ASTM D 4463/D4463M : 2019

1.1This guide covers the deactivation of fresh fluid catalytic cracking (FCC) catalyst by hydrothermal treatment prior to the determination of the catalytic cracking activity in the microactivity test (MAT) or the Advanced Cracking Evaluation (ACE) test.

1.2The hydrothermal treatment of fresh FCC catalyst, prior to the MAT or the ACE test, is important because the catalytic activity of the catalyst in its fresh state is an inadequate measure of its true commercial performance. During operation in a commercial cracking unit, the catalyst is deactivated by thermal, hydrothermal, and chemical degradation. Therefore, to maintain catalytic activity, fresh catalyst is added (semi) continuously to the cracking unit, to replace catalyst lost through the stack or by withdrawal, or both. Under steady state conditions, the catalyst inventory of the unit is called equilibrium catalyst. This catalyst has an activity level substantially below that of fresh catalyst. Therefore, artificially deactivating a fresh catalyst prior to determination of its cracking activity should provide more meaningful catalyst performance data.

1.3Due to the large variations in properties among fresh FCC catalyst types as well as between commercial cracking unit designs or operating conditions, or both, no single set of steam deactivation conditions is adequate to artificially simulate the equilibrium catalyst for all purposes.

1.4This guide offers two approaches to steam deactivate fresh catalysts. The first part provides specific sets of conditions (time, temperature, and steam pressure) that can be used as general pre-treatments prior to comparison of fresh FCC catalyst MAT activities (Test Method D3907) or activities plus selectivities (Test Methods D5154 and D7964).

1.5The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.

1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.7This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.