ASTM E 478 : 2008 : R2017
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
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Standard Test Methods for Chemical Analysis of Copper Alloys
Hardcopy , PDF
01-11-2024
English
15-01-2017
CONTAINED IN VOL. 03.05, 2017 Defines the chemical analysis of copper alloys having chemical ranges.
Committee |
E 01
|
DevelopmentNote |
Supersedes ASTM E 36 (12/2001)
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DocumentType |
Test Method
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Pages |
22
|
ProductNote |
Reconfirmed 2017
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PublisherName |
American Society for Testing and Materials
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Status |
Superseded
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SupersededBy | |
Supersedes |
1.1These test methods cover the chemical analysis of copper alloys having chemical ranges within the following limits:2
Element | Composition, % |
Aluminum | 12.0 max |
Antimony | 1.0 max |
Arsenic | 1.0 max |
Cadmium | 1.5 max |
Cobalt | 1.0 max |
Copper | 40.0 min |
Iron | 6.0 max |
Lead | 27.0 max |
Manganese | 6.0 max |
Nickel | 50.0 max |
Phosphorus | 1.0 max |
Silicon | 5.0 max |
Sulfur | 0.1 max |
Tin | 20.0 max |
Zinc | 50.0 max |
1.2The test methods appear in the following order:
Sections | |
Aluminum by the Carbamate Extraction-Ethyl- | 71 – 78 |
Copper by the Combined Electrodeposition Gravimetric and Oxalyldihydrazide Spectrophotometric Test Method [50 %, minimum] | 10 – 18 |
Iron by the 1,10-Phenanthroline Spectrophotometric Test Method [0.003 % to 1.25 %] | 19 – 28 |
Lead by Atomic Absorption Spectrometry [0.002 % to 15 %] | 90 – 100 |
Lead by the Ethylenedinitrilotetraacetic Acid (EDTA) Titrimetric Test Method [2.0 % to 30.0 %] | 29 – 36 |
Nickel by the Dimethylglyoxime Extraction Sprectophotometric Test Method [0.03 % to 5.0 %] | 37 – 46 |
Nickel by the Dimethylglyoxime Gravimetric Test Method [4 % to 50 %] | 55 – 62 |
Silver in Silver-Bearing Copper by Atomic Absorption Spectrometry [0.01 % to 0.12 %] | 101 – 112 |
Tin by the Iodotimetric Titration Test Method [0.5 % to 20 %] | 63 – 70 |
Tin by the Phenylfluorone Spectrophotometric Test Method [0.01 % to 1.0 %] | 113 – 123 |
Zinc by Atomic Absorption Spectrometry [0.2 % to 2 %] | 79 – 89 |
Zinc by the Ethylenedinitrilotetraacetic Acid (EDTA) Titrimetric Test Method [2 % to 40 %] | 47 – 54 |
1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM B 171/B171M : 2018 | Standard Specification for Copper-Alloy Plate and Sheet for Pressure Vessels, Condensers, and Heat Exchangers |
ASTM B 1014 : 2020 | Standard Specification for Welded Copper and Copper Alloy Condenser and Heat Exchanger Tubes with a Textured Surface(s) |
ASTM B 187/B187M : 2020 | Standard Specification for Copper, Bus Bar, Rod, and Shapes and General Purpose Rod, Bar, and Shapes |
ASTM B 248M : 2017 | Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Plate, Sheet, Strip, and Rolled Bar (Metric) |
ASTM B 372 : 2017 | Standard Specification for Seamless Copper and Copper-Alloy Rectangular Waveguide Tube |
ASTM B 121/B121M : 2016 | Standard Specification for Leaded Brass Plate, Sheet, Strip, and Rolled Bar |
ASTM B 888/B888M : 2019 | Standard Specification for Copper Alloy Strip for Use in Manufacture of Electrical Connectors or Spring Contacts |
ASTM B 395/B395M : 2018 | Standard Specification for U-Bend Seamless Copper and Copper Alloy Heat Exchanger and Condenser Tubes |
ASTM B 411/B411M : 2014 : R2019 | Standard Specification for Copper-Nickel-Silicon Alloy Rod and Bar |
ASTM B 740 : 2009 : R2015 | Standard Specification for Copper-Nickel-Tin Spinodal Alloy Strip |
ASTM B 552 : 2019 | Standard Specification for Seamless and Welded Copper–Nickel Tubes for Water Desalting Plants |
