UNE-EN 16190:2018

This draft European Standard specifies a method for quantitative determination of 17 2,3,7,8-chlorine substituted dibenzo-p-dioxins and dibenzofurans and dioxin-like polychlorinated biphenyls in sludge, treated biowaste and soil using liquid column chromatographic clean-up methods and GC/HRMS.

The analytes to be determined with this European Standard are listed in Table 1.

Table 1 Analytes and their abbreviations

Substance

Abbreviation

Tetrachlorodibenzo-p-dioxin

TCDD

Pentachlorodibenzo-p-dioxin

PeCDD

Hexachlorodibenzo-p-dioxin

HxCDD

Heptachlorodibenzo-p-dioxin

HpCDD

Octachlorodibenzo-p-dioxin

OCDD

Tetrachlorodibenzofuran

TCDF

Pentachlorodibenzofuran

PeCDF

Hexachlorodibenzofuran

HxCDF

Heptachlorodibenzofuran

HpCDF

Octachlorodibenzofuran

OCDF

Polychlorinated biphenyl

PCB

Trichlorobiphenyl

TCB

Tetrachlorobiphenyl

TeCB

Pentachlorobiphenyl

PeCB

Hexachlorobiphenyl

HxCB

Heptachlorobiphenyl

HpCB

Decachlorobiphenyl

DecaCB

The limit of detection depends on the kind of sample, the congener, the equipment used and the quality of chemicals used for extraction and clean-up. Under the conditions specified in this European Standard, limits of detection better than 1 ng/kg (expressed as dry matter) can be achieved.

This method is performance based . It is allowed to modify the method if all performance criteria given in this method are met.

NOTE In principle this method can also be applied for sediments, mineral wastes and for vegetation. It is the responsibility of the user of this European Standard to validate the application for these matrices. For measurement in complex matrices like fly ashes adsorbed on vegetation it can be necessary to further improve the clean-up. This can also apply to sediments and mineral wastes.