CEN/TR 16269:2011

Foreword
Introduction
1 Scope
2 Terms and definitions
3 Symbols and abbreviations
4 Principle
5 Apparatus
6 Sampling, transport and storage
7 Analysis
8 Calculation of results
9 Quality control
10 Measurement uncertainty
11 Artefacts and interferences
12 Reporting of results
Annex A (informative) - Example of a closed vessel
        microwave digestion procedure to determine
        elements in the water-insoluble fraction
        of PM[2,5]
Annex B (informative) - Preparation of stock standard
        solution
Annex C (informative) - Uncertainty budget
Annex D (informative) - Data quality objectives
Annex E (informative) - Reagents
Bibliography

This CEN Technical Report specifies a method for the determination of the mass of water soluble NO3-, SO42-, Cl-, NH4+, Na+, K+, Mg2+, Ca2+ in PM2,5 samples which can be used to comply with Directive 2008/50/EC. This CEN Technical Report describes a measurement method which comprises sampling of anions and cations as part of the PM2,5 particulate phase, sample extraction and analysis of anions and cations by ion chromatography. Alternately, cations, excluding ammonium can be analysed by inductively coupled plasma optical emission spectrometry (ICP-OES).This CEN Technical Report may be used at rural background monitoring sites that are in accordance with the requirements of Directive 2008/50/EC. However, since this CEN Technical Report has not been validated in the field for these, or any other, monitoring site types, it may be considered equally applicable to all site types.NOTEThe detection limits described in this CEN technical report method will be limited by the noise level of the detector and the variability of the mass in laboratory blank filters rather than by the concentrations of anions and cations in ambient air.