• Shopping Cart
    There are no items in your cart

ASTM D 7423 : 2017

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by

Standard Test Method for Determination of Oxygenates in C2, C3, C4, and C5 Hydrocarbon Matrices by Gas Chromatography and Flame Ionization Detection

Available format(s)

Hardcopy , PDF

Superseded date

20-03-2023

Superseded by

ASTM D 7423 : 2023

Language(s)

English

Published date

10-07-2017

€67.30
Excluding VAT

This test method covers the gas chromatographic procedure for the quantitative determination of organic oxygenates in C2, C3, C4, and C5 matrices by multidimensional gas chromatography and flame ionization detection.

Committee
D 02
DocumentType
Test Method
Pages
9
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

1.1This test method covers the gas chromatographic procedure for the quantitative determination of organic oxygenates in C2, C3, C4, and C5 matrices by multidimensional gas chromatography and flame ionization detection. This test method is applicable when the hydrocarbon matrices have a final boiling point not greater than 200 °C. Oxygenate compounds include, but are not limited to, those listed in Table 1. The linear working range for oxygenates is 0.50 mg/kg to 100 mg/kg.

TABLE 1 Oxygenates and Typical Retention Times

Components

Retention Time (min)

Dimethyl ether

6.18

Diethyl ether

8.44

Acetaldehyde

8.89

Ethyl tert-butyl ether

10.66

Methyl tert-butyl ether (MTBE)

10.92

Diisopropyl ether

11.22

Propionaldehyde (Propanal)

12.00

Tertiary amyl methyl ether (TAME)

13.19

Propyl ether

14.00

Isobutylaldehyde

14.10

Butylaldehyde

14.50

Methanol

14.91

Acetone

15.39

Isovaleraldehyde

16.00

Valeraldehyde

16.10

2-Butanone (MEK)

17.14

Ethanol

17.51

N-propyl alcohol and isopropanol

19.20 (co-elution)

Allyl Alcohol

20.00

Isobutanol, Tert-butyl alcohol, Sec-Butanol

20.24 (co-elution)

N-butanol

20.84

1.2This test method is intended to determine the mass concentration of each oxygenate in the hydrocarbon matrix. Oxygenate compound identification is determined by reference standards and column elution retention order.

1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D 5273 : 2018 Standard Guide for Analysis of Propylene Concentrates

ASTM D 4175 : 2020 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2014 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2009 : REV A : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6300 : 2020 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2008 : REV B : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6849 : 2022 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
ASTM D 6300 : 2013 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2005 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6299 : 2010 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 6300 : 2014 : REV A : EDT 1 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 1265 : 1997 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
ASTM D 4175 : 2005 : EDT 2 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6299 : 2013 : EDT 1 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM E 177 : 1990 : REV A : R1996 Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods
ASTM D 4175 : 2015 : REV C Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6299 : 2017 : REV A Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2020 : REV B Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2017 : REV A : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6299 : 2017 : REV B Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 6300 : 2017 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 6299 : 2009 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 1835 : 1997 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 6849 : 2002 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
ASTM D 6300 : 2017 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2008 : REV A Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2020 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6299 : 2013 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2017 : REV B Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6299 : 2021 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2009 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6849 : 2002 : R2012 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
ASTM D 6299 : 2010 : EDT 1 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2022 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6299 : 2022 : EDT 1 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 6300 : 2016 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2009 : REV A : EDT 4 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2009 : REV A : EDT 3 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6849 : 2002 : R2007 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
ASTM D 6300 : 2004 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2018 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 1835 : 2018 : REV A Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 1835 : 2012 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 6300 : 2019 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2001 : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2020 : REV B : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2001 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2005 : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2022 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6300 : 2021 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6300 : 2019 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2002 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6849 : 2013 : R2021 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
ASTM D 6300 : 2020 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6299 : 2000 Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance
ASTM D 6299 : 2010 : EDT 2 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 6299 : 2016 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2015 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2002 : REV A : EDT 2 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6299 : 2019 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 1835 : 2003 : REV A Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 6300 : 2020 : REV B Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6299 : 2000 : REV A Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance
ASTM D 6300 : 2006 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2009 : REV A : EDT 5 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2016 : REV C Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2015 : REV B Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6300 : 2014 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM E 355 : 1996 : R2021 : EDT 1 Standard Practice for Gas Chromatography Terms and Relationships
ASTM D 1835 : 2003 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 6300 : 2015 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2015 : REV A Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6300 : 1999 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 1835 : 2013 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 4175 : 2009 : REV A Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 1835 : 2020 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 4175 : 2016 : REV B Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6299 : 2020 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2002 : REV A : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2008 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6299 : 2008 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 1835 : 2018 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 4175 : 2002 : REV A Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6849 : 2013 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
ASTM D 4175 : 2000 : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 4175 : 2016 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 1265 : 2004 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
ASTM D 6300 : 2013 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 6299 : 2002 : EDT 1 Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2019 : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 1835 : 2022 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 4175 : 2022 : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 1835 : 2016 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 6300 : 2008 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 6300 : 2003 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 1265 : 2011 : R2017 : EDT 1 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
ASTM D 6300 : 2007 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 6299 : 2022 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2017 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 1835 : 2011 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 1265 : 2005 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
ASTM D 6300 : 2002 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2009 : REV A : EDT 2 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 1265 : 2004 : REV A Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
ASTM D 1265 : 2011 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
ASTM D 4175 : 2018 : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2016 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6300 : 2016 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM E 355 : 1996 : R2014 Standard Practice for Gas Chromatography Terms and Relationships
ASTM D 6299 : 2007 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 6299 : 2007 : EDT 1 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 6299 : 2020 : REV A Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2017 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 1265 : 2022 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
ASTM D 6299 : 2017 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
ASTM D 4175 : 2019 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6300 : 2014 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
ASTM D 4175 : 2015 : REV B : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 1835 : 2005 Standard Specification for Liquefied Petroleum (LP) Gases
ASTM D 4175 : 2008 : REV B Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
ASTM D 6299 : 2002 Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance

Access your standards online with a subscription

Features

  • Simple online access to standards, technical information and regulations.

  • Critical updates of standards and customisable alerts and notifications.

  • Multi-user online standards collection: secure, flexible and cost effective.