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ASTM D 7783 : 2013

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by

Standard Practice for Within-laboratory Quantitation Estimation (WQE)

Available format(s)

Hardcopy , PDF

Superseded date

30-04-2022

Superseded by

ASTM D 7783 : 2021

Language(s)

English

Published date

08-04-2013

€74.48
Excluding VAT

This practice establishes a uniform standard for computing the within-laboratory quantitation estimate associated with Z % relative standard deviation (referred to herein as WQEZ %), and provides guidance concerning the appropriate use and application.

Committee
D 19
DocumentType
Standard Practice
Pages
13
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy

1.1This practice establishes a uniform standard for computing the within-laboratory quantitation estimate associated with Z % relative standard deviation (referred to herein as WQEZ %), and provides guidance concerning the appropriate use and application.

1.2WQEZ % is computed to be the lowest concentration for which a single measurement from the laboratory will have an estimated Z % relative standard deviation (Z % RSD, based on within-laboratory standard deviation), where Z is typically an integer multiple of 10, such as 10, 20, or 30. Z can be less than 10 but not more than 30. The WQE10 % is consistent with the quantitation approaches of Currie (1)2 and Oppenheimer, et al (2).

1.3The fundamental assumption of the WQE is that the media tested, the concentrations tested, and the protocol followed in the developing the study data provide a representative and fair evaluation of the scope and applicability of the test method, as written. Properly applied, the WQE procedure ensures that the WQE value has the following properties:

1.3.1Routinely Achievable WQE Value—The laboratory should be able to attain the WQE in routine analyses, using the laboratory‘s standard measurement system(s), at reasonable cost. This property is needed for a quantitation limit to be feasible in practical situations. Representative data must be used in the calculation of the WQE.

1.3.2Accounting for Routine Sources of Error—The WQE should realistically include sources of bias and variation that are common to the measurement process and the measured materials. These sources include, but are not limited to intrinsic instrument noise, some typical amount of carryover error, bottling, preservation, sample handling and storage, analysts, sample preparation, instruments, and matrix.

1.3.3Avoidable Sources of Error Excluded—The WQE should realistically exclude avoidable sources of bias and variation (that is, those sources that can reasonably be avoided in routine sample measurements). Avoidable sources would include, but are not limited to, modifications to the sample, modifications to the measurement procedure, modifications to the measurement equipment of the validated method, and gross and easily discernible transcription errors (provided there was a way to detect and either correct or eliminate these errors in routine processing of samples).

1.4The WQE applies to measurement methods for which instrument calibration error is minor relative to other sources, because this practice does not model or account for instrument calibration error, as is true of quantiation estimates in general. Therefore, the WQE procedure is appropriate when the dominant source of variation is not instrument calibration, but is perhaps one or more of the following:

1.4.1Sample Preparation, and especially when calibration standards do not go through sample preparation.

1.4.2Differences in Analysts, and especially when analysts have little opportunity to affect instrument calibration results (as is the case with automated calibration).

1.4.3Differences in Instruments (measurement equipment), such as differences in manufacturer, model, hardware, electronics, sampling rate, chemical-processing rate, integration time, software algorithms, internal signal processing and thresholds, effective sample volume, and contamination level.

1.5Data Quality Objectives—For a given method, one typically would compute the lowest % RSD possible for any given data set. Thus, if possible, WQE10 % would be computed. If the data indicated that the method was too noisy, one might have to compute instead WQE20 %, or possibly WQE30 %. In any case, a WQE with a higher % RSD level (such as WQE50 %) would not be considered, though a WQE with RSD <10 % (such as WQE1 %) would be acceptable. The appropriate level of  % RSD is based on the data-quality objective(s) for a particular use or uses. This practice allows for calculation of WQEs with user selected  % RSDs less than 30 %.

ASTM D 6091 : 2007 Standard Practice for 99 %/95 % Interlaboratory Detection Estimate (IDE) for Analytical Methods with Negligible Calibration Error
ASTM D 1129 : 2013 : REDLINE Standard Terminology Relating to Water
ASTM D 1129 : 2003 Standard Terminology Relating to Water
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ASTM D 1129 : 2013 Standard Terminology Relating to Water
ASTM D 1129 : 2013 : R2020 Standard Terminology Relating to Water
ASTM D 2777 : 2012 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 1129 : 2006 Standard Terminology Relating to Water
ASTM D 2777 : 2003 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
ASTM D 2777 : 2013 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 2777 : 1998 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
ASTM D 1129 : 1999 : REV A Standard Terminology Relating to Water
ASTM D 1129 : 2006 : REV A Standard Terminology Relating to Water
ASTM D 1129 : 2003 : REV A Standard Terminology Relating to Water
ASTM D 1129 : 2002 Standard Terminology Relating to Water
ASTM D 6512 : 2003 Standard Practice for Interlaboratory Quantitation Estimate
ASTM E 1763 : 2006 Standard Guide for Interpretation and Use of Results from Interlaboratory Testing of Chemical Analysis Methods (Withdrawn 2015)
ASTM D 7510 : 2010 : R2016 : EDT 1 Standard Practice for Performing Detection and Quantitation Estimation and Data Assessment Utilizing DQCALC Software, based on ASTM Practices D6091 and D6512 of Committee D19 on Water
ASTM D 1129 : 2004 Standard Terminology Relating to Water
ASTM D 2777 : 2008 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 7510 : 2010 Standard Practice for Performing Detection and Quantitation Estimation and Data Assessment Utilizing DQCALC Software, based on ASTM Practices D6091 and D6512 of Committee D19 on Water <a href="#fn00003"></a>
ASTM D 2777 : 2006 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 6091 : 2003 Standard Practice for 99 %/95 % Interlaboratory Detection Estimate (IDE) for Analytical Methods with Negligible Calibration Error
ASTM D 1129 : 2002 : REV A Standard Terminology Relating to Water
ASTM D 6091 : 2007 : R2014 Standard Practice for 99 %/95 % Interlaboratory Detection Estimate (IDE) for Analytical Methods with Negligible Calibration Error (Withdrawn 2023)
ASTM E 1763 : 1998 Standard Guide for Interpretation and Use of Results from Interlaboratory Testing of Chemical Analysis Methods
ASTM D 6512 : 2007 Standard Practice for Interlaboratory Quantitation Estimate
ASTM D 1129 : 2010 Standard Terminology Relating to Water
ASTM D 1129 : 2006 : REV A : EDT 1 Standard Terminology Relating to Water
ASTM D 1129 : 2001 Standard Terminology Relating to Water
ASTM D 1129 : 2004 : EDT 1 Standard Terminology Relating to Water
ASTM D 2777 : 2008 : EDT 1 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 6512 : 2000 Standard Practice for Interlaboratory Quantitation Estimate
ASTM D 6091 : 1997 Standard Practice for 99 %/95 % Interlaboratory Detection Estimate (IDE) for Analytical Methods with Negligible Calibration Error
ASTM D 6512 : 2007 : R2014 Standard Practice for Interlaboratory Quantitation Estimate (Withdrawn 2023)

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