• EN 13890:2009

    Superseded A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

    Workplace exposure - Procedures for measuring metals and metalloids in airborne particles - Requirements and test methods

    Available format(s): 

    Superseded date:  24-02-2022

    Language(s): 

    Published date:  16-09-2009

    Publisher:  Comite Europeen de Normalisation

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    Table of Contents - (Show below) - (Hide below)

    Foreword
    Introduction
    1 Scope
    2 Normative references
    3 Terms and definitions
    4 Principle
    5 Requirements
    6 Reagents and materials
    7 Apparatus
    8 Test methods
    9 Test report
    Annex A (informative) - Guidance on determination of
                            analytical recovery
    Annex B (informative) - Estimation of uncertainty of
                            measurement
    Annex C (informative) - Interpolation of standard
                            deviation
    Annex D (informative) - Example of estimation of
                            expanded uncertainty
    Bibliography

    Abstract - (Show below) - (Hide below)

    This European Standard specifies performance requirements and test methods for the evaluation of procedures for measuring metals and metalloids in airborne particles sampled onto a suitable collection substrate, e.g. a filter.This European Standard specifies a method for estimating the uncertainties associated with random and systematic errors and combining them to calculate the expanded uncertainty of the measuring procedure as a whole, as prescribed in EN 482.This European Standard is applicable to measuring procedures in which sampling and analysis is carried out in separate stages, but it does not specify performance requirements for collection, transport and storage of samples, since these are dealt with in EN 13205 and ISO 15767.This European Standard is not applicable to procedures for measuring metals or metalloids present as inorganic gases or vapours, e.g. mercury, arsenic (see EN 838 and EN 1076), or to procedures for measuring metals and metalloids in compounds that could be present as a particle/vapour mixture, e.g. arsenic trioxide.

    General Product Information - (Show below) - (Hide below)

    Committee CEN/TC 137
    Document Type Standard
    Publisher Comite Europeen de Normalisation
    Status Superseded
    Superseded By

    Standards Referenced By This Book - (Show below) - (Hide below)

