ASTM D 7644 : 2023
Current
The latest, up-to-date edition.
Standard Test Method for Determination of Bromadiolone, Brodifacoum, Diphacinone and Warfarin in Water by Liquid Chromatography/Tandem Mass Spectrometry (LC/MS/MS)
Hardcopy , PDF
English
02-06-2023
Important note : Users cannot be edited or removed once added to your Multi user PDF.| Committee |
D 19
|
| DocumentType |
Test Method
|
| Pages |
15
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Current
|
| Supersedes |
1.1This test method covers the determination of bromadiolone, brodifacoum, diphacinone and warfarin (referred to collectively as rodenticides in this test method) in water by direct injection using liquid chromatography (LC) and detected with tandem mass spectrometry (MS/MS). These analytes are qualitatively and quantitatively determined by this test method. This test method adheres to multiple reaction monitoring (MRM) mass spectrometry.
1.2The Detection Verification Level (DVL) and Reporting Range for the rodenticides are listed in Table 1.
1.2.1The DVL is required to be at a concentration at least 3 times below the Reporting Limit (RL) and have a signal/noise ratio greater than 3:1. Fig. 1 displays the signal/noise ratios of the primary single reaction monitoring (SRM) transitions, and Fig. 2 displays the confirmatory SRM transitions at the DVLs for the rodenticides.
1.2.2The reporting limit was calculated from the concentration of the Level 1 calibration standard, as shown in Table 4, accounting for the dilution of a 40 mL water sample up to a final volume of 50 mL with methanol to ensure analyte solubility.
1.3Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
| ASTM E 2554 : 2018 : R2024 : EDT 1 | Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method Using Control Chart Techniques |
| ASTM D 1129 : 2013 : R2020 : EDT 2 | Standard Terminology Relating to Water |
| ASTM D 3694 : 1996 : R2017 | Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents |
| ASTM D 1129 : 2013 : R2020 : EDT 1 | Standard Terminology Relating to Water |
| ASTM E 2554 : 2018 : EDT 1 | Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method Using Control Chart Techniques |
| ASTM D 3856 : 2011 : R2015 | Standard Guide for Management Systems in Laboratories Engaged in Analysis of Water (Withdrawn 2024) |
| ASTM D 3694 : 1996 : R2024 | Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents |
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