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EN 13657:2002
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The latest, up-to-date edition.
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Characterization of waste - Digestion for subsequent determination of aqua regia soluble portion of elements
16-10-2002
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Safety remarks
5 Sample
5.1 Sample pre-treatment
5.2 Mass of test portion
6 Equipment
6.1 Closed vessel system
6.1.1 Microwave unit
6.1.2 Digestion vessels
6.2 Semi-open vessel system
6.2.1 Microwave unit
6.2.2 Digestion vessels
6.3 Apparatus for thermal heating digestion
6.3.1 Reaction vessels
6.3.2 Reflux condenser
6.3.3 Absorption vessel
6.3.4 Roughened glass beards
6.3.5 Temperature-controlled heating apparatus
6.4 General equipment
7 Reagents
8 Interferences and sources of error
8.1 General informations
8.2 Closed vessel system
8.3 Semi-open vessel system for microwave or thermal
heating digestion
9 Procedure
9.1 Blank test
9.2 Procedure for microwave assisted digestion in closed
vessels
9.3 Procedure for microwave assisted digestion in semi-open
vessels
9.3.1 Amount of samples
9.3.2 Digestion
9.3.3 Preparation of the solution for analysis
9.4 Procedure for thermal heating digestion in reflux systems
9.4.1 Amount of samples
9.4.2 Digestion
9.4.3 Preparation of the solution for analysis
10 Test report
Annex A (normative) Calibration of the power adjustment
Annex B (informative) Validation
B.1 Inter-laboratory study
B.2 Robustness study
Bibliography
This standard specifies methods of digestion with aqua regia. Solutions produced by the methods are suitable for analysis e.g. by atomic absorption spectrometry (FLAAS, HGAAS, CVAAS, GFAAS), inductively coupled plasma emission spectrometry (ICP-OES) and inductive coupled plasma mass spectrometry (ICP-MS). The method is applicable to the digestion of waste for example for the following elements: Al, Sb, As, B, Ba, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Hg, Mo, Ni, P, K, Se, Ag, S, Na, Sr, Sn, Te, Ti, Tl, V, Zn.
Committee |
CEN/TC 444
|
DocumentType |
Standard
|
PublisherName |
Comite Europeen de Normalisation
|
Status |
Current
|
Standards | Relationship |
NF EN 13657 : 2003 | Identical |
NBN EN 13657 : 2002 | Identical |
NEN EN 13657 : 2002 | Identical |
NS EN 13657 : 1ED 2002 | Identical |
I.S. EN 13657:2002 | Identical |
PN EN 13657 : 2006 | Identical |
UNE-EN 13657:2003 | Identical |
SN EN 13657 : 2002 | Identical |
UNI EN 13657 : 2004 | Identical |
BS EN 13657:2002 | Identical |
DIN EN 13657:2003-01 | Identical |
DIN EN 15309:2007-08 | Characterization of waste and soil - Determination of elemental composition by X-ray fluorescence |
BS EN 15309:2007 | Characterization of waste and soil. Determination of elemental composition by X-ray fluorescence |
13/30272291 DC : 0 | BS ISO 18227 - SOIL QUALITY - DETERMINATION OF ELEMENTAL COMPOSITION BY X-RAY FLUORESCENCE |
BS ISO 18227:2014 | Soil quality. Determination of elemental composition by X-ray fluorescence |
UNI EN 16174 : 2012 | SLUDGE, TREATED BIOWASTE AND SOIL - DIGESTION OF AQUA REGIA SOLUBLE FRACTIONS OF ELEMENTS |
EN 15410:2011 | Solid recovered fuels - Methods for the determination of the content of major elements (Al, Ca, Fe, K, Mg, Na, P, Si, Ti) |
BS EN 16174:2012 | Sludge, treated biowaste and soil. Digestion of aqua regia soluble fractions of elements |
DIN EN 15410:2011-11 | Solid recovered fuels - Method for the determination of the content of major elements (Al, Ca, Fe, K, Mg, Na, P, Si, Ti) |
UNI EN 16457 : 2014 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
DIN EN 15309 E : 2007 | CHARACTERIZATION OF WASTE AND SOIL - DETERMINATION OF ELEMENTAL COMPOSITION BY X-RAY FLUORESCENCE |
BS EN 15410:2011 | Solid recovered fuels. Methods for the determination of the content of major elements (Al, Ca, Fe, K, Mg, Na, P, Si, Ti) |
CLC/TS 50625-3-3 : 2017 | Collection, logistics & treatment requirements for WEEE - Part 3-3: Specification for de-pollution - WEEE containing CRTs and flat panel displays |
I.S. EN 16457:2014 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
I.S. EN 16174:2012 | SLUDGE, TREATED BIOWASTE AND SOIL - DIGESTION OF AQUA REGIA SOLUBLE FRACTIONS OF ELEMENTS |
17/30348303 DC : 0 | BS EN 17087 - CONSTRUCTION PRODUCTS - ASSESSMENT OF RELEASE OF DANGEROUS SUBSTANCES - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE FOR TESTING OF RELEASE AND ANALYSIS OF CONTENT |
UNE-EN 15002:2015 | Characterization of waste - Preparation of test portions from the laboratory sample |
I.S. EN 15002:2015 | CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE |
