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EN 13804:2013

Current

Current

The latest, up-to-date edition.

Foodstuffs - Determination of elements and their chemical species - General considerations and specific requirements

Published date

06-03-2013

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Foreword
Introduction
1 Scope
2 Sample preparation
3 Specific requirements for analysis of
  trace elements
4 Performance requirements and characteristics
5 Interpretation and expression of results
6 Test report
Bibliography

This European Standard specifies performance criteria for the selection of methods of analysis of elements and their chemical species in foodstuffs and contains performance requirements and characteristics, guidelines for laboratory set-up, sample preparation and test reports.

Committee
CEN/TC 275
DevelopmentNote
Supersedes PREN 13804. (03/2013)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Current

Standards Relationship
GOST R EN 13804 : 2010 Identical
PN EN 13804 : 2013 Identical
BS EN 13804:2013 Identical
NEN EN 13804 : 2013 Identical
UNI EN 13804 : 2013 Identical
NS EN 13804 : 2013 Identical
NF EN 13804 : 2013 Identical
NBN EN 13804 : 2013 Identical
DIN EN 13804:2013-06 Identical
I.S. EN 13804:2013 Identical
SN EN 13804:2013 Identical
UNE-EN 13804:2013 Identical

I.S. EN 15111:2007 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF IODINE BY ICP-MS (INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY)
UNI EN 15517 : 2008 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF INORGANIC ARSENIC IN SEAWEED BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS) AFTER ACID EXTRACTION
BS EN 16801:2016 Foodstuffs. Determination of elements and their chemical species. Determination of methylmercury in foodstuffs of marine origin by isotope dilution GC-ICP-MS
06/30153588 DC : DRAFT JULY 2006 BS EN 15111 - FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF IODINE BY ICP-MS (INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY)
BS EN 16159:2012 Animal feeding stuffs. Determination of selenium by hydride generation atomic absorption spectrometry (HGAAS) after microwave digestion (digestion with 65 % nitric acid and 30 % hydrogen peroxide)
13/30267880 DC : 0 BS EN 13805 - FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - PRESSURE DIGESTION
S.R. CEN/TS 16731:2014 FOODSTUFFS - DETERMINATION OF HYDRIDE-REACTIVE ARSENIC COMPOUNDS IN RICE BY ATOMIC ABSORPTION SPECTROMETRY (HYDRIDE-AAS) FOLLOWING ACID EXTRACTION
I.S. EN 16277:2012 ANIMAL FEEDING STUFFS - DETERMINATION OF MERCURY BY COLD-VAPOUR ATOMIC ABSORPTION SPECTROMETRY (CVAAS) AFTER MICROWAVE PRESSURE DIGESTION (EXTRACTION WITH 65% NITRIC ACID AND 30% HYDROGEN PEROXIDE)
UNI EN 15505 : 2008 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF SODIUM AND MAGNESIUM BY FLAME ATOMIC ABSORPTION SPECTROMETRY (AAS) AFTER MICROWAVE DIGESTION
DIN EN 14083:2003-07 Foodstuffs - Determination of trace elements - Determination of lead, cadmium, chromium and molybdenum by graphite furnace atomic absorption spectrometry (GFAAS) after pressure digestion; German version EN 14083:2003
CEN/TS 16731:2014 Foodstuffs - Determination of hydride-reactive arsenic compounds in rice by atomic absorption spectrometry (Hydride-AAS) following acid extraction
UNE-EN 16801:2016 Foodstuffs - Determination of elements and their chemical species - Determination of methylmercury in foodstuffs of marine origin by isotope dilution GC-ICP-MS
PREN 13805 : DRAFT 2013 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - PRESSURE DIGESTION
BS EN 16206:2012 Animal feeding stuffs. Determination of arsenic by hydride generation atomic absorption spectrometry (HGAAS) after microwave pressure digestion (digestion with 65 % nitric acid and 30 % hydrogen peroxide)
