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EN 13890:2009

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by

Workplace exposure - Procedures for measuring metals and metalloids in airborne particles - Requirements and test methods

Superseded date

24-02-2022

Superseded by

EN ISO 21832:2020

Published date

16-09-2009

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Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Principle
5 Requirements
6 Reagents and materials
7 Apparatus
8 Test methods
9 Test report
Annex A (informative) - Guidance on determination of
                        analytical recovery
Annex B (informative) - Estimation of uncertainty of
                        measurement
Annex C (informative) - Interpolation of standard
                        deviation
Annex D (informative) - Example of estimation of
                        expanded uncertainty
Bibliography

This European Standard specifies performance requirements and test methods for the evaluation of procedures for measuring metals and metalloids in airborne particles sampled onto a suitable collection substrate, e.g. a filter.This European Standard specifies a method for estimating the uncertainties associated with random and systematic errors and combining them to calculate the expanded uncertainty of the measuring procedure as a whole, as prescribed in EN 482.This European Standard is applicable to measuring procedures in which sampling and analysis is carried out in separate stages, but it does not specify performance requirements for collection, transport and storage of samples, since these are dealt with in EN 13205 and ISO 15767.This European Standard is not applicable to procedures for measuring metals or metalloids present as inorganic gases or vapours, e.g. mercury, arsenic (see EN 838 and EN 1076), or to procedures for measuring metals and metalloids in compounds that could be present as a particle/vapour mixture, e.g. arsenic trioxide.

Committee
CEN/TC 137
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Superseded
SupersededBy

Standards Relationship
BS EN 13890:2009 Identical
DIN EN 13890:2010-01 Identical
I.S. EN 13890:2009 Identical
UNI EN 13890 : 2009 Identical
NEN EN 13890 : 2009 Identical
NBN EN 13890 : 2009 Identical
UNE-EN 13890:2010 Identical
PN EN 13890 : 2010 Identical
SN EN 13890 : 2010 Identical
NS EN 13890 : 2009 Identical
NF EN 13890 : 2009 Identical

