• BS EN ISO 15512:2016

    Superseded A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

    Plastics. Determination of water content

    Available format(s):  Hardcopy, PDF

    Superseded date:  21-06-2022

    Language(s):  English

    Published date:  30-11-2016

    Publisher:  British Standards Institution

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    Table of Contents - (Show below) - (Hide below)

    Foreword
    Introduction
    1 Scope
    2 Normative references
    3 Method A - Extraction with anhydrous methanol
    4 Method B1 - Water vaporization using a heating tube oven
    5 Method B2 - Water vaporization using a heated sample vial
    6 Method C - Manometric method
    7 Test report
    Annex A (informative) - Alternative sample preparation
            methods and titration methods
    Annex B (informative) - Selection of the optimum
            heating temperature for the water
            content determination
    Annex C (normative) - Determination of the water
            content of a water standard
    Bibliography

    Abstract - (Show below) - (Hide below)

    Describes methods for the determination of the water content of plastics in the form of powder, granules, and finished articles.

    Scope - (Show below) - (Hide below)

    1.1 This International Standard specifies methods for the determination of the water content of plastics in the form of powder, granules, and finished articles. These methods do not test for water absorption (kinetics and equilibrium) of plastics as measured by ISO62 . Method A is suitable for the determination of water content as low as 0,1%with an accuracy of 0,1%. Method B and Method C are suitable for the determination of water content as low as 0,01%with an accuracy of 0,01%. Water content is an important parameter for processing materials and has to remain below the level specified in the appropriate material standard. 1.2 Four alternative methods are specified in this International Standard. Method A is an extraction method using anhydrous methanol followed by a Karl Fischer titration of the extracted water. It can be used for all plastics and is applicable to granules smaller than 4mm×4mm×3mm. The method can also be used for, e.g. prepolymer materials in the form of a powder that are insoluble in methanol. Method B1 is a vaporization method using a tube oven. The water contained in the test portion is vaporized and carried to the titration cell by a dry air or nitrogen carrier gas, followed by a Karl Fischer titration of the collected water. It can be used for all plastics and is applicable to granules smaller than 4mm×4mm×3mm. Method B2 is a vaporization method using a heated sample vial. The water contained in the test portion is vaporized and carried to the titration cell by a dry air or nitrogen carrier gas, followed by a Karl Fischer titration of the collected water. It can be used for all plastics and is applicable to granules smaller than 4mm×4mm×3mm. Method C is a manometric method. The water content is determined from the increase in pressure, which results when the water is evaporated under a vacuum. This method is not applicable to plastic samples containing volatile compounds, other than water, in amounts contributing significantly to the vapour pressure at room temperature. Checks for the presence of large amounts of volatile compounds are to be carried out periodically, for example by gas chromatography. Such checks are particularly required for new types or grades of material.

    General Product Information - (Show below) - (Hide below)

    Committee PRI/21
    Development Note Renumbers and supersedes BS ISO 15512. Supersedes 96/125222 DC and BS EN ISO 960. (01/2004) Supersedes 07/30144836 DC. (07/2009) Supersedes 13/30266500 DC. (10/2014)
    Document Type Standard
    Publisher British Standards Institution
    Status Superseded
    Superseded By
    Supersedes

    Standards Referencing This Book - (Show below) - (Hide below)

    ISO 1628-1:2009 Plastics Determination of the viscosity of polymers in dilute solution using capillary viscometers Part 1: General principles
    ISO 1628-5:1998 Plastics — Determination of the viscosity of polymers in dilute solution using capillary viscometers — Part 5: Thermoplastic polyester (TP) homopolymers and copolymers
    ISO 1628-6:1990 Plastics — Determination of viscosity number and limiting viscosity number — Part 6: Methyl methacrylate polymers
    ISO 1628-3:2010 Plastics Determination of the viscosity of polymers in dilute solution using capillary viscometers Part 3: Polyethylenes and polypropylenes
    ISO 307:2007 Plastics Polyamides Determination of viscosity number
    ISO 62:2008 Plastics Determination of water absorption
    ISO 1628-2:1998 Plastics Determination of the viscosity of polymers in dilute solution using capillary viscometers Part 2: Poly(vinyl chloride) resins
    ISO 1628-4:1999 Plastics — Determination of the viscosity of polymers in dilute solution using capillary viscometers — Part 4: Polycarbonate (PC) moulding and extrusion materials
    ISO 760:1978 Determination of water Karl Fischer method (General method)
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