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EN 14791:2017

Current

Current

The latest, up-to-date edition.

Stationary source emissions - Determination of mass concentration of sulphur oxides - Standard reference method

Published date

11-01-2017

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European foreword
1 Scope
2 Normative references
3 Terms and definitions
4 Symbols and abbreviations
5 Principle
6 Description of measuring system
7 Performance characteristics of the SRM
8 Field operation
9 Analytical procedure
10 Expression of results
11 Equivalence of Thorin and ion chromatography methods
12 Equivalence of an alternative method
13 Measurement report
Annex A (informative) - Validation of the method in the field
Annex B (informative) - Examples of absorbers
Annex C (informative) - Example of assessment of compliance of
        standard reference method for SO[2] with requirements on
        emission measurements
Annex D (informative) - Type of sampling equipment
Annex E (informative) - Example of comparison of repeatability and
        trueness of Thorin Method and Ion Chromatography Method
Annex F (informative) - Calculation of the uncertainty associated
        with a concentration expressed on dry gas and at an oxygen
        reference concentration
Annex G (informative) - Significant technical changes
Bibliography

This European Standard specifies the standard reference method (SRM) for the determination of the sulphuric oxide SO2 in flue gases emitted to the atmosphere from ducts and stacks. It is based on a sampling system and two analytical principles: ion chromatography and the Thorin method. This European Standard specifies the performance characteristics to be determined and the performance criteria to be fulfilled by measuring systems based on the measurement method. It applies to periodic monitoring and to the calibration or control of automatic measuring systems (AMS) permanently installed on a stack, for regulatory or other purposes. This European Standard specifies criteria for demonstration of equivalence of an alternative method to the SRM by application of prEN 14793.This European Standard has been evaluated during field tests on waste incineration, co-incineration and large combustion installations. It has been validated for sampling periods of 30 min in the range of 0,5 mg/m³ to 2 000 mg/m³ of SO2 for an ion-chromatography variant and 5 mg/m³ to 2 000 mg/m³ of SO2 for the Thorin method according to emission limit values laid down in the Directive 2010/75/EC.The limit values of EU Directives are expressed in units of mg/m³ of SO2 on dry basis and at standard conditions of 273 K and 101,3 kPa.NOTEThe characteristics of installations, the conditions during field tests and the values of repeatability and reproducibility in the field are given in Annex E.

Committee
CEN/TC 264
DevelopmentNote
Supersedes PREN 14791. (01/2017)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Current
Supersedes

Standards Relationship
DIN EN 14791:2017-05 Identical
NF EN 14791 : 2017 Identical
UNE-EN 14791:2017 Identical
NBN EN 14791 : 2006 Identical
UNI EN 14791 : 2006 Identical
PN EN 14791 : 2017 Identical
DIN EN 14791:2006-04 Identical
UNE-EN 14791:2006 Identical
NS EN 14791 : 2017 Identical
NEN EN 14791 : 2017 Identical
I.S. EN 14791:2017 Identical
SN EN 14791 : 2017 Identical
BS EN 14791:2017 Identical

