Skip to content
Please enter a keyword to search

  • ASTM D 8025 : 2016

    View superseded by
    Superseded A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
    View superseded by

    Standard Test Method for Determination of Select Pesticides in Water by Multiple Reaction Monitoring Liquid Chromatography Tandem Mass Spectrometry

    Available format(s):  Hardcopy, PDF

    Superseded date:  09-06-2023

    Language(s):  English

    Published date:  11-08-2016

    Publisher:  American Society for Testing and Materials

    Add To Cart

    Abstract - (Show below) - (Hide below)

    CONTAINED IN VOL. 11.02, 2018 Defines a method for analysis of selected pesticides in a water matrix by filtration followed with liquid chromatography/electrospray ionization tandem mass spectrometry analysis.

    Scope - (Show below) - (Hide below)

    1.1This procedure covers a method for analysis of selected pesticides in a water matrix by filtration followed with liquid chromatography/electrospray ionization tandem mass spectrometry analysis. The samples are prepared in 20 % methanol, filtered, and analyzed by liquid chromatography/tandem mass spectrometry. This method was developed for an agricultural run-off study, not for low level analysis of pesticides in drinking water. This method may be modified for lower level analysis. The analytes are qualitatively and quantitatively determined by this method. This method adheres to multiple reaction monitoring (MRM) mass spectrometry.

    1.2A full collaborative study to meet the requirements of Practice D2777 has not been completed. This standard contains single-operator precision and bias based on single-operator data. Publication of standards that have not been fully validated is done to make the current technology accessible to users of standards, and to solicit additional input from the user community.

    1.3A reporting limit check sample (RLCS) is analyzed during every batch to ensure that if an analyte was present in a sample at or near the reporting limit it would be positively identified and accurately quantitated within set quality control limits. A method detection limit (MDL) study was not done for this method, the method detection limits would be much lower than the reporting limits in this method and would be irrelevant. A RLCS was determined to be more applicable for this standard. If this method is adapted to report much lower or near the MDL then a MDL study would be warranted.

    1.4Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.5The Reporting Range for the target analytes are listed in Table 1.

    1.5.1The reporting limit in this test method is the minimum value below which data are documented as non-detects. The reporting limit is calculated from the concentration of the Level 1 calibration standard as shown in Table 6 after taking into account an 8 mL water sample volume and a final diluted sample volume of 10 mL (80 % water/20 % methanol).

    1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

    General Product Information - (Show below) - (Hide below)

    Committee D 19
    Document Type Test Method
    Publisher American Society for Testing and Materials
    Status Superseded
    Superseded By

    Standards Referencing This Book - (Show below) - (Hide below)

    ASTM D 4841 : 1988 : R2008 Standard Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
    ASTM D 1129 : 2013 : REDLINE Standard Terminology Relating to Water
    ASTM D 1129 : 2003 Standard Terminology Relating to Water
    ASTM D 2777 : 2013 : REDLINE Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 4841 : 1988 : R2018 Standard Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
    ASTM D 1129 : 2013 Standard Terminology Relating to Water
    ASTM D 1129 : 2013 : R2020 Standard Terminology Relating to Water
    ASTM D 5847 : 1999 : REV A : EDT 1 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 2777 : 2012 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 1193 : 1977 : R1983 : EDT 1 Standard Specification for Reagent Water
    ASTM D 4841 : 1988 : R1998 Standard Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
    ASTM D 5847 : 2002 : R2007 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 1129 : 2006 Standard Terminology Relating to Water
    ASTM D 2777 : 2003 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
    ASTM D 2777 : 2021 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 4841 : 1988 : R2003 Standard Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
    ASTM D 2777 : 2013 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM E 2554 : 2013 Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method Using Control Chart Techniques
    ASTM D 4841 : 1988 : R2013 Standard Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
    ASTM D 5847 : 2002 : R2012 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 2777 : 1998 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
    ASTM D 1129 : 2013 : R2020 : EDT 1 Standard Terminology Relating to Water
    ASTM D 1129 : 1999 : REV A Standard Terminology Relating to Water
    ASTM D 3856 : 2011 Standard Guide for Management Systems in Laboratories Engaged in Analysis of Water
    ASTM D 1129 : 2006 : REV A Standard Terminology Relating to Water
    ASTM D 1193 : 2006 : R2011 Standard Specification for Reagent Water
    ASTM D 5847 : 2002 : R2020 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 1129 : 2003 : REV A Standard Terminology Relating to Water
    ASTM D 1129 : 2002 Standard Terminology Relating to Water
    ASTM E 2554 : 2018 : EDT 1 Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method Using Control Chart Techniques
    ASTM D 1193 : 1991 Standard Specification for Reagent Water
    ASTM D 3856 : 1995 : R2006 Standard Guide for Good Laboratory Practices in Laboratories Engaged in Sampling and Analysis of Water
    ASTM D 1129 : 2004 Standard Terminology Relating to Water
    ASTM D 5847 : 2022 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 2777 : 2008 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM E 2554 : 2007 Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method in a Single Laboratory Using a Control Sample Program
    ASTM D 3856 : 2011 : R2015 Standard Guide for Management Systems in Laboratories Engaged in Analysis of Water (Withdrawn 2024)
    ASTM D 2777 : 2006 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 3856 : 1995 : R2000 Standard Guide for Good Laboratory Practices in Laboratories Engaged in Sampling and Analysis of Water
    ASTM D 1129 : 2002 : REV A Standard Terminology Relating to Water
    ASTM E 2554 : 2018 Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method Using Control Chart Techniques
    ASTM D 5847 : 2002 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM E 2554 : 2013-05 PRACTICE FOR ESTIMATING AND MONITORING THE UNCERTAINTY OF TEST RESULTS OF A TEST METHOD USING CONTROL CHART TECHNIQUES
    ASTM D 1193 : 1970 Standard Specification For Reagent Water
    ASTM D 4841 : 1988 : R2013 : EDT 1 Standard Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
    ASTM D 1193 : 2006 Standard Specification for Reagent Water
    ASTM D 1193 : 1999 Standard Specification for Reagent Water
    ASTM D 1129 : 2010 Standard Terminology Relating to Water
    ASTM D 1129 : 2006 : REV A : EDT 1 Standard Terminology Relating to Water
    ASTM D 1129 : 2001 Standard Terminology Relating to Water
    ASTM D 1129 : 2004 : EDT 1 Standard Terminology Relating to Water
    ASTM D 1193 : 2006 : R2018 Standard Specification for Reagent Water
    ASTM D 2777 : 2008 : EDT 1 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    View more information

    • Access your standards online with a subscription

      Features

      • Simple online access to standards, technical information and regulations
      • Critical updates of standards and customisable alerts and notifications
      • Multi - user online standards collection: secure, flexibile and cost effective