I.S. EN 16206:2012 ANIMAL FEEDING STUFFS - DETERMINATION OF ARSENIC BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS) AFTER MICROWAVE PRESSURE DIGESTION (DIGESTION WITH 65% NITRIC ACID AND 30% HYDROGEN PEROXIDE)
S.R. CEN TS 15506:2007 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF TIN IN FRUIT AND VEGETABLES PRESERVED IN CANS BY FLAME ATOMIC ABSORPTION SPECTROMETRY (AAS)
I.S. EN 15517:2008 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF INORGANIC ARSENIC IN SEAWEED BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS) AFTER ACID EXTRACTION
BS EN 14627:2005 Foodstuffs. Determination of trace elements. Determination of total arsenic and selenium by hydride generation atomic absorption spectrometry (HGAAS) after pressure digestion
I.S. EN 13805:2014 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - PRESSURE DIGESTION
UNI EN 16206 : 2012 ANIMAL FEEDING STUFFS - DETERMINATION OF ARSENIC BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS) AFTER MICROWAVE PRESSURE DIGESTION (DIGESTION WITH 65% NITRIC ACID AND 30% HYDROGEN PEROXIDE)
DIN EN 15517:2008-09 Foodstuffs - Determination of trace elements - Determination of inorganic arsenic in seaweed by hydride generation atomic absorption spectrometry (HGAAS) after acid extraction
BS EN 16943:2017 Foodstuffs. Determination of calcium, copper, iron, magnesium, manganese, phosphorus, potassium, sodium, sulfur and zinc by ICP-OES
DIN EN 16206:2012-05 Animal feeding stuffs - Determination of arsenic by hydride generation atomic absorption spectrometry (HGAAS) after microwave pressure digestion (digestion with 65 % nitric acid and 30 % hydrogen peroxide)
BS EN 15505:2008 Foodstuffs. Determination of trace elements. Determination of sodium and magnesium by flame atomic absorption spectrometry (AAS) after microwave digestion
15/30330796 DC : 0 BS EN 16943 - FOODSTUFFS - DETERMINATION OF ELEMENTS AND THEIR CHEMICAL SPECIES - DETERMINATION OF MINERALS BY ICP-OES
08/30174176 DC : DRAFT FEB 2008 BS EN 15763 - FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF ARSENIC, CADMIUM, MERCURY AND LEAD IN FOODSTUFFS BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY (ICP-MS) AFTER PRESSURE DIGESTION
BS EN 16277:2012 Animal feeding stuffs. Determination of mercury by cold-vapour atomic absorption spectrometry (CVAAS) after microwave pressure digestion (extraction with 65% nitric acid and 30% hydrogen peroxide)
I.S. EN 14082:2003 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF LEAD, CADMIUM, ZINC, COPPER, IRON AND CHROMIUM BY ATOMIC ABSORPTION SPECTROMETRY (AAS) AFTER ASH DRYING
UNI EN 16277 : 2012 ANIMAL FEEDING STUFFS - DETERMINATION OF MERCURY BY COLD-VAPOUR ATOMIC ABSORPTION SPECTROMETRY (CVAAS) AFTER MICROWAVE PRESSURE DIGESTION (EXTRACTION WITH 65% NITRIC ACID AND 30% HYDROGEN PEROXIDE)
BS EN 15517:2008 Foodstuffs. Determination of trace elements. Determination of inorganic arsenic in seaweed by hydride generation atomic absorption spectrometry (HGAAS) after acid extraction
I.S. EN 16801:2016 FOODSTUFFS - DETERMINATION OF ELEMENTS AND THEIR CHEMICAL SPECIES - DETERMINATION OF METHYLMERCURY IN FOODSTUFFS OF MARINE ORIGIN BY ISOTOPE DILUTION GC-ICP-MS
I.S. EN 16943:2017 FOODSTUFFS - DETERMINATION OF CALCIUM, COPPER, IRON, MAGNESIUM, MANGANESE, PHOSPHORUS, POTASSIUM, SODIUM, SULFUR AND ZINC BY ICP-OES
UNE-EN 16277:2012 Animal feeding stuffs - Determination of mercury by cold-vapour atomic absorption spectrometry (CVAAS) after microwave pressure digestion (extraction with 65 % nitric acid and 30 % hydrogen peroxide)
UNI CEN/TS 16731 : 2014 Food products - Determination of arsenic compounds reacting to hydride in rice by atomic absorption spectrometry (AAS-hydride) following acid extraction
I.S. EN 15505:2008 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF SODIUM AND MAGNESIUM BY FLAME ATOMIC ABSORPTION SPECTROMETRY (AAS) AFTER MICROWAVE DIGESTION