ASTM B 706 : 2018 | Standard Specification for Seamless Copper Alloy (UNS No. C69100) Pipe and Tube |
ASTM B 453/B453M : 2019 | Standard Specification for Copper-Zinc-Lead Alloy (Leaded-Brass) Rod, Bar, and Shapes |
ASTM B 508 : 2016 | Standard Specification for Copper Alloy Strip for Flexible Metal Hose |
ASTM B 465 : 2020 | Standard Specification for Copper-Iron Alloy Plate, Sheet, Strip, and Rolled Bar |
ASTM B 100 : 2020 | Standard Specification for Wrought Copper-Alloy Bearing and Expansion Plates and Sheets for Bridge and Other Structural Use |
ASTM B 272 : 2012 : R2019 | Standard Specification for Copper Flat Products with Finished (Rolled or Drawn) Edges (Flat Wire and Strip) |
ASTM B 139/B139M : 2012 : R2017 | Standard Specification for Phosphor Bronze Rod, Bar, and Shapes |
ASTM B 206/B206M : 2012 : R2017 | Standard Specification for Copper-Nickel-Zinc (Nickel Silver) Wire and Copper-Nickel Alloy Wire |
ASTM B 248 : 2017 | Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Plate, Sheet, Strip, and Rolled Bar |
ASTM B 251/B251M : 2017 | Standard Specification for General Requirements for Wrought Seamless Copper and Copper-Alloy Tube |
ASTM B 747 : 2020 | Standard Specification for Copper-Zirconium Alloy Sheet and Strip |
ASTM F 468 : 2016 | Standard Specification for Nonferrous Bolts, Hex Cap Screws, Socket Head Cap Screws, and Studs for General Use |
ASTM B 694 : 2019 | Standard Specification for Copper, Copper-Alloy, Copper-Clad Bronze (CCB), Copper-Clad Stainless Steel (CCS), and Copper-Clad Alloy Steel (CAS) Sheet and Strip for Electrical Cable Shielding |
ASTM B 43 : 2020 | Standard Specification for Seamless Red Brass Pipe, Standard Sizes |
ASTM B 129 : 2017 | Standard Specification for Cartridge Brass Cartridge Case Cups |
ASTM B 592 : 2020 | Standard Specification for Copper-Zinc-Aluminum-Cobalt Alloy, Copper-Zinc-Tin-Iron Alloy Plate, Sheet, Strip, and Rolled Bar |
ASTM B 466/B466M : 2018 | Standard Specification for Seamless Copper-Nickel Pipe and Tube |
ASTM B 124/B124M : 2020 | Standard Specification for Copper and Copper Alloy Forging Rod, Bar, and Shapes |
ASTM B 543/B543M : 2018 | Standard Specification for Welded Copper and Copper-Alloy Heat Exchanger Tube |
ASTM B 569 : 2019 | Standard Specification for Brass Strip in Narrow Widths and Light Gage for Heat-Exchanger Tubing |
ASTM B 96/B96M : 2020 | Standard Specification for Copper-Silicon Alloy Plate, Sheet, Strip, and Rolled Bar for General Purposes and Pressure Vessels |
ASTM B 131 : 2017 | Standard Specification for Copper Alloy Bullet Jacket Cups |
ASTM B 250/B250M : 2019 | Standard Specification for General Requirements for Wrought Copper Alloy Wire |
ASTM F 467 : 2013 : R2018 | Standard Specification for Nonferrous Nuts for General Use |
ASTM B 591 : 2020 : REV A | Standard Specification for Copper-Zinc-Tin and Copper-Zinc-Tin-Iron-Nickel Alloys Plate, Sheet, Strip, and Rolled Bar |
ASTM B 882 : 2010 : R2018 | Standard Specification for Pre-Patinated Copper for Architectural Applications |
ASTM B 283/B283M : 2020 | Standard Specification for Copper and Copper-Alloy Die Forgings (Hot-Pressed) |
ASTM B 359/B359M : 2018 | Standard Specification for Copper and Copper-Alloy Seamless Condenser and Heat Exchanger Tubes With Integral Fins |
ASTM B 36/B36M : 2018 | Standard Specification for Brass Plate, Sheet, Strip, And Rolled Bar |
ASTM B 1018 : 2021 | Standard Specification for Seamless Copper-Iron Tube for Air Conditioning and Refrigeration Field Service |
ASTM B 956 : 2019 : EDT 1 | Standard Specification for Welded Copper and Copper-Alloy Condenser and Heat Exchanger Tubes with Integral Fins |
ASTM B 21/B21M : 2020 | Standard Specification for Naval Brass Rod, Bar, and Shapes |
