• There are no items in your cart

ASTM E 537 : 2024

Current

Current

The latest, up-to-date edition.

Standard Test Method for Thermal Stability of Chemicals by Differential Scanning Calorimetry

Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

01-05-2024

€56.53
Excluding VAT

Committee
E 27
DocumentType
Test Method
Pages
9
PublisherName
American Society for Testing and Materials
Status
Current
Supersedes

1.1This test method describes the ascertainment of the presence of enthalpic changes in a test specimen, using minimum quantities of material, approximates the temperature at which these enthalpic changes occur and determines their enthalpies (heats) using differential scanning calorimetry or pressure differential scanning calorimetry.

Note 1:Caution should be used if trying to use pressure differential scanning calorimetry to understand the thermal stability of a liquid or a solid (if it melts during the test or produces gas or liquid products), because the headspace volume to sample size is relatively large, so that the vaporization effect could significantly skew the results. Typically, the pressure differential scanning calorimeter would be limited to situations where a pressurized reactive headspace is required (that is, reactivity of a liquid or solid sample with a gas, more detail in Appendix X1). Sealed high-pressure sample containers are still recommended for the evaluation of intrinsic thermal stability of liquid or solid samples, even within a pressure DSC instrument.

1.2This test method may be performed on solids, liquids, or slurries.

1.3This test method may be performed in a sealed high-pressure sample container with an inert or a reactive headspace atmosphere with an absolute pressure range from 100 Pa through 30 MPa and over a temperature range from 273 K to 800 K (0 °C to 527 °C).

1.4The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4.1Exceptions—Inch-pound units are provided as a courtesy to the user in X1.3.3, X1.4.1, and X1.4.2.

1.5This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific safety precautions are given in Section 8.

1.6This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM E 2041 : 2023 Standard Test Method for Estimating Kinetic Parameters by Differential Scanning Calorimeter Using the Borchardt and Daniels Method
ASTM E 1232 : 2007 : R2019 Standard Test Method for Temperature Limit of Flammability of Chemicals
ASTM E 1231 : 2024 Standard Practice for Calculation of Hazard Potential Figures of Merit for Thermally Unstable Materials
ASTM E 2046 : 2019 Standard Test Method for Reaction Induction Time by Thermal Analysis
ASTM E 1981 : 2022 Standard Guide for Assessing Thermal Stability of Materials by Methods of Accelerating Rate Calorimetry
ASTM E 487 : 2020 Standard Test Methods for Constant-Temperature Stability of Chemical Materials
ASTM E 3174 : 2022 Standard Practice for Determination of Kinetic Reaction Model Using Differential Scanning Calorimetry
ASTM E 2012 : 2006 : R2020 Standard Guide for the Preparation of a Binary Chemical Compatibility Chart
ASTM E 1591 : 2020 Standard Guide for Obtaining Data for Fire Growth Models
ASTM E 2550 : 2021 Standard Test Method for Thermal Stability by Thermogravimetry
ASTM E 2890 : 2021 Standard Test Method for Determination of Kinetic Parameters and Reaction Order for Thermally Unstable Materials by Differential Scanning Calorimetry Using the Kissinger and Farjas Methods
ASTM E 1445 : 2008 : R2023 Standard Terminology Relating to Hazard Potential of Chemicals
ASTM E 2744 : 2021 Standard Test Method for Pressure Calibration of Thermal Analyzers
ASTM E 2160 : 2023 Standard Test Method for Heat of Reaction of Thermally Reactive Materials by Differential Scanning Calorimetry
ASTM E 2070 : 2023 Standard Test Methods for Kinetic Parameters by Differential Scanning Calorimetry Using Isothermal Methods

Access your standards online with a subscription

Features

  • Simple online access to standards, technical information and regulations.

  • Critical updates of standards and customisable alerts and notifications.

  • Multi-user online standards collection: secure, flexible and cost effective.