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EN 1948-3:2006
Current
The latest, up-to-date edition.
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Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 3: Identification and quantification of PCDDs/PCDFs
15-03-2006
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Symbols and abbreviations
5 Principles of identification and quantification
6 Reagents, materials and equipment
7 Safety measures
8 Quality control requirements for identification and
quantification
9 Quality assurance criteria for extraction/clean-up/quantification
procedure blanks
10 Calibration of the HRGC/HRMS
11 Quantification of HRGC/HRMS results
12 Calculation of the measurement results
13 Analytical report
14 Performance characteristics
15 Interferences
Annex A (informative) Examples of operation of gas
chromatography/mass spectrometry analysis of
PCDDs/PCDFs in emission samples
Annex B (informative) Estimation of the measuring
uncertainty and precision of the determination of
polychlorinated dibenzo-p-dioxins and dibenzofurans
Annex C (informative) Mass of ions monitored for PCDDs and PCDFs
Annex D (informative) Relative abundance of chlorine isotope ions
and their ratio for PCDD/PCDF congeners containing 4 to
8 chlorine substituents
Annex E (informative) Further general recommendations for
separation, detection and quantification of PCDDs/PCDFs
Annex F (informative) Variability determination based on the
results of the validation tests
Annex G (informative) Relation to EU Directives
Bibliography
This European Standard specifies the identification and quantification procedures of the sampled PCDDs/PCDFs. It is an integral part of the complete measurement procedure. The use of the other two parts of this standard, prEN 1948-1:2005 and prEN 1948-2:2005, describing sampling and extraction and clean-up, respectively, is necessary for the determination of the PCDDs/PCDFs.This European Standard has been designed to measure PCDD/PCDF concentrations at about 0,1 ng I-TEQ/m3 in stationary source emissions.This European Standard specifies both method validation and a framework of quality control requirements which shall be fulfilled by any PCDD/PCDF identification and quantification methods to be applied. Some methods are described in detail in Annex A as examples of proven procedures.Each of the three sampling methods (Part 1) can be combined with the extraction and clean-up (Part 2) and the identification and quantification (Part 3) to complete the measurement procedure.During comparison measurements of the three sampling methods on municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 these methods have been deemed comparable within the expected range of uncertainty. Validation trials were performed on the flue gas of municipal waste incinerators at the level of about 0,1 ng I-TEQ/m3 and a dust loading of from 1 mg/m3 to 15 mg/m3. Although this European Standard is primarily developed and validated for gaseous streams emitted by waste incinerators, the practical experience shows that it can be applied for wide concentration ranges and various emission sources.The procedure described in the three parts of prEN 1948:2005 specifies requirements in order to measure every 2,3,7,8-chlorine substituted PCDD/PCDF congener required to calculate the total I-TEQ (see Table A.1 of prEN 1948-1:2005).Besides the determination of PCDDs/PCDFs the described measurement methods are suitable for determination of other low-volatile substances, e.g. of dioxin-
Committee |
CEN/TC 264
|
DocumentType |
Standard
|
PublisherName |
Comite Europeen de Normalisation
|
Status |
Current
|
Standards | Relationship |
DIN EN 1948-3:2006-06 | Identical |
SN EN 1948-3 : 2006 | Identical |
NF EN 1948-2 : 2006 | Identical |
UNI EN 1948-3 : 2006 | Identical |
UNE-EN 1948-3:2007 | Identical |
NF EN 1948-3 : 2006 | Identical |
NEN EN 1948-3 : 2006 | Identical |
PN EN 1948-3 : 2006 | Identical |
NS EN 1948-3 : 2ED 2006 | Identical |
NBN EN 1948-3 : 2006 | Identical |
BS EN 1948-3:2006 | Identical |
I.S. EN 1948-3:2006 | Identical |
DD CEN/TS 1948-4:2007 | Stationary source emissions. Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs Sampling and analysis of dioxin-like PCBs |
PD CEN/TS 1948-5:2015 | Stationary source emissions. Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs Long-term sampling of PCDDs/PCDFs and PCBs |
BS ISO 18073:2004 | Water quality. Determination of tetra- to octa-chlorinated dioxins and furans. Method using isotope dilution HRGC/HRMS |
