BS EN 16377:2013
Current
The latest, up-to-date edition.
Characterization of waste. Determination of brominated flame retardants (BFR) in solid waste
Hardcopy , PDF
English
30-09-2013
Foreword
Introduction
1 Scope
2 Normative references
3 Principle
4 Interference
5 Reagents and standards
6 Equipment
7 Sample pretreatment
8 Procedure
9 Calibration
10 Test report
Annex A (normative) - Clean-up procedures
Annex B (informative) - Examples of separation conditions in
gas chromatography and mass spectrometry
Annex C (informative) - Typical ions and time windows for
electron impact ionisation detection
Annex D (informative) - Examples of chromatograms
Annex E (informative) - Precision data
Annex F (informative) - Summary of general requirements
and recommendations
Bibliography
Describes a method for the determination of selected polybrominated flame retardants (BFR), chemically known as polybrominated diphenylethers (BDE), in waste materials using gas chromatography/mass spectrometry (GC-MS) in the electron impact (EI) ionisation mode (GC-EI-MS).
Committee |
EH/4
|
DevelopmentNote |
Supersedes 12/30255723 DC. (10/2013)
|
DocumentType |
Standard
|
Pages |
32
|
PublisherName |
British Standards Institution
|
Status |
Current
|
Supersedes |
This European Standard specifies a method for the determination of selected polybrominated flame retardants (BFR), chemically known as polybrominated diphenylethers (BDE), in waste materials using gas chromatography/mass spectrometry (GC-MS) in the electron impact (EI) ionisation mode (GC-EI-MS). When applying GC-EI-MS, the method is applicable to samples containing 100 µg/kg to 5 000 µg/kg of tetra-to octabromodiphenylether congeners and 100 µg/kg to 10 000 µg/kg of decabromo diphenylether (see Table 1). It is also possible to analyse other brominated flame retardants applying the method described in this European Standard, provided the method\'s applicability has been proven. Table 1 — Brominated flame retardants determined by this method No. Congener Formula Abbreviationa Molar massg/mol 1 2,2’,4,4’-Tetrabromodiphenylether C12H6Br4O BDE-47 485,795 0 2 2,2’,4,4’,5-Pentabromodiphenylether C12H5Br5O BDE-99 564,691 1 3 2,2’,4,4’,6-Pentabromodiphenylether C12H5Br5O BDE-100 564,691 1 4 2,2’,4,4’,5,6’-Hexabromodiphenylether C12H4Br6O BDE-154 643,587 2 5 2,2’,4,4’,5,5’-Hexabromodiphenylether C12H4Br6O BDE-153 643,587 2 6 2,2’,3,4,4’,5’,6-Heptabromodiphenylether C12H3Br7O BDE-183 722,483 2 7 Decabromodiphenylether C12Br10O BDE-209 959,171 4 a Numbering for the BDE according to IUPAC nomenclature for PCB.
Standards | Relationship |
EN 16377:2013 | Identical |
ISO 22892:2006 | Soil quality Guidelines for the identification of target compounds by gas chromatography and mass spectrometry |
EN 14346:2006 | Characterization of waste - Calculation of dry matter by determination of dry residue or water content |
EN ISO 22032:2009 | Water quality - Determination of selected polybrominated diphenyl ethers in sediment and sewage sludge - Method using extraction and gas chromatography/mass spectrometry (ISO 22032:2006) |
ISO 22032:2006 | Water quality — Determination of selected polybrominated diphenyl ethers in sediment and sewage sludge — Method using extraction and gas chromatography/mass spectrometry |
ISO 8466-1:1990 | Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the linear calibration function |
EN 15002:2015 | Characterization of waste - Preparation of test portions from the laboratory sample |
EN ISO 22892:2011 | Soil quality - Guidelines for the identification of target compounds by gas chromatography and mass spectrometry (ISO 22892:2006) |
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