ASTM D 7599 : 2016
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
View Superseded by
Standard Test Method for Determination of Diethanolamine, Triethanolamine, N-Methyldiethanolamine and N-Ethyldiethanolamine in Water by Single Reaction Monitoring Liquid Chromatography/Tandem Mass Spectrometry (LC/MS/MS)
Hardcopy , PDF
20-05-2024
English
01-02-2016
Important note : Users cannot be edited or removed once added to your Multi user PDF.CONTAINED IN VOL. 11.02, 2017 Defines the determination of diethanolamine, triethanolamine, N-methyldiethanolamine and N-ethyldiethanolamine (referred to collectively as ethanolamines in this test method) in surface water by direct injection using liquid chromatography (LC) and detected with tandem mass spectrometry (MS/MS).
| Committee |
D 19
|
| DocumentType |
Test Method
|
| Pages |
10
|
| ProductNote |
Reconfirmed 2016
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Superseded
|
| SupersededBy | |
| Supersedes |
1.1This procedure covers the determination of diethanolamine, triethanolamine, N-methyldiethanolamine and N-ethyldiethanolamine (referred to collectively as ethanolamines in this test method) in surface water by direct injection using liquid chromatography (LC) and detected with tandem mass spectrometry (MS/MS). These analytes are qualitatively and quantitatively determined by this test method. This test method adheres to single reaction monitoring (SRM) mass spectrometry.
1.2This test method has been developed by US EPA Region 5 Chicago Regional Laboratory (CRL).
1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4The Detection Verification Level (DVL) and Reporting Range for the ethanolamines are listed in Table 1.
1.4.1The DVL is required to be at a concentration at least 3 times below the Reporting Limit (RL) and have a signal/noise ratio greater than 3:1. Fig. 1 displays the signal/noise ratios at the DVLs and at higher concentrations for N-methyldiethanolamine.
Diethanolamine
25
24
6
96.34
51.00
156.96
31.31
10.96
32.50
9.49
Diethanolamine
50
24
6
101.41
54.00
154.80
29.54
7.97
29.13
7.91
Diethanolamine
200
24
6
101.57
61.00
138.00
20.98
10.50
20.66
10.85
Diethanolamine
425
24
6
102.06
70.00
138.82
17.98
5.90
17.61
5.70
Triethanolamine
25
24
6
87.70
35.96
157.20
27.00
25.18
30.79
27.48
Triethanolamine
50
24
6
94.95
67.00
121.66
16.39
9.57
17.26
9.66
Triethanolamine
200
22
6
105.00
79.50
132.00
14.06
11.81
13.39
11.52
Triethanolamine
425
24
6
96.94
40.00
144.94
27.56
4.41
28.43
5.76
N-Ethyldiethanolamine
25
24
6
90.61
31.00
132.00
39.42
7.47
43.51
10.42
N-Ethyldiethanolamine
50
23
6
111.88
49.00
146.00
28.71
7.19
25.66
7.56
N-Ethyldiethanolamine
200
24
6
106.20
60.00
134.00
23.09
11.96
21.74
12.23
N-Ethyldiethanolamine
425
24
6
99.67
51.00
130.00
23.07
4.68
23.15
6.01
N-Methyldiethanolamine
25
24
6
88.43
41.72
133.60
25.24
13.29
28.55
16.70
N-Methyldiethanolamine
50
24
6
102.28
56.00
153.80
25.85
8.73
25.27
8.22
N-Methyldiethanolamine
200
24
6
101.02
59.00
136.50
20.07
9.51
19.87
9.54
N-Methyldiethanolamine
425
24
6
94.75
63.00
115.76
15.02
3.34
15.85
3.72
Diethanolamine-D8 (Surrogate)
200
96
6
103.02
60.00
151.95
21.13
9.40
20.51
9.25
1.5This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
| ASTM D 1129 : 2013 : REDLINE | Standard Terminology Relating to Water |
| ASTM D 2777 : 2013 : REDLINE | Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water |
| ASTM E 2554 : 2013-05 | PRACTICE FOR ESTIMATING AND MONITORING THE UNCERTAINTY OF TEST RESULTS OF A TEST METHOD USING CONTROL CHART TECHNIQUES |
Access your standards online with a subscription
Features
-
Simple online access to standards, technical information and regulations.
-
Critical updates of standards and customisable alerts and notifications.
-
Multi-user online standards collection: secure, flexible and cost effective.