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ASTM E 478 : 2008 : R2017

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

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Standard Test Methods for Chemical Analysis of Copper Alloys

Available format(s)

Hardcopy , PDF

Superseded date

01-11-2024

Superseded by

ASTM E 478 : 2024

Language(s)

English

Published date

15-01-2017

€96.91
Excluding VAT

CONTAINED IN VOL. 03.05, 2017 Defines the chemical analysis of copper alloys having chemical ranges.

Committee
E 01
DevelopmentNote
Supersedes ASTM E 36 (12/2001)
DocumentType
Test Method
Pages
22
ProductNote
Reconfirmed 2017
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

1.1These test methods cover the chemical analysis of copper alloys having chemical ranges within the following limits:2

 Element

Composition, %

Aluminum

12.0 max

Antimony

 1.0 max

Arsenic

 1.0 max

Cadmium

 1.5 max

Cobalt

 1.0 max

Copper

40.0 min

Iron

 6.0 max

Lead

27.0 max

Manganese

 6.0 max

Nickel

50.0 max

Phosphorus

 1.0 max

Silicon

 5.0 max

Sulfur

 0.1 max

Tin

20.0 max

Zinc

50.0 max

1.2The test methods appear in the following order:

Sections

Aluminum by the Carbamate Extraction-Ethyl-
enedinitrilotetraacetate Titrimetric Test Method [2 % to 12 %]

71 – 78

Copper by the Combined Electrodeposition Gravimetric and Oxalyldihydrazide Spectrophotometric Test Method [50 %, minimum]

10 – 18

Iron by the 1,10-Phenanthroline Spectrophotometric Test Method [0.003 % to 1.25 %]

19 – 28

Lead by Atomic Absorption Spectrometry [0.002 % to 15 %]

90 – 100

Lead by the Ethylenedinitrilotetraacetic Acid (EDTA) Titrimetric Test Method [2.0 % to 30.0 %]

29 – 36

Nickel by the Dimethylglyoxime Extraction Sprectophotometric Test Method [0.03 % to 5.0 %]

37 – 46

Nickel by the Dimethylglyoxime Gravimetric Test Method [4 % to 50 %]

55 – 62

Silver in Silver-Bearing Copper by Atomic Absorption Spectrometry [0.01 % to 0.12 %]

101 – 112

Tin by the Iodotimetric Titration Test Method [0.5 % to 20 %]

63 – 70

Tin by the Phenylfluorone Spectrophotometric Test Method [0.01 % to 1.0 %]

113 – 123

Zinc by Atomic Absorption Spectrometry [0.2 % to 2 %]

79 – 89

Zinc by the Ethylenedinitrilotetraacetic Acid (EDTA) Titrimetric Test Method [2 % to 40 %]