05/30133024 DC : DRAFT APR 2005 EN 482 - WORKPLACE ATMOSPHERES - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
UNI CEN ISO/TS 15011-6 : 2012 HEALTH AND SAFETY IN WELDING AND ALLIED PROCESSES - LABORATORY METHOD FOR SAMPLING FUME AND GASES - PART 6: PROCEDURE FOR QUANTITATIVE DETERMINATION OF FUME AND GASES FROM RESISTANCE SPOT WELDING
BS ISO 21438-3:2010 Workplace atmospheres. Determination of inorganic acids by ion chromatography Hydrofluoric acid and particulate fluorides
03/303614 DC : DRAFT MAR 2003 BS ISO 15202-3 - WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY - PART 3: ANALYSIS
10/30235960 DC : 0 BS EN 482 - WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
BS EN 13205-1:2014 Workplace exposure. Assessment of sampler performance for measurement of airborne particle concentrations General requirements
04/19981537 DC : DRAFT MARCH 2004 EN 14902 - AMBIENT AIR QUALITY - STANDARD METHOD FOR THE MEASUREMENT OF PB/CD/AS/NI IN AMBIENT AIR
ISO 21438-3:2010 Workplace atmospheres — Determination of inorganic acids by ion chromatography — Part 3: Hydrofluoric acid and particulate fluorides
ASTM D 4856 : 2011 Standard Test Method for Determination of Sulfuric Acid Mist in Workplace Atmospheres Collected on Mixed Cellulose Ester Filters (Ion Chromatographic Analysis)
I.S. EN 689:1995 WORKPLACE EXPOSURE - MEASUREMENT OF EXPOSURE BY INHALATION TO CHEMICAL AGENTS - STRATEGY FOR TESTING COMPLIANCE WITH OCCUPATIONAL EXPOSURE LIMIT VALUES
S.R. CEN/TR 17055:2017 WORKPLACE EXPOSURE - MEASUREMENT OF CHEMICAL AGENTS COMPLYING WITH THE REQUIREMENTS GIVEN IN EN 482 AND EITHER ONE OF EN 838, EN 1076, EN 13205, EN 13890 AND EN 13936 - CHOICE OF PROCEDURES
ISO 30011:2010 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma mass spectrometry
EN 13205-1:2014 Workplace exposure - Assessment of sampler performance for measurement of airborne particle concentrations - Part 1: General requirements
10/30213522 DC : DRAFT JUNE 2010 BS ISO 15202-2 - WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY - PART 2: SAMPLE PREPARATION
11/30228336 DC : 0 BS EN 13205 - WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS
UNE-EN 13936:2014 Workplace exposure - Procedures for measuring a chemical agent present as a mixture of airborne particles and vapour - Requirements and test methods
12/30259160 DC : DRAFT JULY 2012 BS EN 13936 - WORKPLACE EXPOSURE - PROCEDURES FOR MEASURING A CHEMICAL AGENT PRESENT AS A MIXTURE OF AIRBORNE PARTICLES AND VAPOUR - REQUIREMENTS AND TEST METHODS
I.S. CEN/TR 15230:2005 WORKPLACE ATMOSPHERES - GUIDANCE FOR SAMPLING OF INHALABLE, THORACIC AND RESPIRABLE AEROSOL FRACTIONS
UNI EN 13936 : 2014 WORKPLACE EXPOSURE - PROCEDURES FOR MEASURING A CHEMICAL AGENT PRESENT AS A MIXTURE OF AIRBORNE PARTICLES AND VAPOUR - REQUIREMENTS AND TEST METHODS
ISO 15202-2:2012 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Part 2: Sample preparation
BS EN 14530:2004 Workplace atmospheres. Determination of diesel particulate matter. General requirements
ISO/TS 15011-6:2012 Health and safety in welding and allied processes — Laboratory method for sampling fume and gases — Part 6: Procedure for quantitative determination of fume and gases from resistance spot welding
I.S. EN 482:2012 WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
I.S. EN 14042:2003 WORKPLACE ATMOSPHERES - GUIDE FOR THE APPLICATION AND USE OF PROCEDURES FOR THE ASSESSMENT OF EXPOSURE TO CHEMICAL AND BIOLOGICAL AGENTS
PD CEN ISO/TS 15011-6:2012 Health and safety in welding and allied processes. Laboratory method for sampling fume and gases Procedure for quantitative determination of fume from resistance spot welding
ISO 20581:2016 Workplace air General requirements for the performance of procedures for the measurement of chemical agents
10/30219214 DC : 0 BS ISO 15202-1 - WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY - PART 1: SAMPLING
BS ISO 20581:2016 Workplace air. General requirements for the performance of procedures for the measurement of chemical agents
14/30296739 DC : 0 BS EN 482:2012/A1 - WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
DIN EN 13205-1:2014-09 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
ISO 15202-1:2012 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Part 1: Sampling
CEN/TR 15230:2005 Workplace atmospheres - Guidance for sampling of inhalable, thoracic and respirable aerosol fractions
DIN EN 482:2015-12 Workplace exposure - General requirements for the performance of procedures for the measurement of chemical agents (includes Amendment A1:2015)
PREN 13205 : DRAFT 2010 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS
12/30259163 DC : 0 BS EN 13205-1 - WORKPLACE EXPOSURE - ASSESSMENT OF PERFORMANCE OF INSTRUMENTS FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
09/30165939 DC : 0 BS ISO 30011 - WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY
12/30258004 DC : 0 BS ISO 17091 - WORKPLACE AIR - DETERMINATION OF LITHIUM HYDROXIDE, SODIUM HYDROXIDE, POTASSIUM HYDROXIDE AND CALCIUM DIHYDROXIDE - METHOD BY MEASUREMENT OF CORRESPONDING CATIONS BY SUPPRESSED ION CHROMATOGRAPHY
I.S. EN 13205-1:2014 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
PD CEN/TR 15230:2005 Workplace atmospheres. Guidance for sampling of inhalable, thoracic and respirable aerosol fractions
ISO 15202-3:2004 Workplace air — Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry — Part 3: Analysis
PD CEN/TR 17055:2017 Workplace exposure. Measurement of chemical agents complying with the requirements given in EN 482 and either one of EN 838, EN 1076, EN 13205, EN 13890 and EN 13936. Choice of procedures
BS ISO 15202-3:2004 Workplace air. Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Analysis
NF ISO 15202-2 : 2012 WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY - PART 2: SAMPLE PREPARATION
UNI EN 13205-1 : 2014 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
I.S. EN 13936:2014 WORKPLACE EXPOSURE - PROCEDURES FOR MEASURING A CHEMICAL AGENT PRESENT AS A MIXTURE OF AIRBORNE PARTICLES AND VAPOUR - REQUIREMENTS AND TEST METHODS
BS ISO 15202-1:2012 Workplace air. Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Sampling
PREN 482 : DRAFT 2010 WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
ISO 17091:2013 Workplace air — Determination of lithium hydroxide, sodium hydroxide, potassium hydroxide and calcium dihydroxide — Method by measurement of corresponding cations by suppressed ion chromatography
ISO 17733:2015 Workplace air Determination of mercury and inorganic mercury compounds Method by cold-vapour atomic absorption spectrometry or atomic fluorescence spectrometry
BS EN 14042:2003 Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents
BS EN 482 : 2012 WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
UNE-EN 482:2012 Workplace exposure - General requirements for the performance of procedures for the measurement of chemical agents
EN 14530:2004 Workplace atmospheres - Determination of diesel particulate matter - General requirements
EN 14042:2003 Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents
EN 13936:2014 Workplace exposure - Procedures for measuring a chemical agent present as a mixture of airborne particles and vapour - Requirements and test methods
BS ISO 30011:2010 Workplace air. Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma mass spectrometry
DIN EN 13936:2014-04 Workplace exposure - Procedures for measuring a chemical agent present as a mixture of airborne particles and vapour - Requirements and test methods
BS ISO 17091:2013 Workplace air. Determination of lithium hydroxide, sodium hydroxide, potassium hydroxide and calcium dihydroxide. Method by measurement of corresponding cations by suppressed ion chromatography
BS ISO 15202-2:2012 Workplace air. Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Sample preparation
S.R. CEN ISO/TS 15011-6:2012 HEALTH AND SAFETY IN WELDING AND ALLIED PROCESSES - LABORATORY METHOD FOR SAMPLING FUME AND GASES - PART 6: PROCEDURE FOR QUANTITATIVE DETERMINATION OF FUME AND GASES FROM RESISTANCE SPOT WELDING (ISO/TS 15011-6:2012)
BS ISO 17733:2004 Workplace air. Determination of mercury and inorganic mercury compounds. Method by cold vapour atomic absorption spectrometry or atomic fluorescence spectrometry
15/30326686 DC : 0 BS ISO 20581 - WORKPLACE AIR - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
UNE-EN 13205-1:2015 Workplace exposure - Assessment of sampler performance for measurement of airborne particle concentrations - Part 1: General requirements
DIN EN 13205-1 E : 2014 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
EN 689:2018 Workplace exposure - Measurement of exposure by inhalation to chemical agents - Strategy for testing compliance with occupational exposure limit values
ASTM D 4856 : 2011 : R2016 Standard Test Method for Determination of Sulfuric Acid Mist in Workplace Atmospheres Collected on Mixed Cellulose Ester Filters (Ion Chromatographic Analysis)
EN 482:2012+A1:2015 Workplace exposure - General requirements for the performance of procedures for the measurement of chemical agents
CEN/TR 17055:2017 Workplace exposure - Measurement of chemical agents complying with the requirements given in EN 482 and either one of EN 838, EN 1076, EN 13205, EN 13890 and EN 13936 - Choice of procedures
DIN EN 14530:2004-06 Workplace atmospheres - Determination of diesel particulate matter - General requirements
DIN EN 14042:2003-07 WORKPLACE ATMOSPHERES - GUIDE FOR THE APPLICATION AND USE OF PROCEDURES FOR THE ASSESSMENT OF EXPOSURE TO CHEMICAL AND BIOLOGICAL AGENTS