S.R. CEN TS 1948-4:2007 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 4: SAMPLING AND ANALYSIS OF DIOXIN-LIKE PCBS |
ISO 18073:2004 | Water quality — Determination of tetra- to octa-chlorinated dioxins and furans — Method using isotope dilution HRGC/HRMS |
BS 6068-2.90(2004) : 2004 | WATER QUALITY - DETERMINATION OF TETRA- TO OCTA-CHLORINATED DIOXINS AND FURANS - METHOD USING ISOTOPE DILUTION HRGC/HRMS |
ISO 16000-14:2009 | Indoor air Part 14: Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) Extraction, clean-up and analysis by high-resolution gas chromatography and mass spectrometry |
UNI CEN/TS 16190 : 2012 | SLUDGE, TREATED BIOWASTE AND SOIL - DETERMINATION OF DIOXINS AND FURANS AND DIOXIN-LIKE POLYCHLORINATED BIPHENYLS BY GAS CHROMATOGRAPHY WITH HIGH RESOLUTION MASS SELECTIVE DETECTION (HR GC-MS) |
CEN/TS 1948-5:2015 | Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 5: Long-term sampling of PCDDs/PCDFs and PCBs |
EN 1948-4:2010+A1:2013 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 4: SAMPLING AND ANALYSIS OF DIOXIN-LIKE PCBS |
CEN/TS 15675:2007 | Air quality - Measurement of stationary source emissions - Application of EN ISO/IEC 17025:2005 to periodic measurements |
03/320960 DC : DRAFT NOV 2003 | EN 1948-1 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 1: SAMPLING |
I.S. EN 1948-4:2010 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 4: SAMPLING AND ANALYSIS OF DIOXIN-LIKE PCBS |
BS ISO 13914:2013 | Soil quality. Determination of dioxins and furans and dioxin-like polychlorinated biphenyls by gas chromatography with high-resolution mass selective detection (GC/HRMS) |
S.R. CEN TS 15675:2007 | AIR QUALITY - MEASUREMENT OF STATIONARY SOURCE EMISSIONS - APPLICATION OF EN ISO/IEC 17025:2005 TO PERIODIC MEASUREMENTS |
PREN 16190 : DRAFT 2017 | SOIL, TREATED BIOWASTE AND SLUDGE - DETERMINATION OF DIOXINS AND FURANS AND DIOXIN-LIKE POLYCHLORINATED BIPHENYLS BY GAS CHROMATOGRAPHY WITH HIGH RESOLUTION MASS SELECTIVE DETECTION (HR GC-MS) |
I.S. EN 1948-1:2006 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 1: SAMPLING OF PCDDS/PCDFS |
DIN EN 1948-2:2006-06 | Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 2: Extraction and clean-up of PCDDs/PCDFs |
I.S. EN 1948-2:2006 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 2: EXTRACTION AND CLEAN-UP OF PCDDS/PCDFS |
DIN EN 1948-1:2006-06 | Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 1: Sampling of PCDDs/PCDFs |
I.S. EN 1948-3:2006 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 3: IDENTIFICATION AND QUANTIFICATION OF PCDDS/PCDFS |
VDI 3927 Blatt 2:2015-05 | Waste gas cleaning - Reduction of inorganic and organic trace species in combustion flue gases |
VDI 3890:2016-03 | Emission control - Pet cremation facilities |
VDI 2597:2004-07 | Emission control - Plants for the production of lead and lead alloys |
VDI 3476 Blatt 1:2015-06 | Waste gas cleaning - Methods of catalytic waste gas cleaning - Fundamentals |
VDI 3891:2015-07 | Emission control - Human cremation facilities |
VDI 3498 Blatt 2:2002-07 | Ambient air measurement - Indoor air measurement - Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans; Method using small filters |
VDI 3899 Blatt 1:2016-05 | Emission control - Landfill gas - Utilisation and treatment of landfill gas |
VDI 3498 Blatt 1:2002-07 | Ambient air measurement - Indoor air measurement - Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans; Method using large filters |
VDI 3475-3 : 2006 COR 2007 | Emission control - Mechnical-biological treatment facilities for municipal solid waste - Corrigendum concerning guideline VDI 3475 Part 3:2006-12 |
VDI 2578:2017-05 | Emission control - Glassworks |
VDI 3957 Blatt 5:2001-01 (Draft) | Biological measuring techniques for the determination and evaluation of effects of air pollutants on plants (bioindication) - Standardised exposure of spruce |
VDI 2262 Blatt 1:2013-06 | Workplace air - Reduction of exposure to air pollutants - Legal principles, terms and definitions, basic organisational measures for industrial safety and environmental protection |
VDI 3898:2013-01 | Emission control - Plants for dry mechanical, physio-chemical, thermal and biological soil treatment |
VDI 2102 Blatt 1:2007-04 (Draft) | Emission control - Secondary copper smelting and refining plants |
VDI 3476 Blatt 2:2010-01 | Waste gas cleaning - Catalytic waste gas cleaning methods - Oxidative processes |
