UNE-EN ISO 22854:2025

This document specifies the gas chromatographic (GC) method for the determination of saturated, olefinic and aromatic hydrocarbons in automotive motor gasoline, small engine petrol and etanol (E85) automotive fuel. Additionally, the benzene and toluene content, oxygenated compounds and the total oxygen content can be determined.

NOTE 1 For the purposes of this document, the terms % (m/m) and % (V/V) are used to represent respectively the mass fraction, w, and the volume fraction, Æ.

This document defines three procedures, A, B and C. The application ranges are given in Table 1.

NOTE 2 Procedure A has been assessed for total oxygenates content, and later for individual oxygenates. The ranges given are considered to apply to individual oxygenated compounds or the total group of (unidentified, not further precised) oxygenates.

Although specifically developed for the analysis of automotive motor gasoline that contains oxygenates, this test method can also be applied to other hydrocarbon streams having similar boiling ranges, such as naphthas and reformates.

NOTE 3 For Procedure A, applicability of this document has specifically been verified for the determination of n-propanol, acetone, and di-isopropyl ether (DIPE). However, no precision data have been determined for these

compounds.

Procedure B describes the analysis of oxygenated groups (ethanol, methanol, ethers, C3 C5 alcohols) in ethanol (E85) automotive fuel containing ethanol between 50 % (V/V) and 85 % (V/V). The gasoline is diluted with an oxygenate-free component to lower the ethanol content to a value below 20 % (V/V) before the analysis by GC.

The sample can be fully analysed including hydrocarbons. Precision data for the diluted sample are only available for the oxygenated groups.

NOTE 4 An overlap between C9 and C10 aromatics can occur. However, the total is accurate. Isopropyl benzene is resolved from the C8 aromatics and is included with the other C9 aromatics.

Procedure C describes the analysis of small engine petrol fuel containing low contents of aromatics and olefins.