DIN EN 13805:2014-12 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - PRESSURE DIGESTION
EN 16801:2016 Foodstuffs - Determination of elements and their chemical species - Determination of methylmercury in foodstuffs of marine origin by isotope dilution GC-ICP-MS
EN 15517:2008 Foodstuffs - Determination of trace elements - Determination of inorganic arsenic in seaweed by hydride generation atomic absorption spectrometry (HGAAS) after acid extraction
UNI EN 13805 : 2014 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - PRESSURE DIGESTION
EN 16159:2012 Animal feeding stuffs - Determination of selenium by hydride generation atomic absorption spectrometry (HGAAS) after microwave digestion (digestion with 65 % nitric acid and 30 % hydrogen peroxide)
DIN EN 16159:2012-04 Animal feeding stuffs - Determination of selenium by hydride generation atomic absorption spectrometry (HGAAS) after microwave digestion (digestion with 65 % nitric acid and 30 % hydrogen peroxide)
10/30199728 DC : 0 BS EN 16206 - ANIMAL FEEDING STUFFS - DETERMINATION OF ARSENIC BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS) AFTER MICROWAVE PRESSURE DIGESTION (EXTRACTION WITH 65% NITRIC ACID AND 30% HYDROGEN PEROXIDE)
PD CEN/TS 16731:2014 Foodstuffs. Determination of hydride-reactive arsenic compounds in rice by atomic absorption spectrometry (Hydride-AAS) following acid extraction
10/30199731 DC : 0 BS EN 16159 - ANIMAL FEEDING STUFFS - DETERMINATION OF SELENIUM BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS) AFTER MICROWAVE DIGESTION (EXTRACTION WITH 65% NITRIC ACID AND 30% HYDROGEN PEROXIDE)
06/30149862 DC : 0 EN 15517 - FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF INORGANIC ARSENIC IN SEAWEED BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS)
UNE-EN 16206:2012 Animal feeding stuffs - Determination of arsenic by hydride generation atomic absorption spectrometry (HGAAS) after microwave pressure digestion (digestion with 65 % nitric acid and 30 % hydrogen peroxide)
DIN EN 16802:2016-07 FOODSTUFFS - DETERMINATION OF ELEMENTS AND THEIR CHEMICAL SPECIES - DETERMINATION OF INORGANIC ARSENIC IN FOODSTUFFS OF MARINE AND PLANT ORIGIN BY ANION-EXCHANGE HPLC-ICP-MS
11/30199734 DC : 0 BS EN 16277 - ANIMAL FEEDING STUFFS - DETERMINATION OF MERCURY BY COLD-VAPOUR ATOMIC ABSORPTION SPECTROMETRY (CVAAS) AFTER MICROWAVE PRESSURE DIGESTION (EXTRACTION WITH 65% NITRIC ACID AND 30% HYDROGEN PEROXIDE)
UNE-EN 16159:2012 Animal feeding stuffs - Determination of selenium by hydride generation atomic absorption spectrometry (HGAAS) after microwave digestion (digestion with 65 % nitric acid and 30 % hydrogen peroxide)
I.S. CEN TS 15111:2005 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF IODINE IN DIETETIC FOODS BY ICP-MS (INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY)
I.S. EN 16159:2012 ANIMAL FEEDING STUFFS - DETERMINATION OF SELENIUM BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS) AFTER MICROWAVE DIGESTION (DIGESTION WITH 65% NITRIC ACID AND 30% HYDROGEN PEROXIDE)
BS EN 14082:2003 Foodstuffs. Determination of trace elements. Determination of lead, cadmium, zinc, copper, iron and chromium by atomic absorption spectrometry (AAS) after ash drying
BS EN 14332:2004 Foodstuffs. Determination of trace elements. Determination of arsenic in seafood by graphite furnace atomic absorption spectrometry (GFAAS) after microwave digestion
BS EN 14546:2005 Foodstuffs. Determination of trace elements. Determination of total arsenic by hydride generation atomic absorption spectrometry (HGAAS) after dry ashing
BS EN 15111:2007 Foodstuffs. Determination of trace elements. Determination of iodine by ICP-MS (inductively coupled plasma mass spectrometry)
BS EN 13806:2002 Foodstuffs. Determination of trace elements. Determination of mercury by cold-vapour atomic absorption spectrometry (CVAAS) after pressure digestion
