• ASTM D 2036 : 2009 : R2015

    Superseded A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

    Standard Test Methods for Cyanides in Water

    Available format(s):  Hardcopy, PDF

    Superseded date:  18-06-2022

    Language(s):  English

    Published date:  11-08-2015

    Publisher:  American Society for Testing and Materials

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    Abstract - (Show below) - (Hide below)

    These test methods cover the determination of cyanides in water.

    Scope - (Show below) - (Hide below)

    1.1These test methods cover the determination of cyanides in water. The following test methods are included:

    Sections

    Test Method A
     Total Cyanides after Distillation

    12 – 18

    Test Method B
     Cyanides Amenable to Chlorination2
     by Difference

    19 – 25

    Test Method C
     Weak Acid Dissociable Cyanides

    26 – 32

    Test Method D
     Cyanides Amenable to Chlorination without
     Distillation (Short-Cut Method)

    33 – 39

    1.2Cyanogen halides may be determined separately.

    Note 1:Cyanogen chloride is the most common of the cyanogen halide complexes as it is a reaction product and is usually present when chlorinating cyanide-containing industrial waste water. For the presence or absence of CNCl, the spot test method given in Annex A1 can be used.

    1.3These test methods do not distinguish between cyanide ions and metallocyanide compounds and complexes. Furthermore, they do not detect the cyanates. Cyanates can be determined using ion chromatography without digestion.

    Note 2:The cyanate complexes are decomposed when the sample is acidified in the distillation procedure.

    1.4The cyanide in cyanocomplexes of gold, platinum, cobalt and some other transition metals is not completely recovered by these test methods. Refer to Test Method D6994 for the determination of cyanometal complexes.

    1.5Cyanide from only a few organic cyanides are recovered, and those only to a minor extent.

    1.6Part or all of these test methods have been used successfully with reagent water and various waste waters. It is the user's responsibility to assure the validity of the test method for the water matrix being tested.

    1.7The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.8This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in 5.1, 8.8, 8.18, Section 9, 11.3, and 16.1.9.

    General Product Information - (Show below) - (Hide below)

    Committee D 19
    Document Type Test Method
    Product Note Reconfirmed 2015
    Publisher American Society for Testing and Materials
    Status Superseded
    Superseded By
    Supersedes

    Standards Referenced By This Book - (Show below) - (Hide below)

    ASTM D 7365 : 2009 : REV A : R2022 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
    ASTM D 7572 : 2015 : R2022 Standard Guide for Recovery of Aqueous Cyanides by Extraction from Mine Rock and Soil
    ASTM D 3694 : 1996 : R2017 Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents
    ASTM D 7572 : 2015 Standard Guide for Recovery of Aqueous Cyanides by Extraction from Mine Rock and Soil
    ASTM D 4193 : 2008 : R2013 : EDT 1 Standard Test Method for Thiocyanate in Water
    ASTM D 7365 : 2009 : REV A : R2015 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
    ASTM D 7284 : 2013 : R2017 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
    ASTM E 800 : 2014 Standard Guide for Measurement of Gases Present or Generated During Fires
    ASTM D 6888 : 2016 Standard Test Method for Available Cyanides with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
    ASTM D 4165 : 2006 : R2012 Standard Test Method for Cyanogen Chloride in Water
    ASTM D 7511 : 2012 : R2017 : EDT 1 Standard Test Method for Total Cyanide by Segmented Flow Injection Analysis, In-Line Ultraviolet Digestion and Amperometric Detection
    ASTM D 7237 : 2018 Standard Test Method for Free Cyanide and Aquatic Free Cyanide with Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
    ASTM D 7295 : 2018 Standard Practice for Sampling Combustion Effluents and Other Stationary Sources for the Subsequent Determination of Hydrogen Cyanide
    ASTM D 7728 : 2018 Standard Guide for Selection of ASTM Analytical Methods for Implementation of International Cyanide Management Code Guidance
    ASTM D 4193 : 2008 : R2020 : EDT 1 Standard Test Method for Thiocyanate in Water
    ASTM D 4165 : 2006 : R2020 : EDT 1 Standard Test Method for Cyanogen Chloride in Water
    ASTM E 800 : 2020 Standard Guide for Measurement of Gases Present or Generated During Fires
    ASTM D 7284 : 2020 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection

    Standards Referencing This Book - (Show below) - (Hide below)

