen-demanding substances under the conditions of the test contained in the sample that can be injected into the reaction zone. The injector opening limits the maximum size of particles that can be injected. If oxygen-demanding substances that are water-insoluble liquids or solids are present, a preliminary treatment may be desired. These pretreatment methods are described in Annex A2.

1.3This test method is particularly useful for measuring oxygen demand in certain industrial effluents and process streams. Its application for monitoring secondary sewage effluents is not established. Its use for the monitoring of natural waters is greatly limited by the interferences defined in Section 6.

1.4In addition to laboratory analysis, this test method is applicable to on-stream monitoring. Sample conditioning techniques for solids pretreatment applications are noted in Annex A2.

1.5The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.7This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.