BS EN ISO 15181-6:2014

Foreword
Introduction
1 Scope
2 Normative references
3 Principle
4 Supplementary information
5 Apparatus
6 Reagents and materials
7 Test samples
8 Preparation of calibration standards
9 Recovery and conversion check standards
10 Procedure
11 Calculation and expression of results
12 Validation of the method
13 Test report
Annex A (normative) - Supplementary information
Annex B (informative) - Additional information
        on tralopyril and BCCPCA
Bibliography

Describes a method for determining the amount of tralopyril that has been released from an antifouling paint into artificial seawater in accordance with the procedure given in ISO 15181-1.

This part of ISO 15181 specifies a method for determining the amount of tralopyril that has been released from an antifouling paint into artificial seawater in accordance with the procedure given in ISO 15181-1.

Tralopyril is unstable in water and degrades hydrolytically to form 3-bromo-5-(4-chlorophenyl)-4-cyano-1H-pyrrole-2-carboxylic acid (BCCPCA). This part of ISO 15181 specifies a method for accelerating the conversion of the released tralopyril into this degradation product by heat treatment and quantifying the concentration of the BCCPCA degradation product in the artificial seawater extract, and gives the final calculation for the release rate of tralopyril under the specified laboratory conditions.

This part of ISO 15181 is designed to allow the concurrent determination of tralopyril and other biocides that can be released by a given antifouling paint (for example, zineb) through the analysis of separate sub-samples of an artificial seawater extract generated in accordance with ISO 15181-1.

When used in conjunction with ISO 15181-1, the practical limits for quantifying release rates by this method are from 0,36 μg cm⁻² d⁻¹ to 270 μg cm⁻² d⁻¹. The quantitation of release rates lower than this range requires the use of an analytical method with a limit of quantitation for tralopyril in artificial seawater of less than 2 μg/l.