DIN EN 14790:2006-04 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE WATER VAPOUR IN DUCTS - STANDARD REFERENCE METHOD
CEN/TS 17021:2017 Stationary source emissions - Determination of the mass concentration of sulphur dioxide by instrumental techniques
DIN EN 15267-4:2015-08 (Draft) AIR QUALITY - CERTIFICATION OF AUTOMATED MEASURING SYSTEMS - PART 4: PERFORMANCE CRITERIA AND TEST PROCEDURES FOR AUTOMATED MEASURING SYSTEMS FOR PERIODIC MEASUREMENTS OF EMISSIONS FROM STATIONARY SOURCES
PD CEN/TS 17021:2017 Stationary source emissions. Determination of the mass concentration of sulphur dioxide by instrumental techniques
I.S. EN 14790:2017 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE WATER VAPOUR IN DUCTS - STANDARD REFERENCE METHOD
VDI 3890:2016-03 Emission control - Pet cremation facilities
VDI 3460 Blatt 1:2014-02 Emission control - Thermal waste treatment - Fundamentals
VDI 2283:2008-06 Emission control - Preparation plants for ready-mix asphalt (asphalt mixing plants)
VDI 3476 Blatt 1:2015-06 Waste gas cleaning - Methods of catalytic waste gas cleaning - Fundamentals
VDI 2441:2016-05 Process gas and waste gas cleaning by cold plasma - Barrier discharge, corona discharge, UV radiation
VDI 3899 Blatt 1:2016-05 Emission control - Landfill gas - Utilisation and treatment of landfill gas
VDI 2447:2011-04 Emission control - Plants to the production and processing of acrylonitrile (AN)
VDI 4219:2009-08 Determination of the uncertainty of emission measurements by use of discontinuous measurement methods
VDI 2293:2011-09 Emission control - Coal preparation plants including driers
VDI 2462 Blatt 2:1974-02 Gaseous emission measurement; determination of sulphur dioxide; titrimetric hydrogen peroxide method
VDI 2578:2017-05 Emission control - Glassworks
VDI 2594:2015-09 Emission control - Pulp production in the sugar industry
VDI 3898:2013-01 Emission control - Plants for dry mechanical, physio-chemical, thermal and biological soil treatment
VDI 2102 Blatt 1:2007-04 (Draft) Emission control - Secondary copper smelting and refining plants
VDI 3475 Blatt 5:2015-10 Emission control - Biological waste treatment facilities - Anaerobic digestion and post-treatment
VDI 3454 Blatt 2:2012-04 Emission control - Claus units - Emission measurement
VDI 3476 Blatt 2:2010-01 Waste gas cleaning - Catalytic waste gas cleaning methods - Oxidative processes
UNE-EN 15267-4:2018 Air quality - Certification of automated measuring systems - Part 4: Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
BS EN 15267-4:2017 Air quality. Certification of automated measuring systems Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
I.S. EN 15267-4:2017 AIR QUALITY - CERTIFICATION OF AUTOMATED MEASURING SYSTEMS - PART 4: PERFORMANCE CRITERIA AND TEST PROCEDURES FOR AUTOMATED MEASURING SYSTEMS FOR PERIODIC MEASUREMENTS OF EMISSIONS FROM STATIONARY SOURCES
I.S. CEN/TS 17021:2017 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF SULPHUR DIOXIDE BY INSTRUMENTAL TECHNIQUES
S.R. CWA 16060:2009 ENVIRONMENTAL TECHNOLOGY VERIFICATION - AIR EMISSION ABATEMENT TECHNOLOGIES
UNE-EN 14790:2017 Stationary source emissions - Determination of the water vapour in ducts - Standard reference method
BS EN 14790:2005 Stationary source emissions. Determination of the water vapour in ducts
EN 14790:2017 Stationary source emissions - Determination of the water vapour in ducts - Standard reference method
EN 15267-4:2017 Air quality - Certification of automated measuring systems - Part 4: Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources
UNE-CWA 16060:2010 IN Environmental technology verification - Air emission abatement technologies
DIN EN 14790:2017-05 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE WATER VAPOUR IN DUCTS - STANDARD REFERENCE METHOD
NS-EN 15267-4:2023 Air quality - Assessment of air quality monitoring equipment - Part 4: Performance criteria and test procedures for portable automated measuring systems for periodic measurements of emissions from stationary sources

CEN/TS 15675:2007 Air quality - Measurement of stationary source emissions - Application of EN ISO/IEC 17025:2005 to periodic measurements
ISO 14956:2002 Air quality — Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty
ISO 5725-6:1994 Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values
EN 15259:2007 Air quality - Measurement of stationary source emissions - Requirements for measurement sections and sites and for the measurement objective, plan and report
ISO/IEC Guide 99:2007 International vocabulary of metrology Basic and general concepts and associated terms (VIM)
PREN 13284-1 : DRAFT 2015 STATIONARY SOURCE EMISSIONS - DETERMINATION OF LOW RANGE MASS CONCENTRATION OF DUST - PART 1: MANUAL GRAVIMETRIC METHOD
EN ISO 14956:2002 Air quality - Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty (ISO 14956:2002)
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
ISO/IEC Guide 98-3:2008 Uncertainty of measurement — Part 3: Guide to the expression of uncertainty in measurement (GUM:1995)
EN 14793:2017 Stationary source emissions - Demonstration of equivalence of an alternative method with a reference method

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