    05/30133024 DC : DRAFT APR 2005 EN 482 - WORKPLACE ATMOSPHERES - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
    UNI CEN ISO/TS 15011-6 : 2012 HEALTH AND SAFETY IN WELDING AND ALLIED PROCESSES - LABORATORY METHOD FOR SAMPLING FUME AND GASES - PART 6: PROCEDURE FOR QUANTITATIVE DETERMINATION OF FUME AND GASES FROM RESISTANCE SPOT WELDING
    BS ISO 21438-3:2010 Workplace atmospheres. Determination of inorganic acids by ion chromatography Hydrofluoric acid and particulate fluorides
    03/303614 DC : DRAFT MAR 2003 BS ISO 15202-3 - WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY - PART 3: ANALYSIS
    10/30235960 DC : 0 BS EN 482 - WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
    BS EN 13205-1:2014 Workplace exposure. Assessment of sampler performance for measurement of airborne particle concentrations General requirements
    04/19981537 DC : DRAFT MARCH 2004 EN 14902 - AMBIENT AIR QUALITY - STANDARD METHOD FOR THE MEASUREMENT OF PB/CD/AS/NI IN AMBIENT AIR
    ISO 21438-3:2010 Workplace atmospheres — Determination of inorganic acids by ion chromatography — Part 3: Hydrofluoric acid and particulate fluorides
    ASTM D 4856 : 2011 Standard Test Method for Determination of Sulfuric Acid Mist in Workplace Atmospheres Collected on Mixed Cellulose Ester Filters (Ion Chromatographic Analysis)
    I.S. EN 689:1995 WORKPLACE EXPOSURE - MEASUREMENT OF EXPOSURE BY INHALATION TO CHEMICAL AGENTS - STRATEGY FOR TESTING COMPLIANCE WITH OCCUPATIONAL EXPOSURE LIMIT VALUES
    S.R. CEN/TR 17055:2017 WORKPLACE EXPOSURE - MEASUREMENT OF CHEMICAL AGENTS COMPLYING WITH THE REQUIREMENTS GIVEN IN EN 482 AND EITHER ONE OF EN 838, EN 1076, EN 13205, EN 13890 AND EN 13936 - CHOICE OF PROCEDURES
    ISO 30011:2010 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma mass spectrometry
    EN 13205-1:2014 Workplace exposure - Assessment of sampler performance for measurement of airborne particle concentrations - Part 1: General requirements
    10/30213522 DC : DRAFT JUNE 2010 BS ISO 15202-2 - WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY - PART 2: SAMPLE PREPARATION
    11/30228336 DC : 0 BS EN 13205 - WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS
    UNE-EN 13936:2014 Workplace exposure - Procedures for measuring a chemical agent present as a mixture of airborne particles and vapour - Requirements and test methods
    12/30259160 DC : DRAFT JULY 2012 BS EN 13936 - WORKPLACE EXPOSURE - PROCEDURES FOR MEASURING A CHEMICAL AGENT PRESENT AS A MIXTURE OF AIRBORNE PARTICLES AND VAPOUR - REQUIREMENTS AND TEST METHODS
    I.S. CEN/TR 15230:2005 WORKPLACE ATMOSPHERES - GUIDANCE FOR SAMPLING OF INHALABLE, THORACIC AND RESPIRABLE AEROSOL FRACTIONS
    UNI EN 13936 : 2014 WORKPLACE EXPOSURE - PROCEDURES FOR MEASURING A CHEMICAL AGENT PRESENT AS A MIXTURE OF AIRBORNE PARTICLES AND VAPOUR - REQUIREMENTS AND TEST METHODS
    ISO 15202-2:2012 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Part 2: Sample preparation
    BS EN 14530:2004 Workplace atmospheres. Determination of diesel particulate matter. General requirements
    ISO/TS 15011-6:2012 Health and safety in welding and allied processes — Laboratory method for sampling fume and gases — Part 6: Procedure for quantitative determination of fume and gases from resistance spot welding
    I.S. EN 482:2012 WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
    I.S. EN 14042:2003 WORKPLACE ATMOSPHERES - GUIDE FOR THE APPLICATION AND USE OF PROCEDURES FOR THE ASSESSMENT OF EXPOSURE TO CHEMICAL AND BIOLOGICAL AGENTS
    PD CEN ISO/TS 15011-6:2012 Health and safety in welding and allied processes. Laboratory method for sampling fume and gases Procedure for quantitative determination of fume from resistance spot welding
    ISO 20581:2016 Workplace air General requirements for the performance of procedures for the measurement of chemical agents
    10/30219214 DC : 0 BS ISO 15202-1 - WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY - PART 1: SAMPLING
    BS ISO 20581:2016 Workplace air. General requirements for the performance of procedures for the measurement of chemical agents
    14/30296739 DC : 0 BS EN 482:2012/A1 - WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
    DIN EN 13205-1:2014-09 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
    ISO 15202-1:2012 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Part 1: Sampling
    CEN/TR 15230:2005 Workplace atmospheres - Guidance for sampling of inhalable, thoracic and respirable aerosol fractions
    DIN EN 482:2015-12 Workplace exposure - General requirements for the performance of procedures for the measurement of chemical agents (includes Amendment A1:2015)
    PREN 13205 : DRAFT 2010 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS
    12/30259163 DC : 0 BS EN 13205-1 - WORKPLACE EXPOSURE - ASSESSMENT OF PERFORMANCE OF INSTRUMENTS FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
    09/30165939 DC : 0 BS ISO 30011 - WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY
    12/30258004 DC : 0 BS ISO 17091 - WORKPLACE AIR - DETERMINATION OF LITHIUM HYDROXIDE, SODIUM HYDROXIDE, POTASSIUM HYDROXIDE AND CALCIUM DIHYDROXIDE - METHOD BY MEASUREMENT OF CORRESPONDING CATIONS BY SUPPRESSED ION CHROMATOGRAPHY
    I.S. EN 13205-1:2014 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
