EN 15527:2008
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
View Superseded by
Characterization of waste - Determination of polycyclic aromatic hydrocarbons (PAH) in waste using gas chromatography mass spectrometry (GC/MS)
25-02-2022
09-07-2008
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Principle
5 Reagents
5.1 General
5.2 Reagents for extraction procedures
5.3 Reagents for clean-up procedures
5.4 Reagents for gas chromatographic analysis
5.5 Standards
6 Apparatus
6.1 Extraction and clean-up procedures
6.2 Gas chromatograph
6.3 Capillary columns
6.4 Preparation of standard solutions
7 Hazards
8 Interference
8.1 Interference during sampling, storage and extraction
8.2 Interference due to co-elution
9 Sample conservation
10 Pretreatment
10.1 General
10.2 Drying
10.3 Particle size reduction
11 Procedure
11.1 Blank
11.2 Extraction
11.3 Addition of the internal standard solution
11.4 Concentration or dilution
11.5 Clean up of the extract
11.6 Addition of the injection standard
11.7 Gas chromatographic analysis with mass spectrometric
detection
12 Performance characteristics
13 Test report
Annex A (informative) Representative chromatograms
Annex B (informative) Additional validation data
Annex C (informative) Summary of general requirements and
recommendations
Bibliography
This European Standard specifies the quantitative determination of 16 polynuclear aromatic hydrocarbons (PAH) according to the priority list of the Environmental Protection Agency (EPA, 1982). This European Standard is applicable for wastes such as contaminated soil, sludge and rubble, bitumen or waste containing bitumen.This European Standard describes a gas chromatographic method with mass spectrometric detection (GC-MS). Under the conditions specified in this document, a typical lower limit of application of 0,1 mg/kg for each individual PAH can be achieved. NOTE 1This method may be applied to the analysis of other PAH compounds not specified in the scope provided its applicability has been proven by proper in-house validation experiments.NOTE 2For some materials, e. g. bitumen, the lower limit of application of 0,1 mg/kg cannot be achieved due to interferences.NOTE 3Under certain circumstances the method may be applicable to PAH concentrations lower than 0,1 mg/kg but it is in the responsibility of the laboratory to provide proper validation data for such low concentrations.
Committee |
CEN/TC 444
|
DocumentType |
Standard
|
PublisherName |
Comite Europeen de Normalisation
|
Status |
Superseded
|
SupersededBy |
Standards | Relationship |
ONORM EN 15527 : 2008 | Identical |
UNE-EN 15527:2008 | Identical |
I.S. EN 15527:2008 | Identical |
DIN EN 15527:2008-09 | Identical |
NS EN 15527 : 1ED 2008 | Identical |
NF EN 15527 : 2008 | Identical |
NEN EN 15527 : 2008 | Identical |
PN EN 15527 : 2008 | Identical |
NBN EN 15527 : 2008 | Identical |
BS EN 15527:2008 | Identical |
SN EN 15527 : 2008 | Identical |
UNI EN 15527 : 2008 | Identical |
17/30364005 DC : 0 | BS EN 16181 - SOIL, TREATED BIOWASTE AND SLUDGE - DETERMINATION OF POLYCYCLIC AROMATIC HYDROCARBONS (PAH) BY GAS CHROMATOGRAPHY (GC) AND HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC) |
DIN EN 16691:2015-12 | WATER QUALITY - DETERMINATION OF SELECTED POLYCYCLIC AROMATIC HYDROCARBONS (PAH) IN WHOLE WATER SAMPLES - METHOD USING SOLID PHASE EXTRACTION (SPE) WITH SPE-DISKS COMBINED WITH GAS CHROMATOGRAPHY-MASS SPECTROMETRY (GC-MS) |
UNI EN 16457 : 2014 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
I.S. EN 16457:2014 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
S.R. CEN/TS 16181:2013 | SLUDGE, TREATED BIOWASTE AND SOIL - DETERMINATION OF POLYCYCLIC AROMATIC HYDROCARBONS (PAH) BY GAS CHROMATOGRAPHY (GC) AND HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC) |
UNE-EN 16457:2014 | Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report |
UNI CEN/TS 16181 : 2013 | SLUDGE, TREATED BIOWASTE AND SOIL - DETERMINATION OF POLYCYCLIC AROMATIC HYDROCARBONS (PAH) BY GAS CHROMATOGRAPHY (GC) AND HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC) |
EN 16691:2015 | Water quality - Determination of selected polycyclic aromatic hydrocarbons (PAH) in whole water samples - Method using solid phase extraction (SPE) with SPE-disks combined with gas chromatography mass spectrometry (GC-MS) |
BS EN 16691:2015 | Water quality. Determination of selected polycyclic aromatic hydrocarbons (PAH) in whole water samples. Method using solid phase extraction (SPE) with SPE-disks combined with gas chromatography mass spectrometry (GC-MS) |
12/30263896 DC : 0 | BS EN 16457 - CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
UNE-EN 16691:2016 | Water quality - Determination of selected polycyclic aromatic hydrocarbons (PAH) in whole water samples - Method using solid phase extraction (SPE) with SPE-disks combined with gas chromatography mass spectrometry (GC-MS) |
DIN EN 16457:2014-07 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
I.S. EN 16691:2015 | WATER QUALITY - DETERMINATION OF SELECTED POLYCYCLIC AROMATIC HYDROCARBONS (PAH) IN WHOLE WATER SAMPLES - METHOD USING SOLID PHASE EXTRACTION (SPE) WITH SPE-DISKS COMBINED WITH GAS CHROMATOGRAPHY MASS SPECTROMETRY (GC-MS) |
ISO 13859:2014 | Soil quality — Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC) |
12/30231382 DC | BS ISO 13859. Soil quality. Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC) |
EN 16457:2014 | Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report |
DIN EN 16457 E : 2014 | CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT |
BS EN 16457:2014 | Characterization of waste. Framework for the preparation and application of a testing programme. Objectives, planning and report |
10/30147451 DC : 0 | EN 16181 - SLUDGE, TREATED BIOWASTE AND SOIL - DETERMINATION OF POLYCYCLIC AROMATIC HYDROCARBONS (PAH) BY GAS CHROMATOGRAPHY (GC) AND HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC) POLYCYCLIC AROMATIC HYDROCARBONS |
CEN/TS 16181:2013 | Sludge, treated biowaste and soil - Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC) |
ISO 22892:2006 | Soil quality Guidelines for the identification of target compounds by gas chromatography and mass spectrometry |
ISO 18287:2006 | Soil quality Determination of polycyclic aromatic hydrocarbons (PAH) Gas chromatographic method with mass spectrometric detection (GC-MS) |
EN 14346:2006 | Characterization of waste - Calculation of dry matter by determination of dry residue or water content |
ISO 16720:2005 | Soil quality Pretreatment of samples by freeze-drying for subsequent analysis |
EN ISO 16720:2007 | Soil quality - Pretreatment of samples by freeze-drying for subsequent analysis (ISO 16720:2005) |
ISO 14507:2003 | Soil quality Pretreatment of samples for determination of organic contaminants |
EN 15002:2015 | Characterization of waste - Preparation of test portions from the laboratory sample |
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