47 – 54

1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM B 1014 : 2020 Standard Specification for Welded Copper and Copper Alloy Condenser and Heat Exchanger Tubes with a Textured Surface(s)
ASTM B 187/B187M : 2020 Standard Specification for Copper, Bus Bar, Rod, and Shapes and General Purpose Rod, Bar, and Shapes
ASTM B 248M : 2017 Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Plate, Sheet, Strip, and Rolled Bar (Metric)
ASTM B 372 : 2017 Standard Specification for Seamless Copper and Copper-Alloy Rectangular Waveguide Tube
ASTM B 121/B121M : 2016 Standard Specification for Leaded Brass Plate, Sheet, Strip, and Rolled Bar
ASTM B 888/B888M : 2019 Standard Specification for Copper Alloy Strip for Use in Manufacture of Electrical Connectors or Spring Contacts
ASTM B 395/B395M : 2018 Standard Specification for U-Bend Seamless Copper and Copper Alloy Heat Exchanger and Condenser Tubes
ASTM B 411/B411M : 2014 : R2019 Standard Specification for Copper-Nickel-Silicon Alloy Rod and Bar
ASTM B 740 : 2009 : R2015 Standard Specification for Copper-Nickel-Tin Spinodal Alloy Strip
ASTM B 552 : 2019 Standard Specification for Seamless and Welded Copper–Nickel Tubes for Water Desalting Plants
ASTM B 706 : 2018 Standard Specification for Seamless Copper Alloy (UNS No. C69100) Pipe and Tube
ASTM B 453/B453M : 2019 Standard Specification for Copper-Zinc-Lead Alloy (Leaded-Brass) Rod, Bar, and Shapes
ASTM B 508 : 2016 Standard Specification for Copper Alloy Strip for Flexible Metal Hose
ASTM B 465 : 2020 Standard Specification for Copper-Iron Alloy Plate, Sheet, Strip, and Rolled Bar
ASTM B 100 : 2020 Standard Specification for Wrought Copper-Alloy Bearing and Expansion Plates and Sheets for Bridge and Other Structural Use
ASTM B 272 : 2012 : R2019 Standard Specification for Copper Flat Products with Finished (Rolled or Drawn) Edges (Flat Wire and Strip)
ASTM B 139/B139M : 2012 : R2017 Standard Specification for Phosphor Bronze Rod, Bar, and Shapes
ASTM B 206/B206M : 2012 : R2017 Standard Specification for Copper-Nickel-Zinc (Nickel Silver) Wire and Copper-Nickel Alloy Wire
ASTM B 248 : 2017 Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Plate, Sheet, Strip, and Rolled Bar
ASTM B 251/B251M : 2017 Standard Specification for General Requirements for Wrought Seamless Copper and Copper-Alloy Tube
ASTM B 747 : 2020 Standard Specification for Copper-Zirconium Alloy Sheet and Strip
ASTM F 468 : 2016 Standard Specification for Nonferrous Bolts, Hex Cap Screws, Socket Head Cap Screws, and Studs for General Use
ASTM B 694 : 2019 Standard Specification for Copper, Copper-Alloy, Copper-Clad Bronze (CCB), Copper-Clad Stainless Steel (CCS), and Copper-Clad Alloy Steel (CAS) Sheet and Strip for Electrical Cable Shielding
ASTM B 43 : 2020 Standard Specification for Seamless Red Brass Pipe, Standard Sizes
ASTM B 129 : 2017 Standard Specification for Cartridge Brass Cartridge Case Cups
ASTM B 592 : 2020 Standard Specification for Copper-Zinc-Aluminum-Cobalt Alloy, Copper-Zinc-Tin-Iron Alloy Plate, Sheet, Strip, and Rolled Bar
ASTM B 466/B466M : 2018 Standard Specification for Seamless Copper-Nickel Pipe and Tube
ASTM B 124/B124M : 2020 Standard Specification for Copper and Copper Alloy Forging Rod, Bar, and Shapes
ASTM B 543/B543M : 2018 Standard Specification for Welded Copper and Copper-Alloy Heat Exchanger Tube
ASTM B 569 : 2019 Standard Specification for Brass Strip in Narrow Widths and Light Gage for Heat-Exchanger Tubing
ASTM B 96/B96M : 2020 Standard Specification for Copper-Silicon Alloy Plate, Sheet, Strip, and Rolled Bar for General Purposes and Pressure Vessels
ASTM B 131 : 2017 Standard Specification for Copper Alloy Bullet Jacket Cups
ASTM B 250/B250M : 2019 Standard Specification for General Requirements for Wrought Copper Alloy Wire
ASTM F 467 : 2013 : R2018 Standard Specification for Nonferrous Nuts for General Use
ASTM B 591 : 2020 : REV A Standard Specification for Copper-Zinc-Tin and Copper-Zinc-Tin-Iron-Nickel Alloys Plate, Sheet, Strip, and Rolled Bar
ASTM B 882 : 2010 : R2018 Standard Specification for Pre-Patinated Copper for Architectural Applications
ASTM B 283/B283M : 2020 Standard Specification for Copper and Copper-Alloy Die Forgings (Hot-Pressed)
ASTM B 359/B359M : 2018 Standard Specification for Copper and Copper-Alloy Seamless Condenser and Heat Exchanger Tubes With Integral Fins
