ASTM D 1159 : 2023
Current
The latest, up-to-date edition.
Standard Test Method for Bromine Numbers of Petroleum Distillates and Commercial Aliphatic Olefins by Electrometric Titration
Hardcopy , PDF
English
08-11-2023
Committee |
D 02
|
DocumentType |
Test Method
|
Pages |
10
|
PublisherName |
American Society for Testing and Materials
|
Status |
Current
|
Supersedes |
1.1This test method3 covers the determination of the bromine number of the following materials:
1.1.1Petroleum distillates that are substantially free of material lighter than isobutane and that have 90 % distillation points (by Test Method D86) under 327 °C (626 °F). This test method is generally applicable to gasoline (including leaded, unleaded, and oxygenated fuels), kerosine, and distillates in the gas oil range that fall in the following limits:
90 % Distillation Point, °C (°F) | Bromine Number, max3 |
Under 205 (400) | 175 |
205 to 327 (400 to 626) | 10 |
1.1.2Commercial olefins that are essentially mixtures of aliphatic mono-olefins and that fall within the range of 95 to 165 bromine number (see Note 1). This test method has been found suitable for such materials as commercial propylene trimer and tetramer, butene dimer, and mixed nonenes, octenes, and heptenes. This test method is not satisfactory for normal alpha-olefins.
Note 1:These limits are imposed since the precision of this test method has been determined only up to or within the range of these bromine numbers.
1.2The magnitude of the bromine number is an indication of the quantity of bromine-reactive constituents, not an identification of constituents; therefore, its application as a measure of olefinic unsaturation should not be undertaken without the study given in Annex A1.
1.3For petroleum hydrocarbon mixtures of bromine number less than 1.0, a more precise measure for bromine-reactive constituents can be obtained by using Test Method D2710. If the bromine number is less than 0.5, then Test Method D2710 or the comparable bromine index methods for industrial aromatic hydrocarbons, Test Methods D1492 or D5776 must be used in accordance with their respective scopes. The practice of using a factor of 1000 to convert bromine number to bromine index is not applicable for these lower values of bromine number.
1.4The values stated in SI units are to be regarded as the standard.
1.4.1Exception—The values given in parentheses are for information only.
1.5This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Sections 7, 8, and 9.
1.6This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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