ASTM D 7994 : 2025
Current
The latest, up-to-date edition.
Standard Test Method for Total Fluorine, Chlorine, and Sulfur in Liquid Petroleum Gas (LPG) by Oxidative Pyrohydrolytic Combustion Followed by Ion Chromatography Detection (Combustion Ion Chromatography-CIC)
English
15-12-2025
| Committee |
D 02
|
| DocumentType |
Test Method
|
| Pages |
11
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Current
|
| Supersedes |
1.1ÂThis test method covers the individual determination of total fluorine, chlorine, and sulfur in liquid petroleum gas (LPG), low molecular weight hydrocarbons, their mixtures, and dimethyl ether (DME) in the range of 1 mg/kg to 225 mg/kg fluorine, 1 mg/kg to 281 mg/kg chlorine and 1 mg/kg to 248 mg/kg sulfur. This test method is applicable to products described in Specifications D1835 and D7901 and it can be applicable to process streams with similar properties to LPG and other materials such as butylene, propylene, and olefins.
1.2ÂThis test method can also be applied to the measurement of the bromine and iodine in samples covered by the scope of this test method, but the precision and bias statement of this test method is not applicable to these halides.
1.3ÂThis test method can be applied to sample concentrations outside the scope of this test method through adjustments of sample injection volume or number of injections combusted (or both), adjustment of injection volume to the ion chromatograph, and adjustment of the final dilution volume of the absorbing solution prior to injection to the ion chromatograph. The precision and scope of this test method is not applicable to samples that are outside the scope of the method.
1.4ÂThe values stated in SI units are to be regarded as standard.
1.4.1ÂException—Values given in parentheses are for information only.
1.5ÂThis standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See Section 9.
1.6ÂThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
| ASTM D 1835 : 2022 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 8149 : 2020 : R2025 | Standard Practice for Optimization, Calibration, and Validation of Ion Chromatographic Determination of Heteroatoms and Anions in Petroleum Products and Lubricants |
| ASTM D 5273 : 2024 | Standard Guide for Analysis of Propylene Concentrates |
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