ASTM B 36/B36M : 2018 Standard Specification for Brass Plate, Sheet, Strip, And Rolled Bar
ASTM B 1018 : 2021 Standard Specification for Seamless Copper-Iron Tube for Air Conditioning and Refrigeration Field Service
ASTM B 956 : 2019 : EDT 1 Standard Specification for Welded Copper and Copper-Alloy Condenser and Heat Exchanger Tubes with Integral Fins
ASTM B 21/B21M : 2020 Standard Specification for Naval Brass Rod, Bar, and Shapes
ASTM B 919 : 2019 Standard Specification for Welded Copper Heat Exchanger Tubes With Internal Enhancement
ASTM B 301/B301M : 2013 : R2020 Standard Specification for Free-Cutting Copper Rod, Bar, Wire, and Shapes
ASTM F 3042 : 2013 : R2018 Standard Specification for Nonferrous Hex Socket, Slotted Headless, and Square Head Set Screws
ASTM B 967/B967M : 2018 Standard Specification for Copper-Zinc-Tin-Bismuth Alloy Rod, Bar and Wire
ASTM B 929 : 2017 Standard Specification for Copper-Nickel-Tin Spinodal Alloy Rod and Bar
ASTM B 140/B140M : 2012 : R2017 Standard Specification for Copper-Zinc-Lead (Red Brass or Hardware Bronze) Rod, Bar, and Shapes
ASTM B 315 : 2019 Standard Specification for Seamless Copper Alloy Pipe and Tube
ASTM B 824 : 2017 Standard Specification for General Requirements for Copper Alloy Castings
ASTM B 16/B16M : 2019 Standard Specification for Free-Cutting Brass Rod, Bar and Shapes for Use in Screw Machines
ASTM F 467M : 2006 : REV A : R2018 Standard Specification for Nonferrous Nuts for General Use (Metric)
ASTM B 122/B122M : 2020 Standard Specification for Copper-Nickel-Tin Alloy, Copper-Nickel-Zinc Alloy (Nickel Silver), and Copper-Nickel Alloy Plate, Sheet, Strip, and Rolled Bar
ASTM F 468M : 2006 : R2018 Standard Specification for Nonferrous Bolts, Hex Cap Screws, and Studs for General Use (Metric)
ASTM B 138/B138M : 2011 : R2017 Standard Specification for Manganese Bronze Rod, Bar, and Shapes
ASTM B 5 : 2016 Standard Specification for High Conductivity Tough-Pitch Copper Refinery Shapes
ASTM B 42 : 2020 Standard Specification for Seamless Copper Pipe, Standard Sizes
ASTM B 19 : 2020 Standard Specification for Cartridge Brass Sheet, Strip, Plate, Bar, and Disks
ASTM B 370 : 2012 : R2019 Standard Specification for Copper Sheet and Strip for Building Construction
ASTM B 111/B111M : 2018 : REV A Standard Specification for Copper and Copper-Alloy Seamless Condenser Tubes and Ferrule Stock
ASTM B 98/B98M : 2013 : R2019 Standard Specification for Copper-Silicon Alloy Rod, Bar and Shapes
ASTM B 151/B151M : 2020 Standard Specification for Copper-Nickel-Zinc Alloy (Nickel Silver) and Copper-Nickel Rod and Bar
ASTM B 103/B103M : 2019 Standard Specification for Phosphor Bronze Plate, Sheet, Strip, and Rolled Bar
ASTM B 1017 : 2021 Standard Specification for Seamless Copper-Iron Tube for Air Conditioning and Refrigeration
ASTM B 249/B249M : 2020 Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Rod, Bar, Shapes and Forgings
ASTM B 644 : 2011 : R2017 Standard Specification for Copper Alloy Addition Agents
ASTM B 30 : 2020 Standard Specification for Copper Alloys in Ingot and Other Remelt Forms
ASTM B 130 : 2019 Standard Specification for Commercial Bronze Strip for Bullet Jackets
ASTM B 49 : 2020 Standard Specification for Copper Rod for Electrical Purposes
ASTM B 950 : 2021 : EDT 1 Standard Guide for Editorial Procedures and Form of Product Specifications for Copper and Copper Alloys
ASTM B 936 : 2019 Standard Specification for Copper-Chromium-Iron-Titanium Alloy Plate, Sheet, Strip and Rolled Bar
ASTM B 467 : 2014 Standard Specification for Welded Copper-Nickel Pipe
ASTM B 150/B150M : 2019 Standard Specification for Aluminum Bronze Rod, Bar, and Shapes
ASTM B 159/B159M : 2017 Standard Specification for Phosphor Bronze Wire
ASTM B 974/B974M : 2016 : R2021 Standard Specification for Free-Cutting Bismuth Brass Rod, Bar and Wire
ASTM B 587 : 2019 Standard Specification for Welded Brass Tube
ASTM B 927/B927M : 2017 Standard Specification for Brass Rod, Bar, and Shapes
ASTM B 152/B152M : 2019 Standard Specification for Copper Sheet, Strip, Plate, and Rolled Bar
ASTM B 371/B371M : 2019 Standard Specification for Copper-Zinc-Silicon Alloy Rod
ASTM B 608 : 2018 Standard Specification for Welded Copper-Alloy Pipe
