• CEN/TS 15411:2006

    Withdrawn A Withdrawn Standard is one, which is removed from sale, and its unique number can no longer be used. The Standard can be withdrawn and not replaced, or it can be withdrawn and replaced by a Standard with a different number.

    Solid recovered fuels - Methods for the determination of the content of trace elements (As, Ba, Be, Cd, Co, Cr, Cu, Hg, Mo, Mn, Ni, Pb, Sb, Se, Tl, V and Zn)

    Available format(s): 

    Withdrawn date:  08-03-2023

    Language(s): 

    Published date:  27-09-2006

    Publisher:  Comite Europeen de Normalisation

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    Table of Contents - (Show below) - (Hide below)

    Foreword
    Introduction
    1 Scope
    2 Normative references
    3 Terms and definitions
    4 Safety remarks
    5 Principle
    6 Apparatus
    7 Reagents
    8 Procedure
    9 Digestion procedure
    10 Analysis of the digestion solutions
    11 Expression of results
    12 Quality control
    13 Performance characteristics
    14 Test report
    Annex A (normative) Guidelines - Characteristics of the
                        laboratory sample for chemical analysis
                        of SRF
    Bibliography

    Abstract - (Show below) - (Hide below)

    This Technical Specification specifies three methods of digestion for solid recovered fuels:a)microwave assisted digestion with hydrofluoric, nitric and hydrochloric acid mixture;b)hot water bath digestion of with hydrofluoric, nitric and hydrochloric acid mixture, after ashing of the SRFs sample;c)oven digestion with nitric, perchloric and hydrofluoric acid mixture.Instrumental determination of As, Ba, Be, Cd, Cr, Co, Cu, Pb, Mn, Mo, Ni, Sb, Se, Tl, V, Zn is performed by Inductively Coupled Plasma with optical or mass detection or graphite furnace Atomic Absorption Spectrometry. Hg can be analysed only after the microwave assisted procedure or, alternatively, by a direct analysis method.The effectiveness of the digestion can be verified by qualitative X-ray fluorescence (XRF) analysis on the remaining residue. If necessary an alternative digestion method (among those proposed) is used.Method a) is recommended for general use, but the amount of the test portion can be very low in case of high concentration of organic matter.Method b) is recommended for SRFs with high organic matter concentration that can be difficult to digest with the other methods. This method is not suitable for mercury.Method c) is recommended for SRFs samples for which the other methods leave a significant insoluble residue.

    General Product Information - (Show below) - (Hide below)

    Committee CEN/TC 343
    Document Type Technical Specification
    Publisher Comite Europeen de Normalisation
    Status Withdrawn
    Superseded By

    Standards Referenced By This Book - (Show below) - (Hide below)

    DD CEN/TS 15442:2006 Solid recovered fuels. Methods for sampling
    DD CEN/TS 15407:2006 Solid recovered fuels. Method for the determination of carbon (C), hydrogen (H) and nitrogen (N) content
    CEN/TS 15407:2006 Solid recovered fuels - Method for the determination of carbon (C), hydrogen (H) and nitrogen (N) content
    CEN/TS 15442:2006 Solid recovered fuels - Methods for sampling
    DIN EN 15442:2011-05 Solid recovered fuels - Methods for sampling; German version EN 15442:2011
    I.S. CEN TS 15407:2006 SOLID RECOVERED FUELS - METHOD FOR THE DETERMINATION OF CARBON (C), HYDROGEN (H) AND NITROGEN (N) CONTENT
    I.S. CEN TS 15442:2006 SOLID RECOVERED FUELS - METHODS FOR SAMPLING

    Standards Referencing This Book - (Show below) - (Hide below)

    CEN/TS 15357:2006 Solid recovered fuels - Terminology, definitions and descriptions
    CEN/TS 15413:2006 Solid recovered fuels - Methods for the preparation of the test sample from the laboratory sample
    ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
    EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
    EN 13656 : 2002 CHARACTERIZATION OF WASTE - MICROWAVE ASSISTED DIGESTION WITH HYDROFLUORIC (HF), NITRIC (HNO[3]), AND HYDROCHLORIC (HCL) ACID MIXTURE FOR SUBSEQUENT DETERMINATION OF ELEMENTS
    ISO 17294-2:2016 Water quality — Application of inductively coupled plasma mass spectrometry (ICP-MS) — Part 2: Determination of selected elements including uranium isotopes
    EN ISO 17294-2:2016 Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 2: Determination of selected elements including uranium isotopes (ISO 17294-2:2016)
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