09/30198710 DC : 0 | BS EN 1948-4 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 4: SAMPLING AND ANALYSIS OF DIOXIN-LIKE PCBS |
12/30231398 DC : 0 | BS ISO 13914 - SOIL QUALITY - DETERMINATION OF DIOXINS AND FURANS AND DIOXIN-LIKE POLYCHLORINATED BIPHENYLS BY GAS CHROMATOGRAPHY WITH HIGH-RESOLUTION MASS SELECTIVE DETECTION (HR GC/MS) |
DIN EN 1948-4:2014-03 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 4: SAMPLING AND ANALYSIS OF DIOXIN-LIKE PCBS |
BS EN 1948-3:2006 | Stationary source emissions. Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs Identification and quantification of PCDDs/PCDFs |
EN 1948-2:2006 | Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 2: Extraction and clean-up of PCDDs/PCDFs |
UNI EN 1948-2 : 2006 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 2: EXTRACTION AND CLEAN-UP OF PCDDS/PCDFS |
UNI EN 1948-1 : 2006 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 1: SAMPLING OF PCDDS/PCDFS |
DD CEN/TS 15675:2007 | Air quality. Measurement of stationary source emissions. Application of EN ISO/IEC 17025:2005 to periodic measurements |
BS ISO 16000-14:2009 | Indoor air Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs). Extraction, clean-up and analysis by high-resolution gas chromatography and mass spectrometry |
UNE-EN 1948-4:2011 | Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 4: Sampling and analysis of dioxin-like PCBs |
03/320961 DC : DRAFT NOV 2003 | EN 1948-2 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 2: EXTRACTION AND CLEAN-UP OF PCDDS/PCDFS |
BS EN 1948-2:2006 | Stationary source emissions. Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs Extraction and clean-up of PCDDs/PCDFs |
EN 1948-1:2006 | Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 1: Sampling of PCDDs/PCDFs |
07/30146333 DC : 0 | BS ISO 16000-14 - INDOOR AIR - PART 14: DETERMINATION OF TOTAL (GAS AND PARTICLE-PHASE) POLYCHLORINATED DIOXIN-LIKE BIPHENYLS (PCBS) AND POLYCHLORINATED DIBENZO-P-DIOXINS/DIBENZOFURANS (PCDDS/PCDFS) - EXTRACTION, CLEAN-UP AND ANALYSIS BY HIGH-RESOLUTION GAS CHROMATOGRAPHY/MASS SPECTROMETRY |
BS EN 1948-4 : 2010 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 4: SAMPLING AND ANALYSIS OF DIOXIN-LIKE PCBS |
S.R. CEN/TS 16190:2012 | SLUDGE, TREATED BIOWASTE AND SOIL - DETERMINATION OF DIOXINS AND FURANS AND DIOXIN-LIKE POLYCHLORINATED BIPHENYLS BY GAS CHROMATOGRAPHY WITH HIGH RESOLUTION MASS SELECTIVE DETECTION (HR GC-MS) |
DIN ISO 16000-14:2012-03 | Indoor air - Part 14: Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) - Extraction, clean-up and analysis by high-resolution gas chromatography and mass spectrometry (ISO 16000-14:2009) |
17/30363999 DC : 0 | BS EN 16190 - SOIL, TREATED BIOWASTE AND SLUDGE - DETERMINATION OF DIOXINS AND FURANS AND DIOXIN-LIKE POLYCHLORINATED BIPHENYLS BY GAS CHROMATOGRAPHY WITH HIGH RESOLUTION MASS SELECTIVE DETECTION (HR GC-MS) |
S.R. CEN/TS 1948-5:2015 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 5: LONG-TERM SAMPLING OF PCDDS/PCDFS AND PCBS |
UNI EN 1948-4 : 2014 | STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 4: SAMPLING AND ANALYSIS OF DIOXIN-LIKE PCBS |
ISO 13914:2013 | Soil quality — Determination of dioxins and furans and dioxin-like polychlorinated biphenyls by gas chromatography with high-resolution mass selective detection (GC/HRMS) |
CEN/TS 16190:2012 | Sludge, treated biowaste and soil - Determination of dioxins and furans and dioxin-like polychlorinated biphenyls by gas chromatography with high resolution mass selective detection (HR GC-MS) |
CEN/TS 1948-4:2007 | Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 4: Sampling and analysis of dioxin-like PCBs |
EN 1948-2:2006 | Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 2: Extraction and clean-up of PCDDs/PCDFs |
EN 13284-1:2017 | Stationary source emissions - Determination of low range mass concentration of dust - Part 1: Manual gravimetric method |
EN 1948-1:2006 | Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 1: Sampling of PCDDs/PCDFs |
XP X43 331 : 96 XP | AIR QUALITY - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE CONFIDENCE INTERVAL OF A MEASUREMENT METHOD IN THE ABSENCE OF A REFERENCE SAMPLE BY SIMULTANEOUS PARALLEL MEASUREMENTS |
ISO 5725-2:1994 | Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method |
ENV 13005 : DRAFT 1999 | GUIDE TO THE EXPRESSION OF UNCERTAINTY IN MEASUREMENT |
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