    ASTM D 6994 : 2010 Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection
    ASTM D 7365 : 2007 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
    ASTM D 1129 : 2013 : REDLINE Standard Terminology Relating to Water
    ASTM D 1129 : 2003 Standard Terminology Relating to Water
    ASTM D 2777 : 2013 : REDLINE Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 7365 : 2009 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
    ASTM D 5788 : 1995 : R2001 Standard Guide for Spiking Organics into Aqueous Samples
    ASTM D 5788 : 1995 : R2017 Standard Guide for Spiking Organics into Aqueous Samples
    ASTM D 1129 : 2013 Standard Terminology Relating to Water
    ASTM D 1129 : 2013 : R2020 Standard Terminology Relating to Water
    ASTM D 5847 : 1999 : REV A : EDT 1 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 6888 : 2003 Standard Test Method for Available Cyanide with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
    ASTM D 6696 : 2016 : REDLINE Standard Guide for Understanding Cyanide Species
    ASTM D 7284 : 2013 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
    ASTM D 2777 : 2012 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 6994 : 2004 Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection
    ASTM D 6696 : 2016 Standard Guide for Understanding Cyanide Species
    ASTM D 1193 : 1977 : R1983 : EDT 1 Standard Specification for Reagent Water
    ASTM D 5847 : 2002 : R2007 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 5788 : 1995 Standard Guide for Spiking Organics into Aqueous Samples
    ASTM D 6888 : 2016 Standard Test Method for Available Cyanides with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
    ASTM D 6696 : 2010 Standard Guide for Understanding Cyanide Species
    ASTM D 1129 : 2006 Standard Terminology Relating to Water
    ASTM D 6696 : 2014 Standard Guide for Understanding Cyanide Species
    ASTM D 2777 : 2003 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
    ASTM D 6994 : 2015 : REDLINE Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection
    ASTM D 2777 : 2013 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM E 275 : 2008 Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers
    ASTM E 275 : 2008 : R2013 Standard Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers
    ASTM D 7365 : 2009 : REV A Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
    ASTM E 275 : 2008 : R2022 Standard Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers
    ASTM D 6696 : 2005 : EDT 1 Standard Guide for Understanding Cyanide Species
    ASTM D 5847 : 2002 : R2012 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 2777 : 1998 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
    ASTM D 1129 : 1999 : REV A Standard Terminology Relating to Water
    ASTM D 6888 : 2009 Standard Test Method for Available Cyanide with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
    ASTM D 1129 : 2006 : REV A Standard Terminology Relating to Water
    ASTM D 1193 : 2006 : R2011 Standard Specification for Reagent Water
    ASTM D 6888 : 2004 Standard Test Method for Available Cyanide with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
    ASTM D 5847 : 2002 : R2020 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 1129 : 2003 : REV A Standard Terminology Relating to Water
    ASTM D 1129 : 2002 Standard Terminology Relating to Water
    ASTM D 6696 : 2005 Standard Guide for Understanding Cyanide Species
    ASTM D 7284 : 2008 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
    ASTM D 7284 : 2008 : EDT 1 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
    ASTM D 5788 : 1995 : R2005 Standard Guide for Spiking Organics into Aqueous Samples
    ASTM D 5788 : 1995 : R2011 Standard Guide for Spiking Organics into Aqueous Samples
    ASTM D 1193 : 1991 Standard Specification for Reagent Water
    ASTM D 1129 : 2004 Standard Terminology Relating to Water
    ASTM D 7284 : 2013 : R2017 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
    ASTM D 2777 : 2008 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 2777 : 2006 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 6696 : 2001 Standard Guide for Understanding Cyanide Species
    ASTM D 1129 : 2002 : REV A Standard Terminology Relating to Water
    ASTM D 5847 : 2002 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 7365 : 2009 : REV A : R2015 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
    ASTM D 1193 : 1970 Standard Specification For Reagent Water
    ASTM D 1193 : 2006 Standard Specification for Reagent Water
    ASTM D 1193 : 1999 Standard Specification for Reagent Water
    ASTM D 1129 : 2010 Standard Terminology Relating to Water
    ASTM D 1129 : 2006 : REV A : EDT 1 Standard Terminology Relating to Water
    ASTM D 1129 : 2001 Standard Terminology Relating to Water
    ASTM D 6994 : 2015 Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection
    ASTM D 1129 : 2004 : EDT 1 Standard Terminology Relating to Water
    ASTM D 1193 : 2006 : R2018 Standard Specification for Reagent Water
    ASTM D 6888 : 2016 : REDLINE Standard Test Method for Available Cyanides with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
    ASTM D 2777 : 2008 : EDT 1 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
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