ASTM B 919 : 2019 | Standard Specification for Welded Copper Heat Exchanger Tubes With Internal Enhancement |
ASTM B 301/B301M : 2013 : R2020 | Standard Specification for Free-Cutting Copper Rod, Bar, Wire, and Shapes |
ASTM F 3042 : 2013 : R2018 | Standard Specification for Nonferrous Hex Socket, Slotted Headless, and Square Head Set Screws |
ASTM B 967/B967M : 2018 | Standard Specification for Copper-Zinc-Tin-Bismuth Alloy Rod, Bar and Wire |
ASTM B 929 : 2017 | Standard Specification for Copper-Nickel-Tin Spinodal Alloy Rod and Bar |
ASTM B 140/B140M : 2012 : R2017 | Standard Specification for Copper-Zinc-Lead (Red Brass or Hardware Bronze) Rod, Bar, and Shapes |
ASTM B 315 : 2019 | Standard Specification for Seamless Copper Alloy Pipe and Tube |
ASTM B 824 : 2017 | Standard Specification for General Requirements for Copper Alloy Castings |
ASTM B 16/B16M : 2019 | Standard Specification for Free-Cutting Brass Rod, Bar and Shapes for Use in Screw Machines |
ASTM F 467M : 2006 : REV A : R2018 | Standard Specification for Nonferrous Nuts for General Use (Metric) |
ASTM B 122/B122M : 2020 | Standard Specification for Copper-Nickel-Tin Alloy, Copper-Nickel-Zinc Alloy (Nickel Silver), and Copper-Nickel Alloy Plate, Sheet, Strip, and Rolled Bar |
ASTM F 468M : 2006 : R2018 | Standard Specification for Nonferrous Bolts, Hex Cap Screws, and Studs for General Use (Metric) |
ASTM B 138/B138M : 2011 : R2017 | Standard Specification for Manganese Bronze Rod, Bar, and Shapes |
ASTM B 5 : 2016 | Standard Specification for High Conductivity Tough-Pitch Copper Refinery Shapes |
ASTM B 42 : 2020 | Standard Specification for Seamless Copper Pipe, Standard Sizes |
ASTM B 19 : 2020 | Standard Specification for Cartridge Brass Sheet, Strip, Plate, Bar, and Disks |
ASTM B 370 : 2012 : R2019 | Standard Specification for Copper Sheet and Strip for Building Construction |
ASTM B 111/B111M : 2018 : REV A | Standard Specification for Copper and Copper-Alloy Seamless Condenser Tubes and Ferrule Stock |
ASTM B 98/B98M : 2013 : R2019 | Standard Specification for Copper-Silicon Alloy Rod, Bar and Shapes |
ASTM B 151/B151M : 2020 | Standard Specification for Copper-Nickel-Zinc Alloy (Nickel Silver) and Copper-Nickel Rod and Bar |
ASTM B 103/B103M : 2019 | Standard Specification for Phosphor Bronze Plate, Sheet, Strip, and Rolled Bar |
ASTM B 1017 : 2021 | Standard Specification for Seamless Copper-Iron Tube for Air Conditioning and Refrigeration |
ASTM B 249/B249M : 2020 | Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Rod, Bar, Shapes and Forgings |
ASTM B 644 : 2011 : R2017 | Standard Specification for Copper Alloy Addition Agents |
ASTM B 30 : 2020 | Standard Specification for Copper Alloys in Ingot and Other Remelt Forms |
ASTM B 130 : 2019 | Standard Specification for Commercial Bronze Strip for Bullet Jackets |
ASTM B 49 : 2020 | Standard Specification for Copper Rod for Electrical Purposes |
ASTM B 950 : 2021 : EDT 1 | Standard Guide for Editorial Procedures and Form of Product Specifications for Copper and Copper Alloys |
ASTM B 936 : 2019 | Standard Specification for Copper-Chromium-Iron-Titanium Alloy Plate, Sheet, Strip and Rolled Bar |
ASTM B 467 : 2014 | Standard Specification for Welded Copper-Nickel Pipe |
ASTM B 150/B150M : 2019 | Standard Specification for Aluminum Bronze Rod, Bar, and Shapes |
ASTM B 159/B159M : 2017 | Standard Specification for Phosphor Bronze Wire |
ASTM B 974/B974M : 2016 : R2021 | Standard Specification for Free-Cutting Bismuth Brass Rod, Bar and Wire |
ASTM B 587 : 2019 | Standard Specification for Welded Brass Tube |
ASTM B 927/B927M : 2017 | Standard Specification for Brass Rod, Bar, and Shapes |
ASTM B 152/B152M : 2019 | Standard Specification for Copper Sheet, Strip, Plate, and Rolled Bar |