EN 12919:1999 Workplace atmospheres - Pumps for the sampling of chemical agents with a volume flow rate of over 5 l/min - Requirements and test methods
EN 838:2010 Workplace exposure - Procedures for measuring gases and vapours using diffusive samplers - Requirements and test methods
EN 481:1993 Workplace atmospheres - Size fraction definitions for measurement of airborne particles
EN 1076:2009 Workplace exposure - Procedures for measuring gases and vapours using pumped samplers - Requirements and test methods
EN 482:2012+A1:2015 Workplace exposure - General requirements for the performance of procedures for the measurement of chemical agents
ISO 15202-1:2012 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Part 1: Sampling
CEN/TR 15230:2005 Workplace atmospheres - Guidance for sampling of inhalable, thoracic and respirable aerosol fractions
ISO/TS 21748:2004 Guidance for the use of repeatability, reproducibility and trueness estimates in measurement uncertainty estimation
EN 13205:2001 Workplace atmospheres - Assessment of performance of instruments for measurement of airborne particle concentrations
ENV 13005 : DRAFT 1999 GUIDE TO THE EXPRESSION OF UNCERTAINTY IN MEASUREMENT
ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
EN 1540:2011 Workplace exposure - Terminology
EN 1232:1997 Workplace atmospheres - Pumps for personal sampling of chemical agents - Requirements and test methods
ISO 15202-2:2012 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Part 2: Sample preparation
ISO 15767:2009 Workplace atmospheres Controlling and characterizing uncertainty in weighing collected aerosols
ISO 3534-1:2006 Statistics — Vocabulary and symbols — Part 1: General statistical terms and terms used in probability

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