    PD CEN/TR 15230:2005 Workplace atmospheres. Guidance for sampling of inhalable, thoracic and respirable aerosol fractions
    ISO 15202-3:2004 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Part 3: Analysis
    PD CEN/TR 17055:2017 Workplace exposure. Measurement of chemical agents complying with the requirements given in EN 482 and either one of EN 838, EN 1076, EN 13205, EN 13890 and EN 13936. Choice of procedures
    BS ISO 15202-3:2004 Workplace air. Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Analysis
    NF ISO 15202-2 : 2012 WORKPLACE AIR - DETERMINATION OF METALS AND METALLOIDS IN AIRBORNE PARTICULATE MATTER BY INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY - PART 2: SAMPLE PREPARATION
    UNI EN 13205-1 : 2014 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
    I.S. EN 13936:2014 WORKPLACE EXPOSURE - PROCEDURES FOR MEASURING A CHEMICAL AGENT PRESENT AS A MIXTURE OF AIRBORNE PARTICLES AND VAPOUR - REQUIREMENTS AND TEST METHODS
    BS ISO 15202-1:2012 Workplace air. Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Sampling
    PREN 482 : DRAFT 2010 WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
    ISO 17091:2013 Workplace air — Determination of lithium hydroxide, sodium hydroxide, potassium hydroxide and calcium dihydroxide — Method by measurement of corresponding cations by suppressed ion chromatography
    ISO 17733:2015 Workplace air Determination of mercury and inorganic mercury compounds Method by cold-vapour atomic absorption spectrometry or atomic fluorescence spectrometry
    DIN EN 14530 E : 2004 WORKPLACE ATMOSPHERES - DETERMINATION OF DIESEL PARTICULATE MATTER - GENERAL REQUIREMENTS
    BS EN 14042:2003 Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents
    BS EN 482 : 2012 WORKPLACE EXPOSURE - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
    UNE-EN 482:2012 Workplace exposure - General requirements for the performance of procedures for the measurement of chemical agents
    EN 14530:2004 Workplace atmospheres - Determination of diesel particulate matter - General requirements
    EN 14042:2003 Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents
    EN 13936:2014 Workplace exposure - Procedures for measuring a chemical agent present as a mixture of airborne particles and vapour - Requirements and test methods
    DIN EN 13936 E : 2014 WORKPLACE EXPOSURE - PROCEDURES FOR MEASURING A CHEMICAL AGENT PRESENT AS A MIXTURE OF AIRBORNE PARTICLES AND VAPOUR - REQUIREMENTS AND TEST METHODS
    BS ISO 30011:2010 Workplace air. Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma mass spectrometry
    DIN EN 13936:2014-04 Workplace exposure - Procedures for measuring a chemical agent present as a mixture of airborne particles and vapour - Requirements and test methods
    BS ISO 17091:2013 Workplace air. Determination of lithium hydroxide, sodium hydroxide, potassium hydroxide and calcium dihydroxide. Method by measurement of corresponding cations by suppressed ion chromatography
    BS ISO 15202-2:2012 Workplace air. Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Sample preparation
    S.R. CEN ISO/TS 15011-6:2012 HEALTH AND SAFETY IN WELDING AND ALLIED PROCESSES - LABORATORY METHOD FOR SAMPLING FUME AND GASES - PART 6: PROCEDURE FOR QUANTITATIVE DETERMINATION OF FUME AND GASES FROM RESISTANCE SPOT WELDING (ISO/TS 15011-6:2012)
    BS ISO 17733:2004 Workplace air. Determination of mercury and inorganic mercury compounds. Method by cold vapour atomic absorption spectrometry or atomic fluorescence spectrometry
    15/30326686 DC : 0 BS ISO 20581 - WORKPLACE AIR - GENERAL REQUIREMENTS FOR THE PERFORMANCE OF PROCEDURES FOR THE MEASUREMENT OF CHEMICAL AGENTS
    UNE-EN 13205-1:2015 Workplace exposure - Assessment of sampler performance for measurement of airborne particle concentrations - Part 1: General requirements
    DIN EN 13205-1 E : 2014 WORKPLACE EXPOSURE - ASSESSMENT OF SAMPLER PERFORMANCE FOR MEASUREMENT OF AIRBORNE PARTICLE CONCENTRATIONS - PART 1: GENERAL REQUIREMENTS
    EN 689:2018 Workplace exposure - Measurement of exposure by inhalation to chemical agents - Strategy for testing compliance with occupational exposure limit values
    ASTM D 4856 : 2011 : R2016 Standard Test Method for Determination of Sulfuric Acid Mist in Workplace Atmospheres Collected on Mixed Cellulose Ester Filters (Ion Chromatographic Analysis)
    EN 482:2012+A1:2015 Workplace exposure - General requirements for the performance of procedures for the measurement of chemical agents
    CEN ISO/TS 15011-6:2012/AC:2012 Health and safety in welding and allied processes - Laboratory method for sampling fume and gases - Part 6: Procedure for quantitative determination of fume and gases from resistance spot welding - Technical Corrigendum 1 (ISO/TS 15011-6:2012/Cor 1:2012)
    CEN/TR 17055:2017 Workplace exposure - Measurement of chemical agents complying with the requirements given in EN 482 and either one of EN 838, EN 1076, EN 13205, EN 13890 and EN 13936 - Choice of procedures
    DIN EN 14530:2004-06 Workplace atmospheres - Determination of diesel particulate matter - General requirements
    DIN EN 14042:2003-07 WORKPLACE ATMOSPHERES - GUIDE FOR THE APPLICATION AND USE OF PROCEDURES FOR THE ASSESSMENT OF EXPOSURE TO CHEMICAL AND BIOLOGICAL AGENTS