ASTM B 371/B371M : 2019 | Standard Specification for Copper-Zinc-Silicon Alloy Rod |
ASTM B 608 : 2018 | Standard Specification for Welded Copper-Alloy Pipe |
ASTM B 101 : 2012 : R2019 | Standard Specification for Lead-Coated Copper Sheet and Strip for Building Construction |
ASTM B 101 : 2022 | Standard Specification for Lead-Coated Copper Sheet and Strip for Building Construction |
ASTM B 936 : 2023 | Standard Specification for Copper-Chromium-Iron-Titanium Alloy Plate, Sheet, Strip and Rolled Bar |
ASTM B 115 : 2024 | Standard Specification for Electrolytic Copper Cathode |
ASTM B 134/B134M : 2015 : R2021 | Standard Specification for Brass Wire |
ASTM B 130 : 2024 | Standard Specification for Commercial Bronze Strip for Bullet Jackets |
ASTM B 152/B152M : 2024 | Standard Specification for Copper Sheet, Strip, Plate, and Rolled Bar |
ASTM B 888/B888M : 2024 | Standard Specification for Copper Alloy Strip for Use in Manufacture of Electrical Connectors or Spring Contacts |
ASTM B 249/B249M : 2023 | Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Rod, Bar, Shapes and Forgings |
ASTM B 140/B140M : 2022 | Standard Specification for Copper-Zinc-Lead (Red Brass or Hardware Bronze) Rod, Bar, and Shapes |
ASTM B 129 : 2022 | Standard Specification for Cartridge Brass Cartridge Case Cups |
ASTM B 131 : 2022 | Standard Specification for Copper Alloy Bullet Jacket Cups |
ASTM B 248M : 2022 | Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Plate, Sheet, Strip, and Rolled Bar (Metric) |
ASTM B 283/B283M : 2024 | Standard Specification for Copper and Copper-Alloy Die Forgings (Hot-Pressed) |
ASTM B 99/B99M : 2015 : R2021 | Standard Specification for Copper-Silicon Alloy Wire for General Applications |
ASTM B 138/B138M : 2011 : R2024 | Standard Specification for Manganese Bronze Rod, Bar, and Shapes |
ASTM B 5 : 2022 | Standard Specification for High Conductivity Tough-Pitch Copper Refinery Shapes |
ASTM B 455/B455M : 2020 | Standard Specification for Copper-Zinc-Lead Alloy (Leaded-Brass) Extruded Shapes |
ASTM B 30 : 2023 | Standard Specification for Copper Alloys in Ingot and Other Remelt Forms |
ASTM F 3042 : 2013 : R2024 | Standard Specification for Nonferrous Hex Socket, Slotted Headless, and Square Head Set Screws |
ASTM B 103/B103M : 2023 | Standard Specification for Phosphor Bronze Plate, Sheet, Strip, and Rolled Bar |
ASTM B 508 : 2022 | Standard Specification for Copper Alloy Strip for Flexible Metal Hose |
ASTM B 16/B16M : 2024 | Standard Specification for Free-Cutting Brass Rod, Bar and Shapes for Use in Screw Machines |
ASTM B 950 : 2023 | Standard Guide for Editorial Procedures and Form of Product Specifications for Copper and Copper Alloys |
ASTM B 569 : 2024 | Standard Specification for Brass Strip in Narrow Widths and Light Gage for Heat-Exchanger Tubing |
ASTM B 36/B36M : 2023 | Standard Specification for Brass Plate, Sheet, Strip, And Rolled Bar |
ASTM B 929 : 2023 | Standard Specification for Copper-Nickel-Tin Spinodal Alloy Rod and Bar |
ASTM B 927/B927M : 2023 | Standard Specification for Brass Rod, Bar, and Shapes |
ASTM B 139/B139M : 2012 : R2024 | Standard Specification for Phosphor Bronze Rod, Bar, and Shapes |
ASTM F 468 : 2023 | Standard Specification for Nonferrous Bolts, Hex Cap Screws, Socket Head Cap Screws, and Studs for General Use |
ASTM B 111/B111M : 2024 | Standard Specification for Copper and Copper-Alloy Seamless Condenser Tubes and Ferrule Stock |
ASTM B 121/B121M : 2023 | Standard Specification for Leaded Brass Plate, Sheet, Strip, and Rolled Bar |
SAE AMS4554D | Brass Tubing, Seamless, 66.5Cu - 33Zn - 0.45Pb, Annealed |
ASTM B 644 : 2024 | Standard Specification for Copper Alloy Addition Agents |