S.R. CLC/TS 50625-3-3:2017 | COLLECTION, LOGISTICS & TREATMENT REQUIREMENTS FOR WEEE - PART 3-3: SPECIFICATION FOR DE-POLLUTION - WEEE CONTAINING CRTS AND FLAT PANEL DISPLAYS |
10/30147493 DC : 0 | BS EN 16174 - SLUDGE, TREATED BIOWASTE AND SOIL - DIGESTION OF AQUA REGIA SOLUBLE FRACTIONS OF ELEMENTS |
UNE-EN 16457:2014 | Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report |
PD CLC/TS 50625-3-3:2017 | Collection, logistics & treatment requirements for WEEE Specification for de-pollution. WEEE containing CRTs and flat panel displays |
UNI EN 15410 : 2011 | SOLID RECOVERED FUELS - METHODS FOR THE DETERMINATION OF THE CONTENT OF MAJOR ELEMENTS (AL, CA, FE, K, MG, NA, P, SI, TI) |
12/30263896 DC : 0 | BS EN 16457 - CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
DIN EN 16174:2012-11 | Sludge, treated biowaste and soil - Digestion of aqua regia soluble fractions of elements |
I.S. EN 15410:2011 | SOLID RECOVERED FUELS - METHODS FOR THE DETERMINATION OF THE CONTENT OF MAJOR ELEMENTS (AL, CA, FE, K, MG, NA, P, SI, TI) |
DIN EN 16457:2014-07 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
I.S. EN 15309:2007 | CHARACTERIZATION OF WASTE AND SOIL - DETERMINATION OF ELEMENTAL COMPOSITION BY X-RAY FLUORESCENCE |
13/30291099 DC : 0 | BS EN 15002 - CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE |
DIN EN 15002:2015-07 | CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE |
EN 15002:2015 | Characterization of waste - Preparation of test portions from the laboratory sample |
EN 15309:2007 | Characterization of waste and soil - Determination of elemental composition by X-ray fluorescence |
EN 16457:2014 | Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report |
EN 16174:2012 | Sludge, treated biowaste and soil - Digestion of aqua regia soluble fractions of elements |
ISO 18227:2014 | Soil quality — Determination of elemental composition by X-ray fluorescence |
UNE-EN 15410:2012 | Solid recovered fuels - Methods for the determination of the content of major elements (Al, Ca, Fe, K, Mg, Na, P, Si, Ti) |
DIN EN 16457 E : 2014 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
BS EN 16457:2014 | Characterization of waste. Framework for the preparation and application of a testing programme. Objectives, planning and report |
04/30116791 DC : DRAFT JUL 2004 | BS EN 15002 - CHARACTERISATION OF WASTE - PREPARATION OF TEST PORTIONS FROM LABORATORY SAMPLE |
CEI CLC/TS 50625-3-3 : 1ED 2018 | COLLECTION, LOGISTICS & TREATMENT REQUIREMENTS FOR WEEE - PART 3-3: SPECIFICATION FOR DE-POLLUTION - WEEE CONTAINING CRTS AND FLAT PANEL DISPLAY |
DIN EN 15002 E : 2015 | CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE |
BS EN 15002:2015 | Characterization of waste. Preparation of test portions from the laboratory sample |
ISO 5725-1:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 1: General principles and definitions |
ISO 11466:1995 | Soil quality — Extraction of trace elements soluble in aqua regia |
EN 1483:2007 | Water quality - Determination of mercury - Method using atomic absorption spectrometry |
EN ISO 5961 : 1995 | WATER QUALITY - DETERMINATION OF CADMIUM BY ATOMIC ABSORPTION SPECTROMETRY (ISO 5961:1994) |
ISO 5961:1994 | Water quality Determination of cadmium by atomic absorption spectrometry |
ISO 5725-3:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 3: Intermediate measures of the precision of a standard measurement method |
ENV 12506 : DRAFT 2000 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF PH, AS, CD, CR (6), CU, NI, PB, ZN, CL[-], NO[2][-], SO[4][2-] |
ISO 5725-6:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values |
ISO 8288:1986 | Water quality — Determination of cobalt, nickel, copper, zinc, cadmium and lead — Flame atomic absorption spectrometric methods |
ISO 5725-4:1994 | Accuracy (trueness and precision) of measurement methods and results Part 4: Basic methods for the determination of the trueness of a standard measurement method |
ISO 11885:2007 | Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) |
EN 1233 : 1996 | WATER QUALITY - DETERMINATION OF CHROMIUM - ATOMIC ABSORPTION SPECTROMETRIC METHODS |
ISO 5725-2:1994 | Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method |
EN ISO 3696:1995 | Water for analytical laboratory use - Specification and test methods (ISO 3696:1987) |
EN ISO 11969:1996 | WATER QUALITY - DETERMINATION OF ARSENIC - ATOMIC ABSORPTION SPECTROMETRIC METHOD (HYDRIDE TECHNIQUE) |
ISO 5725-5:1998 | Accuracy (trueness and precision) of measurement methods and results — Part 5: Alternative methods for the determination of the precision of a standard measurement method |
EN 45001 : 1989 | GENERAL CRITERIA FOR THE OPERATION OF TESTING LABORATORIES |
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