    Standards Referencing This Book - (Show below) - (Hide below)

    EN 12919:1999 Workplace atmospheres - Pumps for the sampling of chemical agents with a volume flow rate of over 5 l/min - Requirements and test methods
    EN 838:2010 Workplace exposure - Procedures for measuring gases and vapours using diffusive samplers - Requirements and test methods
    EN 481:1993 Workplace atmospheres - Size fraction definitions for measurement of airborne particles
    EN 1076:2009 Workplace exposure - Procedures for measuring gases and vapours using pumped samplers - Requirements and test methods
    EN 482:2012+A1:2015 Workplace exposure - General requirements for the performance of procedures for the measurement of chemical agents
    ISO 15202-1:2012 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Part 1: Sampling
    CEN/TR 15230:2005 Workplace atmospheres - Guidance for sampling of inhalable, thoracic and respirable aerosol fractions
    ISO/TS 21748:2004 Guidance for the use of repeatability, reproducibility and trueness estimates in measurement uncertainty estimation
    EN 13205:2001 Workplace atmospheres - Assessment of performance of instruments for measurement of airborne particle concentrations
    ENV 13005 : DRAFT 1999 GUIDE TO THE EXPRESSION OF UNCERTAINTY IN MEASUREMENT
    ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
    EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
    EN 1540:2011 Workplace exposure - Terminology
    EN 1232:1997 Workplace atmospheres - Pumps for personal sampling of chemical agents - Requirements and test methods
    ISO 15202-2:2012 Workplace air Determination of metals and metalloids in airborne particulate matter by inductively coupled plasma atomic emission spectrometry Part 2: Sample preparation
    ISO 15767:2009 Workplace atmospheres Controlling and characterizing uncertainty in weighing collected aerosols
    ISO 3534-1:2006 Statistics — Vocabulary and symbols — Part 1: General statistical terms and terms used in probability
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