ASTM B 206/B206M : 2012 : R2024 | Standard Specification for Copper-Nickel-Zinc (Nickel Silver) Wire and Copper-Nickel Alloy Wire |
ASTM B 967/B967M : 2018 : R2023 | Standard Specification for Copper-Zinc-Tin-Bismuth Alloy Rod, Bar and Wire |
ASTM B 372 : 2022 | Standard Specification for Seamless Copper and Copper-Alloy Rectangular Waveguide Tube |
ASTM B 359/B359M : 2023 | Standard Specification for Copper and Copper-Alloy Seamless Condenser and Heat Exchanger Tubes With Integral Fins |
ASTM B 882 : 2024 | Standard Specification for Pre-Patinated Copper for Architectural Applications |
ASTM B 467 : 2014 : R2022 | Standard Specification for Welded Copper-Nickel Pipe |
ASTM B 740 : 2021 | Standard Specification for Copper-Nickel-Tin Spinodal Alloy Strip |
ASTM B 248 : 2022 | Standard Specification for General Requirements for Wrought Copper and Copper-Alloy Plate, Sheet, Strip, and Rolled Bar |
ASTM B 159/B159M : 2017 : R2024 | Standard Specification for Phosphor Bronze Wire |
SAE AMS4700F | Copper Wire, Bare, High Purity |
ASTM E 255 : 2023 | Standard Practice for Sampling Copper and Copper Alloys for the Determination of Chemical Composition |
ASTM E 29 : 2013 : R2019 | Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications |
ASTM E 135 : 2023 | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 135 : 2024 | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 29 : 2002 | Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications |
ASTM E 50 : 2017 : REDLINE | Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials |
ASTM E 135 : 2021 : REV A | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 255 : 1991 : R1997 | Standard Practice for Sampling Copper and Copper Alloys for the Determination of Chemical Composition |
ASTM E 60 : 2011 : R2016 | Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry |
ASTM E 135 : 2003 : REV B | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 1601 : 2019 | Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method |
ASTM E 135 : 2023 : REV A | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 1601 : 1998 | Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method |
ASTM E 1601 : 2010 | Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method |
ASTM E 1601 : 2012 : REDLINE | Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method |
ASTM E 135 : 2002 : REV A | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 135 : 2022 : REV B | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 1601 : 2012 | Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method |
ASTM E 50 : 2017 | Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials |
ASTM E 135 : 2022 : REV A | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 50 : 2024 | Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials |
ASTM E 135 : 2021 | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 135 : 2003 | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 135 : 2003 : REV C | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 60 : 2011 : R2022 : EDT 1 | Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry |
ASTM E 173 : 1993 | Practice for Conducting Interlaboratory Studies of Methods for Chemical Analysis of Metals (Withdrawn 1997) |
ASTM E 135 : 2022 | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 50 : 1982 : R1986 | Standard Practices for Apparatus, Reagents, and Safety Precautions for Chemical Analysis of Metals |
ASTM E 135 : 2020 : REV B | Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials |
ASTM E 255 : 2007 : R2014 | Standard Practice for Sampling Copper and Copper Alloys for the Determination of Chemical Composition (Withdrawn 2023) |
ASTM E 29 : 2022 | Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications |
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