• EN 13999-4:2007+A1:2009

    Current The latest, up-to-date edition.

    Adhesives - Short term method for measuring the emission properties of low-solvent or solvent-free adhesives after application - Part 4: Determination of volatile diisocyanates

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    Published date:  28-04-2009

    Publisher:  Comite Europeen de Normalisation

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    Table of Contents - (Show below) - (Hide below)

    Foreword
    SAFETY STATEMENT
    1 Scope
    2 Normative references
    3 Principle
    4 Reagents and materials
    5 Apparatus
    6 Procedure
    7 Identification and calculation
    8 Interferences
    9 Precision and bias
    10 Test report
    11 Quality control
    Bibliography

    Abstract - (Show below) - (Hide below)

    This European Standard specifies a procedure for the determination of volatile isocyanates in the exhaust air of an emission test chamber after application of a low-solvent or solvent-free adhesive as defined in EN 923.The method is based on chemosorption of volatile isocyanates with 1-(2-methoxyphenyl) piperazine (in the following: 1-2MP) impregnated filters with subsequent desorption and liquid chromatographic analysis. The method permits measurement of a wide range of organic compounds containing isocyanate functional groups (NCO), including isocyanate monomers. For testing of adhesives emissions mainly toluene diisocyanate (TDI) and methylene bis (4-phenyl isocyanate also known as 4,4-diisocyanato-diphenylmethane or MDI), are of concern. The method as described in this European Standard can be used for other isocyanates too, such as isophorone diisocyanate (IPDI) and 1,6-hexamethylene diisocyanate (HDI) - see ISO 16702. Isocyanate oligomers or prepolymers are not volatile enough to be detected in emission test chambers at room temperature.

    General Product Information - (Show below) - (Hide below)

    Committee CEN/TC 193
    Development Note Supersedes ENV 13999-4. (05/2007) 2007 Edition Re-Issued in April 2009 & incorporates AMD 1 2009. (06/2009)
    Document Type Standard
    Publisher Comite Europeen de Normalisation
    Status Current

    Standards Referenced By This Book - (Show below) - (Hide below)

    DIN EN 13999-1:2014-03 ADHESIVES - SHORT TERM METHOD FOR MEASURING THE EMISSION PROPERTIES OF LOW-SOLVENT OR SOLVENT-FREE ADHESIVES AFTER APPLICATION - PART 1: GENERAL PROCEDURE
    UNE-EN 13999-1:2014 Adhesives - Short term method for measuring the emission properties of low-solvent or solvent-free adhesives after application - Part 1: General procedure
    DIN EN 15274:2015-06 GENERAL PURPOSE ADHESIVES FOR STRUCTURAL ASSEMBLY - REQUIREMENTS AND TEST METHODS
    I.S. EN 13999-1:2013 ADHESIVES - SHORT TERM METHOD FOR MEASURING THE EMISSION PROPERTIES OF LOW-SOLVENT OR SOLVENT-FREE ADHESIVES AFTER APPLICATION - PART 1: GENERAL PROCEDURE
    I.S. EN 15274:2015 GENERAL PURPOSE ADHESIVES FOR STRUCTURAL ASSEMBLY - REQUIREMENTS AND TEST METHODS
    14/30300568 DC : 0 BS EN 15274 - GENERAL PURPOSE ADHESIVES FOR STRUCTURAL ASSEMBLY - REQUIREMENTS AND TEST METHODS
    SAE J 2989 : APR 2018 HANDLING AND PACKAGING OF MATERIALS AND COMPONENTS FOR EMISSIONS TESTING
    DIN EN 15274 E : 2015 GENERAL PURPOSE ADHESIVES FOR STRUCTURAL ASSEMBLY - REQUIREMENTS AND TEST METHODS
    UNI EN 13999-1 : 2014 ADHESIVES - SHORT TERM METHOD FOR MEASURING THE EMISSION PROPERTIES OF LOW-SOLVENT OR SOLVENT-FREE ADHESIVES AFTER APPLICATION - PART 1: GENERAL PROCEDURE
    EN 13999-1:2013 Adhesives - Short term method for measuring the emission properties of low-solvent or solvent-free adhesives after application - Part 1: General procedure
    12/30259194 DC : 0 BS EN 13999-1 - ADHESIVES - SHORT TERM METHOD FOR MEASURING THE EMISSION PROPERTIES OF LOW-SOLVENT OR SOLVENT-FREE ADHESIVES AFTER APPLICATION - PART 1: GENERAL PROCEDURE
    PREN 13999-1 : DRAFT 2012 ADHESIVES - SHORT TERM METHOD FOR MEASURING THE EMISSION PROPERTIES OF LOW-SOLVENT OR SOLVENT-FREE ADHESIVES AFTER APPLICATION - PART 1: GENERAL PROCEDURE
    PREN 15274 : DRAFT 2014 GENERAL PURPOSE ADHESIVES FOR STRUCTURAL ASSEMBLY - REQUIREMENTS AND TEST METHODS
    UNE-EN 15274:2015 General purpose adhesives for structural assembly - Requirements and test methods
    EN 15274:2015 General purpose adhesives for structural assembly - Requirements and test methods
    BS EN 15274:2015 General purpose adhesives for structural assembly. Requirements and test methods
    BS EN 13999-1:2013 Adhesives. Short term method for measuring the emission properties of low-solvent or solvent-free adhesives after application General procedure

    Standards Referencing This Book - (Show below) - (Hide below)

    EN 13999-1:2013 Adhesives - Short term method for measuring the emission properties of low-solvent or solvent-free adhesives after application - Part 1: General procedure
    EN ISO 16017-1:2000 Indoor, ambient and workplace air - Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography - Part 1: Pumped sampling (ISO 16017-1:2000)
    ISO 16017-1:2000 Indoor, ambient and workplace air — Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography — Part 1: Pumped sampling
    ISO 16702:2007 Workplace air quality — Determination of total organic isocyanate groups in air using 1-(2-methoxyphenyl)piperazine and liquid chromatography
    ISO 16017-2:2003 Indoor, ambient and workplace air — Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography — Part 2: Diffusive sampling
    EN ISO 16017-2:2003 Indoor, ambient and workplace air - Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography - Part 2: Diffusive sampling (ISO 16017-2:2003)
    EN ISO 16000-9:2006/AC:2007 INDOOR AIR - PART 9: DETERMINATION OF THE EMISSION OF VOLATILE ORGANIC COMPOUNDS FROM BUILDING PRODUCTS AND FURNISHING - EMISSION TEST CHAMBER METHOD
    ISO 16000-9:2006 Indoor air — Part 9: Determination of the emission of volatile organic compounds from building products and furnishing — Emission test chamber method
    EN 923 : 2015 COR 2016 ADHESIVES - TERMS AND DEFINITIONS
    EN 1232:1997 Workplace atmospheres - Pumps for personal sampling of chemical agents - Requirements and test methods
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