BS EN 13805:2014 Foodstuffs. Determination of trace elements. Pressure digestion
BS EN 14084:2003 Foodstuffs. Determination of trace elements. Determination of lead, cadmium, zinc, copper and iron by atomic absorption spectrometry (AAS) after microwave digestion
UNE-EN 13805:2015 Foodstuffs - Determination of trace elements - Pressure digestion
DIN EN 15505:2008-06 Foodstuffs - Determination of trace elements - Determination of sodium and magnesium by flame atomic absorption spectrometry (AAS) after microwave digestion
EN 14084:2003 Foodstuffs - Determination of trace elements - Determination of lead, cadmium, zinc, copper and iron by atomic absorption spectrometry (AAS) after microwave digestion
EN 15505:2008 Foodstuffs - Determination of trace elements - Determination of sodium and magnesium by flame atomic absorption spectrometry (AAS) after microwave digestion
EN 16277:2012 Animal feeding stuffs - Determination of mercury by cold-vapour atomic absorption spectrometry (CVAAS) after microwave pressure digestion (extraction with 65 % nitric acid and 30 % hydrogen peroxide)
EN 13805:2014 Foodstuffs - Determination of trace elements - Pressure digestion
EN 13806:2002 Foodstuffs - Determination of trace elements - Determination of mercury by cold-vapour atomic absorption spectrometry (CVAAS) after pressure digestion
EN 14083:2003 Foodstuffs - Determination of trace elements - Determination of lead, cadmium, chromium and molybdenum by graphite furnace atomic absorption spectrometry (GFAAS) after pressure digestion
EN 14082:2003 Foodstuffs - Determination of trace elements - Determination of lead, cadmium, zinc, copper, iron and chromium by atomic absorption spectrometry (AAS) after dry ashing
EN 16802:2016 Foodstuffs - Determination of elements and their chemical species - Determination of inorganic arsenic in foodstuffs of marine and plant origin by anion-exchange HPLC-ICP-MS
EN 16206:2012 Animal feeding stuffs - Determination of arsenic by hydride generation atomic absorption spectrometry (HGAAS) after microwave pressure digestion (digestion with 65 % nitric acid and 30 % hydrogen peroxide)
EN 14332:2004 Foodstuffs - Determination of trace elements - Determination of arsenic in seafood by graphite furnace atomic absorption spectrometry (GFAAS) after microwave digestion
EN 14546:2005 Foodstuffs - Determination of trace elements - Determination of total arsenic by hydride generation atomic absorption spectrometry (HGAAS) after dry ashing
EN 16943:2017 Foodstuffs - Determination of calcium, copper, iron, magnesium, manganese, phosphorus, potassium, sodium, sulfur and zinc by ICP-OES
EN 14627:2005 Foodstuffs - Determination of trace elements - Determination of total arsenic and selenium by hydride generation atomic absorption spectrometry (HGAAS) after pressure digestion
06/30147941 DC : 0 EN 15505 - FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF SODIUM, MAGNESIUM AND CALCIUM BY FLAME ATOMIC ABSORPTION SPECTROMETRY (AAS) AFTER MICROWAVE DIGESTION
UNE-EN 16943:2017 Foodstuffs - Determination of calcium, copper, iron, magnesium, manganese, phosphorus, potassium, sodium, sulfur and zinc by ICP-OES
14/30267877 DC : 0 BS EN 16802 - FOODSTUFFS - DETERMINATION OF ELEMENTS AND THEIR CHEMICAL SPECIES - DETERMINATION OF INORGANIC ARSENIC IN FOODSTUFFS OF MARINE AND PLANT ORIGIN BY ANION-EXCHANGE HPLC-ICP-MS FOLLOWING WATERBATH EXTRACTION
DIN EN 16277:2012-09 ANIMAL FEEDING STUFFS - DETERMINATION OF MERCURY BY COLD-VAPOUR ATOMIC ABSORPTION SPECTROMETRY (CVAAS) AFTER MICROWAVE PRESSURE DIGESTION (EXTRACTION WITH 65% NITRIC ACID AND 30% HYDROGEN PEROXIDE)
DD CEN/TS 15506:2007 Foodstuffs. Determination of trace elements. Determination of tin in fruit and vegetables preserved in cans by flame atomic absorption spectrometry (AAS)
