BS EN ISO 18857-2:2011

Foreword
Introduction
1 Scope
2 Normative references
3 Principle
4 Interferences
5 Reagents
6 Apparatus
7 Sampling and sample pretreatment
8 Procedure
9 Calibration and analysis of samples
10 Expression of results
11 Test report
Annex A (informative) - Example of a sorbent
Annex B (informative) - Suitable capillary columns
Annex C (informative) - Examples of chromatograms
Annex D (informative) - Performance data
Bibliography

Describes a gas chromatographic-mass spectrometric (GC-MS) determination of selected alkylphenols, their ethoxylates and bisphenol A in non-filtered samples of drinking, ground, surface, and waste waters following solid-phase extraction and derivatisation.

This part of ISO 18857 specifies a gas chromatographic-mass spectrometric (GC-MS) determination of selected alkylphenols, their ethoxylates and bisphenol A in non-filtered samples of drinking, ground, surface, and waste waters following solid-phase extraction and derivatisation.

The lower limit of the working range depends on the matrix, on the specific compound to be analysed and on the sensitivity of the mass spectrometric detection unit. The method is applicable in a working range from 0,005 μg/l to 0,2 μg/l for 4-(1,1,3,3-tetramethylbutyl)phenol (OP), and its mono- (OP₁EO) and diethoxylate (OP₂ EO), from 0,03 μg/l to 0,2 μg/l for 4-nonylphenol (mixture of isomers) (NP), and its mono- (NP₁ EO) and diethoxylate (NP₂EO), and from 0,05 μg/l to 0,2 μg/l for bisphenol A (BPA).

Depending on the matrix, the method is also applicable to waste water in a working range from 0,1 μg/l to 50 μg/l for OP, OP₁EO, OP₂ EO and BPA, and from 0,5 μg/l to 50 μg/l for NP, NP₁EO and NP₂EO. The working ranges are based on experimental work carried out in ruggedness testing. Water samples containing suspended matter at concentrations of more than 500 mg/l and waste water samples are extracted by passinga 100 ml sample through the cartridge.