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ASTM D 8545 : 2023 : EDT 1

Current

Current

The latest, up-to-date edition.

Standard Test Method for Determination of the Metal Deactivator Additive (MDA) (N,N′-disalicylidene-1,2-propanediamine) Content in Aviation Turbine Fuel by High Performance Liquid Chromatography (HPLC)

Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

05-02-2024

€61.92
Excluding VAT

Committee
D 02
DocumentType
Test Method
Pages
12
ProductNote
Editorially corrected 5.1 in February 2024.
PublisherName
American Society for Testing and Materials
Status
Current
Supersedes

1.1This test method covers the determination of the metal deactivator additive (MDA) content of aviation turbine fuels. The specific MDA determined and used to develop this test method is N,N-disalicylidene-1,2-propanediamine. Other MDAs have not been tested by this test method.

1.1.1This test method specifically covers the determination of uncomplexed MDA content in aviation turbine fuel. MDA is a chelator of divalent metal ions, and the MDA-metal ion complexed species content of aviation turbine fuel will not be accounted for by this test method.

1.2This test method is divided into two procedures: (1) Procedure A uses a semi-portable capillary-liquid chromatography system (Capillary-HPLC) that may be used in the field or laboratory; (2) Procedure B uses a standard laboratory version of liquid chromatography (Conventional-HPLC). Procedures A and B have separate precisions.

1.3The test method has an interim repeatability determined in accordance with Practice D6300. Based on the mean values of the samples used in the interim repeatability study, Procedure A is applicable in the range of 0.50 mg/mL to 10.0 mg/mL; the range for Procedure B is 0.60 mg/mL to 9.6 mg/mL. Higher concentrations can be determined by dilution, but the precision of the test method has not been determined.

1.3.1An extended interlaboratory study (ILS) will be conducted in the future to determine the full repeatability and reproducibility and the final applicable concentration ranges.

1.3.2The test method applies to MDA in petroleum-based aviation fuels and Synthetic Aviation Fuels (SAF). However, for the interim precision, a petroleum-based aviation fuel was used. Future ILS will include petroleum-based and SAFs. The test method is applicable to aviation fuels conforming to Specification D1655.

1.4Appendix X2 indicates other additives that have been verified to not interfere with the analysis of this test method.

1.5The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.7This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D 1655 : 2024 Standard Specification for Aviation Turbine Fuels
ASTM D 4175 : 2024 : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 1655 : 2024 : REV B Standard Specification for Aviation Turbine Fuels
ASTM D 6300 : 2023 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 1655 : 2024 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 4175 : 2023 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2024 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 1655 : 2023 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 6300 : 2024 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants

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