14/30267874 DC : 0 BS EN 16801 - FOODSTUFFS - DETERMINATION OF ELEMENTS AND THEIR CHEMICAL SPECIES - DETERMINATION OF METHYLMERCURY BY ISOTOPE DILUTION GC-ICPMS IN FOODSTUFFS OF MARINE ORIGIN
02/710049 DC : DRAFT OCT 2002 PREN 14546 - FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF TOTAL ARSENIC BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS) AFTER DRY ASHING
BS EN 16802:2016 Foodstuffs. Determination of elements and their chemical species. Determination of inorganic arsenic in foodstuffs of marine and plant origin by anion-exchange HPLC-ICP-MS
I.S. EN 16802:2016 FOODSTUFFS - DETERMINATION OF ELEMENTS AND THEIR CHEMICAL SPECIES - DETERMINATION OF INORGANIC ARSENIC IN FOODSTUFFS OF MARINE AND PLANT ORIGIN BY ANION-EXCHANGE HPLC-ICP-MS
DIN EN 16943:2016-01 (Draft) FOODSTUFFS - DETERMINATION OF CALCIUM, COPPER, IRON, MAGNESIUM, MANGANESE, PHOSPHORUS, POTASSIUM, SODIUM, SULFUR AND ZINC BY ICP-OES
UNI EN 16159 : 2012 ANIMAL FEEDING STUFFS - DETERMINATION OF SELENIUM BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY (HGAAS) AFTER MICROWAVE DIGESTION (DIGESTION WITH 65 % NITRIC ACID AND 30 % HYDROGEN PEROXIDE)
DD CEN/TS 15111:2005 Foodstuffs. Determination of trace elements. Determination of iodine in dietetic foods by ICP-MS (inductively coupled plasma mass spectrometry)
UNE-EN 16802:2016 Foodstuffs - Determination of elements and their chemical species - Determination of inorganic arsenic in foodstuffs of marine and plant origin by anion-exchange HPLC-ICP-MS
BS EN 14083:2003 Foodstuffs. Determination of trace elements. Determination of lead, cadmium, chromium and molybdenum by graphite furnace atomic absorption spectrometry (GFAAS) after pressure digestion
DIN EN 15111:2007-06 Foodstuffs - Determination of trace elements - Determination of iodine by ICP-MS (inductively coupled plasma mass spectrometry)
DIN EN 13806:2002-11 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF MERCURY BY COLD-VAPOUR ATOMIC ABSORPTION SPECTROMETRY (CVAAS) AFTER PRESSURE DIGESTION
CEN/TS 15111:2005 Foodstuffs - Determination of trace elements - Determination of iodine in dietetic foods by ICP-MS (inductively coupled plasma mass spectrometry)
DIN EN 14546:2005-07 Foodstuffs - Determination of trace elements - Determination of total arsenic by hydride generation atomic absorption spectrometry (HGAAS) after dry ashing
DIN EN 14082:2003-06 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF LEAD, CADMIUM, ZINC, COPPER, IRON AND CHROMIUM BY ATOMIC ABSORPTION SPECTROMETRY (AAS) AFTER DRY ASHING
CEN/TS 15506:2007 Foodstuffs - Determination of trace elements - Determination of tin in fruit and vegetables preserved in cans by flame atomic absorption spectrometry (AAS)
DIN EN 14332:2004-10 Foodstuffs - Determination of trace elements - Determination of arsenic in seafood by graphite furnace atomic absorption spectrometry (GFAAS) after microwave digestion
DIN EN 14627:2005-07 Foodstuffs - Determination of trace elements - Determination of total arsenic and selenium by hydride generation atomic absorption spectrometry (HGAAS) after pressure digestion
EN 15111:2007 Foodstuffs - Determination of trace elements - Determination of iodine by ICP-MS (inductively coupled plasma mass spectrometry)
DIN EN 14084:2003-07 FOODSTUFFS - DETERMINATION OF TRACE ELEMENTS - DETERMINATION OF LEAD, CADMIUM, ZINC, COPPER AND IRON BY ATOMIC ABSORPTION SPECTROMETRY (AAS) AFTER MICROWAVE DIGESTION

ISO/IEC 17025:2005 General requirements for the competence of testing and calibration laboratories
DIN 32645:2008-11 CHEMICAL ANALYSIS - DECISION LIMIT, DETECTION LIMIT AND DETERMINATION LIMIT UNDER REPEATABILITY CONDITIONS - TERMS, METHODS, EVALUATION
ISO/IEC Guide 98-3:2008 Uncertainty of measurement — Part 3: Guide to the expression of uncertainty in measurement (GUM:1995)

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