ASTM B 101 : 2012 : R2019 Standard Specification for Lead-Coated Copper Sheet and Strip for Building Construction
ASTM B 101 : 2022 Standard Specification for Lead-Coated Copper Sheet and Strip for Building Construction
ASTM B 936 : 2023 Standard Specification for Copper-Chromium-Iron-Titanium Alloy Plate, Sheet, Strip and Rolled Bar
ASTM B 115 : 2024 Standard Specification for Electrolytic Copper Cathode
ASTM B 134/B134M : 2015 : R2021 Standard Specification for Brass Wire
ASTM B 130 : 2024 Standard Specification for Commercial Bronze Strip for Bullet Jackets
ASTM B 152/B152M : 2024 Standard Specification for Copper Sheet, Strip, Plate, and Rolled Bar
ASTM B 888/B888M : 2024 Standard Specification for Copper Alloy Strip for Use in Manufacture of Electrical Connectors or Spring Contacts
ASTM B 249/B249M : 2023 Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Rod, Bar, Shapes and Forgings
ASTM B 140/B140M : 2022 Standard Specification for Copper-Zinc-Lead (Red Brass or Hardware Bronze) Rod, Bar, and Shapes
ASTM B 129 : 2022 Standard Specification for Cartridge Brass Cartridge Case Cups
ASTM B 131 : 2022 Standard Specification for Copper Alloy Bullet Jacket Cups
ASTM B 248M : 2022 Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Plate, Sheet, Strip, and Rolled Bar (Metric)
ASTM B 283/B283M : 2024 Standard Specification for Copper and Copper-Alloy Die Forgings (Hot-Pressed)
ASTM B 99/B99M : 2015 : R2021 Standard Specification for Copper-Silicon Alloy Wire for General Applications
ASTM B 138/B138M : 2011 : R2024 Standard Specification for Manganese Bronze Rod, Bar, and Shapes
ASTM B 5 : 2022 Standard Specification for High Conductivity Tough-Pitch Copper Refinery Shapes
ASTM B 455/B455M : 2020 Standard Specification for Copper-Zinc-Lead Alloy (Leaded-Brass) Extruded Shapes
ASTM B 30 : 2023 Standard Specification for Copper Alloys in Ingot and Other Remelt Forms
ASTM F 3042 : 2013 : R2024 Standard Specification for Nonferrous Hex Socket, Slotted Headless, and Square Head Set Screws
ASTM B 103/B103M : 2023 Standard Specification for Phosphor Bronze Plate, Sheet, Strip, and Rolled Bar
ASTM B 508 : 2022 Standard Specification for Copper Alloy Strip for Flexible Metal Hose
ASTM B 16/B16M : 2024 Standard Specification for Free-Cutting Brass Rod, Bar and Shapes for Use in Screw Machines
ASTM B 950 : 2023 Standard Guide for Editorial Procedures and Form of Product Specifications for Copper and Copper Alloys
ASTM B 569 : 2024 Standard Specification for Brass Strip in Narrow Widths and Light Gage for Heat-Exchanger Tubing
ASTM B 36/B36M : 2023 Standard Specification for Brass Plate, Sheet, Strip, And Rolled Bar
ASTM B 929 : 2023 Standard Specification for Copper-Nickel-Tin Spinodal Alloy Rod and Bar
ASTM B 927/B927M : 2023 Standard Specification for Brass Rod, Bar, and Shapes
ASTM B 139/B139M : 2012 : R2024 Standard Specification for Phosphor Bronze Rod, Bar, and Shapes
ASTM F 468 : 2023 Standard Specification for Nonferrous Bolts, Hex Cap Screws, Socket Head Cap Screws, and Studs for General Use
ASTM B 111/B111M : 2024 Standard Specification for Copper and Copper-Alloy Seamless Condenser Tubes and Ferrule Stock
ASTM B 121/B121M : 2023 Standard Specification for Leaded Brass Plate, Sheet, Strip, and Rolled Bar
SAE AMS4554D Brass Tubing, Seamless, 66.5Cu - 33Zn - 0.45Pb, Annealed
ASTM B 644 : 2024 Standard Specification for Copper Alloy Addition Agents
ASTM B 206/B206M : 2012 : R2024 Standard Specification for Copper-Nickel-Zinc (Nickel Silver) Wire and Copper-Nickel Alloy Wire
ASTM B 967/B967M : 2018 : R2023 Standard Specification for Copper-Zinc-Tin-Bismuth Alloy Rod, Bar and Wire
ASTM B 372 : 2022 Standard Specification for Seamless Copper and Copper-Alloy Rectangular Waveguide Tube
ASTM B 359/B359M : 2023 Standard Specification for Copper and Copper-Alloy Seamless Condenser and Heat Exchanger Tubes With Integral Fins
ASTM B 882 : 2024 Standard Specification for Pre-Patinated Copper for Architectural Applications
ASTM B 467 : 2014 : R2022 Standard Specification for Welded Copper-Nickel Pipe
ASTM B 740 : 2021 Standard Specification for Copper-Nickel-Tin Spinodal Alloy Strip
ASTM B 248 : 2022 Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Plate, Sheet, Strip, and Rolled Bar
ASTM B 159/B159M : 2017 : R2024 Standard Specification for Phosphor Bronze Wire
SAE AMS4700F Copper Wire, Bare, High Purity

