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ASTM D 4868 : 2017 : REDLINE

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Current

The latest, up-to-date edition.

Standard Test Method for Estimation of Net and Gross Heat of Combustion of Hydrocarbon Burner and Diesel Fuels

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Published date

12-01-2022

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CONTAINED IN VOL. 05.02, 2017 Defines the estimation of the gross and net heat of combustion in SI units, megajoules per kilogram, of petroleum fuels from the fuel density, sulfur, water, and ash content.

Committee
D 02
DocumentType
Redline
Pages
3
PublisherName
American Society for Testing and Materials
Status
Current
Supersedes

1.1This test method covers the estimation of the gross and net heat of combustion in SI units, megajoules per kilogram, of hydrocarbon fuels and blendstocks from the fuel density and sulfur, water, and ash contents.

1.1.1This test method is not applicable to fuels containing non-hydrocarbons such as alcohols (for example, ethanol, methanol), ethers (for example, MTBE), or esters (for example, biodiesel).

Note 1:The equation for estimation of net and gross heat of combustion used in this method was originally published as NBS Miscellaneous Publication No. 97.

1.2This test method is especially useful for estimating, using a minimum number of tests, the heat of combustion of burner and diesel fuels (which do not contain non-hydrocarbon components) for which it is not usually critical to obtain very precise heat determinations.

Note 2:More accurate estimation methods are available for aviation fuels (Test Methods D1405, D4529,and D3338). However, those estimation methods require additional tests to those required in this test method.

1.3This test method is purely empirical (Note 1). It was derived using liquid hydrocarbon fuels produced by normal refining processes from conventional crude oil that conform to the requirements of specifications for petroleum fuels as described in Note 3. This test method is valid for those fuels in the density range from 750 kg/m3 to 1000 kg/m3 and those that do not contain an unusually high aromatic content. High aromatic content fuels will not normally meet some fuel specification criteria.

Note 3:The estimation of the heat of combustion of a hydrocarbon fuel from its density and sulfur, water, and ash content is justifiable only when the fuel belongs to well-defined classes for which a relationship between these quantities have been derived from accurate experimental measurements on representative samples of these classes. Even in these classes, the possibility that the estimate can be in error for individual fuels should be recognized. This test method has been tested for a limited number of fuels from oil sand bitumen and shale oil origin and has been found to be valid. The classes of fuels used to establish the correlation presented in this test method are represented by the following applications:

Fuel (not applicable to any fuels containing non-hydrocarbon components)

Specification

Fuel Oils

Grades No. 1, 2, 4 (light), 4, 5 (light), 5 (heavy), and 6

D396

Diesel

Grades No. 1-D, 2-D, and 4-D

D975

Aviation Turbine

Jet A and Jet A-1

D1655

Jet B

D6615

Gas Turbine

Grades No. 0-GT, 1-GT, 2-GT, 3-GT, and 4-GT

D2880

Kerosene

Grades No. 1-K and 2-K

D3699

1.4This test method is not applicable to pure hydrocarbon compounds. It is not intended as a substitute for highly accurate experimental measurements of heat of combustion (Note 4).

Note 4:The procedures for the experimental determination of the gross and net heats of combustion are described in Test Methods D240 and D4809.

1.5The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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ASTM D 6823 : 2008 : R2013 Standard Specification for Commercial Boiler Fuels With Used Lubricating Oils
ASTM D 6448 : 2016 : REDLINE Standard Specification for Industrial Burner Fuels from Used Lubricating Oils
FM 6930 : 2009 FLAMMABILITY CLASSIFICATION OF INDUSTRIAL FLUIDS
ISO 18888:2017 Gas turbine combined cycle power plants — Thermal performance tests
BS ISO 18888:2017 Gas turbine combined cycle power plants. Thermal performance tests

ASTM D 129 : 2013-08 TEST METHOD FOR SULFUR IN PETROLEUM PRODUCTS (GENERAL HIGH PRESSURE DECOMPOSITION DEVICE METHOD)
ASTM D 3699 : 2013-05 SPECIFICATION FOR KEROSINE
ASTM D 4529 : 2017 : REDLINE Standard Test Method for Estimation of Net Heat of Combustion of Aviation Fuels
ASTM D 240 : 2017 : REDLINE Standard Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter
ASTM D 2622 : 2016 : REDLINE Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry
ASTM D 1481 : 2017 : REDLINE Standard Test Method for Density and Relative Density (Specific Gravity) of Viscous Materials by Lipkin Bicapillary Pycnometer
ASTM D 1480 : 2015 : REDLINE Standard Test Method for Density and Relative Density (Specific Gravity) of Viscous Materials by Bingham Pycnometer
ASTM D 1744 : 2013 Standard Test Method for Determination of Water in Liquid Petroleum Products by Karl Fischer Reagent (Withdrawn 2016)

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