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CEN/TR 10350:2013

Current

Current

The latest, up-to-date edition.

Analysis of steels and irons - Internal laboratory procedure for checking the accuracy of an analytical method by using Certified Reference Materials

Published date

27-02-2013

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Foreword
Introduction
1 Scope
2 Principle
3 Terms and definitions
4 Procedure
5 Evaluation of precision
6 Assessment of the trueness
7 Conclusion
Annex A (informative) - Symbols used
Annex B (informative) - Table of the chi[2] distribution
Annex C (informative) - Examples
Bibliography

The present statistical procedure describes how to check results for absence of bias by comparison of these analytical results with those obtained during the certification of CRMs.If the resulting data confirm the absence of bias, the method may be considered accurate when applied to all steels and irons whose composition ranges are adequately covered or bounded by the CRMs used.The resulting data give also an estimate of the repeatability and/or the intermediate precision ("intralaboratory reproducibility") for the CRMs used. The comparison of these analytical data with the repeatability data obtained during the certification may also be performed depending on the strict purpose of the method under consideration.For the purpose of this Technical Report, the use of existing CRMs is essential for the assessment of the trueness, but it may be only indicative for the other statistical data.NOTEThis Technical Report does not describe the use of CRMs as calibrants, this subject being treated in ISO Guide 32.

Committee
CEN/TC 459/SC 2
DocumentType
Technical Report
PublisherName
Comite Europeen de Normalisation
Status
Current

Standards Relationship
PD CEN/TR 10350:2013 Identical
S.R. CEN/TR 10350:2013 Identical
FD CEN/TR 10350 : 2013 FD Identical
NEN NPR CEN/TR 10350 : 2013 Identical

PD CEN/TR 10317:2014 European certified reference materials (EURONORM-CRMs) for the determination of the chemical composition of iron and steel products prepared under the auspices of the European Committee for Iron and Steel Standardization (ECISS)
S.R. CEN/TR 10317:2014 EUROPEAN CERTIFIED REFERENCE MATERIALS (EURONORM-CRMS) FOR THE DETERMINATION OF THE CHEMICAL COMPOSITION OF IRON AND STEEL PRODUCTS PREPARED UNDER THE AUSPICES OF THE EUROPEAN COMMITTEE FOR IRON AND STEEL STANDARDIZATION (ECISS)
CEN/TR 10317:2014 European certified reference materials (EURONORM-CRMs) for the determination of the chemical composition of iron and steel products prepared under the auspices of the European Committee for Iron and Steel Standardization (ECISS)
PD CEN/TR 10261:2013 Iron and steel. European standards for the determination of chemical composition
CEN/TR 10261:2013 Iron and steel - European standards for the determination of chemical composition

ISO Guide 33:2015 Reference materials — Good practice in using reference materials
CEN/TR 10317:2014 European certified reference materials (EURONORM-CRMs) for the determination of the chemical composition of iron and steel products prepared under the auspices of the European Committee for Iron and Steel Standardization (ECISS)
ISO 3534-2:2006 Statistics — Vocabulary and symbols — Part 2: Applied statistics
ISO Guide 30:2015 Reference materials — Selected terms and definitions
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method

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