ASTM E 255 : 2023 Standard Practice for Sampling Copper and Copper Alloys for the Determination of Chemical Composition
ASTM E 29 : 2013 : R2019 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
ASTM E 135 : 2023 Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 135 : 2024 Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 29 : 2002 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
ASTM E 50 : 2017 : REDLINE Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials
ASTM E 135 : 2021 : REV A Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 255 : 1991 : R1997 Standard Practice for Sampling Copper and Copper Alloys for the Determination of Chemical Composition
ASTM E 60 : 2011 : R2016 Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry
ASTM E 135 : 2003 : REV B Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 1601 : 2019 Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method
ASTM E 135 : 2023 : REV A Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 1601 : 1998 Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method
ASTM E 1601 : 2010 Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method
ASTM E 1601 : 2012 : REDLINE Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method
ASTM E 135 : 2002 : REV A Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 135 : 2022 : REV B Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 1601 : 2012 Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method
ASTM E 50 : 2017 Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials
ASTM E 135 : 2022 : REV A Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 50 : 2024 Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials
ASTM E 135 : 2021 Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 135 : 2003 Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 135 : 2003 : REV C Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 60 : 2011 : R2022 : EDT 1 Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry
ASTM E 173 : 1993 Practice for Conducting Interlaboratory Studies of Methods for Chemical Analysis of Metals (Withdrawn 1997)
ASTM E 135 : 2022 Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 50 : 1982 : R1986 Standard Practices for Apparatus, Reagents, and Safety Precautions for Chemical Analysis of Metals
ASTM E 135 : 2020 : REV B Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
ASTM E 255 : 2007 : R2014 Standard Practice for Sampling Copper and Copper Alloys for the Determination of Chemical Composition (Withdrawn 2023)
ASTM E 29 : 2022 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications

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