• EN 16135:2011

    Current The latest, up-to-date edition.

    Automotive fuels - Determination of manganese content in unleaded petrol - Flame atomic absorption spectrometric method (FAAS)

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    Published date:  06-12-2011

    Publisher:  Comite Europeen de Normalisation

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    Table of Contents - (Show below) - (Hide below)

    Foreword
    1 Scope
    2 Normative references
    3 Principle
    4 Reagents
    5 Apparatus
    6 Sampling
    7 Preparation of solutions
    8 Calibration
    9 Sample analysis
    10 Calculation
    11 Expression of results
    12 Precision
    13 Test report
    Bibliography

    Abstract - (Show below) - (Hide below)

    This European Standard specifies a method based on flame atomic absorption spectrometry (FAAS) for the determination of manganese content as methylcyclopentadienyl manganese tricarbonyl (MMT )) in unleaded petrol from about 2 mg/l to about 8 mg/l. This test method is applicable to unleaded petrol containing up to 3,7 % (m/m) oxygen, including those with ethanol up to 10 % (V/V).NOTE 1Manganese as MMT is added to petrol to increase antiknock properties.WARNING - The use of this European Standard may involve hazardous materials, operations and equipment. This European Standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this European Standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.NOTE 2Solutions of MMT in unleaded petrol are unstable when exposed to light. Low and erratic results are expected if samples are exposed to light prior the analysis.NOTE 3Manganese contents higher than 8 mg/l can be measured after preliminary dilution of the sample with a suitable solvent. However, the precision has not been established for such procedure.NOTE 4Application to the determination of other manganese compounds in unleaded petrol has not been tested.NOTE 5For the purposes of this European Standard, the terms "% (m/m)" and "% (V/V)" are used to represent the mass fraction (µ) and the volume fraction of a material respectively.

    General Product Information - (Show below) - (Hide below)

    Committee CEN/TC 19
    Development Note Supersedes PREN 16135. (12/2011)
    Document Type Standard
    Publisher Comite Europeen de Normalisation
    Status Current
    Supersedes

    Standards Referenced By This Book - (Show below) - (Hide below)

    I.S. EN 228:2017 AUTOMOTIVE FUELS - UNLEADED PETROL - REQUIREMENTS AND TEST METHODS
    DIN EN 228:2004-03 AUTOMOTIVE FUELS - UNLEADED PETROL - REQUIREMENTS AND TEST METHODS
    DIN EN 228:2017-08 AUTOMOTIVE FUELS - UNLEADED PETROL - REQUIREMENTS AND TEST METHODS
    EN 228:2012+A1:2017 Automotive fuels - Unleaded petrol - Requirements and test methods
    PD CEN/TR 16514:2013 Automotive fuels. Unleaded petrol containing more than 3,7 % (m/m) oxygen. Roadmap, test methods, and requirements for E10+ petrol
    S.R. CEN/TR 16514:2013 AUTOMOTIVE FUELS - UNLEADED PETROL CONTAINING MORE THAN 3,7% (M/M) OXYGEN - ROADMAP, TEST METHODS, AND REQUIREMENTS FOR E10+ PETROL
    CEN/TR 16514 : 2013 AUTOMOTIVE FUELS - UNLEADED PETROL CONTAINING MORE THAN 3,7% (M/M) OXYGEN - ROADMAP, TEST METHODS, AND REQUIREMENTS FOR E10+ PETROL
    UNE-EN 228:2013 Automotive fuels - Unleaded petrol - Requirements and test methods

    Standards Referencing This Book - (Show below) - (Hide below)

    ISO 3171:1988 Petroleum liquids — Automatic pipeline sampling
    ISO 3170:2004 Petroleum liquids — Manual sampling
    ISO 3675:1998 Crude petroleum and liquid petroleum products Laboratory determination of density Hydrometer method
    ISO 1042:1998 Laboratory glassware One-mark volumetric flasks
    ISO 648:2008 Laboratory glassware — Single-volume pipettes
    EN ISO 12185:1996 Crude petroleum and petroleum products - Determination of density - Oscillating U-tube method (ISO 12185:1996)
    EN ISO 648:2008 Laboratory glassware - Single-volume pipettes (ISO 648:2008)
    EN ISO 3675:1998 Crude petroleum and liquid petroleum products - Laboratory determination of density - Hydrometer method (ISO 3675:1998)
    EN ISO 1042 : 1999 LABORATORY GLASSWARE - ONE-MARK VOLUMETRIC FLASKS
    ISO 12185:1996 Crude petroleum and petroleum products — Determination of density — Oscillating U-tube method
    ISO 4259:2006 Petroleum products Determination and application of precision data in relation to methods of test
    EN ISO 3170:2004 Petroleum liquids - Manual sampling (ISO 3170:2004)
    EN ISO 3171:1999 Petroleum liquids - Automatic pipeline sampling (ISO 3171:1988)
    EN ISO 4259:2006 Petroleum products - Determination and application of precision data in relation to methods of test (ISO 4259:2006)
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