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ASTM E 1943 : 2024

Current

Current

The latest, up-to-date edition.

Standard Guide for Remediation of Ground Water by Natural Attenuation at Petroleum Release Sites

Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

01-11-2024

€87.94
Excluding VAT

Committee
E 50
DocumentType
Guide
Pages
44
PublisherName
American Society for Testing and Materials
Status
Current
Supersedes

1.1This is a guide for determining the appropriateness of remediation by natural attenuation and implementing remediation by natural attenuation at a given petroleum release site, either as a stand alone remedial action or in combination with other remedial actions.

1.2Natural attenuation is a potential remediation alternative for containment and reduction of the mass and concentration of petroleum hydrocarbons in the environment to protect human health and the environment. Remediation by natural attenuation depends upon natural processes such as biodegradation, dispersion, dilution, volatilization, hydrolysis, and sorption to attenuate petroleum constituents of concern to achieve remedial goals.

Note 1:Remedial goals must be established through another process as determined by the appropriate regulatory agency.

1.3In general, remediation by natural attenuation should not be considered a presumptive remedy. A determination of whether remediation by natural attenuation is appropriate for an individual petroleum release site, relative to site-specific remedial goals, requires site characterization, assessment of potential risks, evaluation of the need for source area control, and evaluation of potential effectiveness similar to other remedial action technologies. Application and implementation of remediation by natural attenuation requires demonstration of remedial progress and attainment of remedial goals by use of converging lines of evidence obtained through monitoring and evaluation of resulting data. When properly applied to a site, remediation by natural attenuation is a process for risk management and achieving remedial goals. Monitoring should be conducted until it has been demonstrated that natural attenuation will continue and eventually meet remedial goals. The determination of when monitoring can be terminated is a technical policy decision.

1.3.1The primary line of evidence for remediation by natural attenuation is provided by observed reductions in plume geometry and observed reductions in concentrations of the constituents of concern at the site.

1.3.2Secondary lines of evidence for remediation by natural attenuation are provided by geochemical indicators of naturally occurring degradation and estimates of attenuation rates.

1.3.3Additional optional lines of evidence can be provided by microbiological information and further analysis of primary and secondary lines of evidence such as through solute transport modeling or estimates of assimilative capacity.

1.4The emphasis in this guide is on the use of remediation by natural attenuation for petroleum hydrocarbon constituents where ground water is impacted. Though soil and ground water impacts are often linked, this guide does not address natural attenuation in soils separate from ground water or in situations where soils containing constituents of concern exist without an associated ground water impact. Even if natural attenuation is selected as the remedial action for ground water, additional remedial action may be necessary to address other completed exposure pathways at the site.

1.5This guide does not address enhanced bioremediation or enhanced attenuation.

1.6Also, while much of what is discussed is relevant to other organic chemicals or constituents of concern, these situations will involve additional considerations not addressed in this guide.

1.7The guide is organized as follows:

1.7.1Section 2 lists referenced documents.

1.7.2Section 3 defines terminology used in this guide.

1.7.3Section 4 describes the significance and use of this guide.

1.7.4Section 5 provides an overview of the use of natural attenuation as a remedial action alternative, including;

1.7.4.1Advantages of remediation by natural attenuation as a remedial alternative;

1.7.4.2Limitations of remediation by natural attenuation as a remedial alternative; and

1.7.4.3Using multiple lines of evidence to demonstrate the appropriateness of remediation by natural remediation.

1.7.5Section 6 describes the decision process for appropriate application and implementation of remediation by natural attenuation including;

1.7.5.1Initial response, site characterization, selection of chemicals of concern, and establishment of remedial goals;

1.7.5.2Evaluation of plume status;

1.7.5.3Collection and evaluation of additional data;

1.7.5.4Comparing remediation by natural attenuation performance to remedial goals;

1.7.5.5Comparing remediation by natural attenuation to other remedial options;

1.7.5.6Implementation of a continued monitoring program;

1.7.5.7Evaluation of progress of remediation by natural attenuation; and

1.7.5.8No further action.

1.7.6Section 7 lists keywords relevant to this guide.

1.7.7Appendix X1 describes natural attenuation processes;

1.7.8Appendix X2 describes site characterization requirements for evaluating remediation by natural attenuation;

1.7.9Appendix X3 describes considerations for designing and implementing monitoring for remediation by natural attenuation;

1.7.10Appendix X4 describes sampling considerations and analytical methods for determining indicator parameters for remediation by natural attenuation;

1.7.11Appendix X5 describes the interpretation of different lines of evidence as indicators of natural attenuation;

1.7.12Appendix X6 describes methods for evaluation and quantification of natural attenuation rates; and

1.7.13Appendix X7 describes example problems illustrating the application and implementation of remediation by natural attenuation.

1.8This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.9This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM E 2081 : 2022 Standard Guide for Risk-Based Corrective Action
ASTM E 2616 : 2009 : R2020 Standard Guide for Remedy Selection Integrating Risk-Based Corrective Action and Non-Risk Considerations
ASTM E 2531 : 2006 : R2020 Standard Guide for Development of Conceptual Site Models and Remediation Strategies for Light Nonaqueous-Phase Liquids Released to the Subsurface
ASTM E 3361 : 2022 Standard Guide for Estimating Natural Attenuation Rates for Non-Aqueous Phase Liquids in the Subsurface

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