BS EN ISO 16591:2010

Foreword
1 Scope
2 Normative references
3 Principle
4 Reagents and materials
5 Apparatus
6 Samples and sampling
7 Apparatus preparation
8 Apparatus verification and calibration curve
   construction
9 Procedure
10 Calculation
11 Expression of results
12 Precision
13 Test report
Annex A (informative) - Determination of sulfur
        contents below 1 mg/kg - Standby technique
Annex B (informative) - Troubleshooting
Annex C (informative) - Calculation of sulfur
        content from electrochemical data
Bibliography

Describes a method for the determination of the sulfur content by oxidative microcoulometry of petroleum light and middle distillates with a final boiling point not higher than 400 degrees C. Applies to materials with sulfur contents in the range of 1 mg/kg to 100 mg/kg. Products with sulfur contents above 100 mg/kg can be analysed after dilution with a suitable sulfur-free solvent. Products with sulfur contents below 1 mg/kg can also be analysed by a modified technique. The precision quoted only applies to measurements in the 1 mg/kg to 100 mg/kg range. Nitrogen interferes with the analysis at concentrations above 0,1% (m/m), and chlorine interferes at concentrations above 1,0% (m/m), but these interferences are overcome by the addition of sodium azide to the cell electrolyte. Bromine and organometallic compounds also interfere with the analysis at concentrations above approximately 500 mg/kg.

This International Standard specifies a method for the determination of the sulfur content by oxidative microcoulometry of petroleum light and middle distillates with a final boiling point not higher than 400°C. It is applicable to materials with sulfur contents in the range of 1mg/kg to 100mg/kg. Products with sulfur contents above 100mg/kg can be analysed after dilution with a suitable sulfur-free solvent. Products with sulfur contents below 1mg/kg can also be analysed by a modified technique described in AnnexA. The precision quoted only applies to measurements in the 1mg/kg to 100mg/kg range. Nitrogen interferes with the analysis at concentrations above 0,1%(m/m), and chlorine interferes at concentrations above 1,0%(m/m), but these interferences are overcome by the addition of sodium azide to the cell electrolyte. Bromine and organometallic compounds also interfere with the analysis at concentrations above approximately 500mg/kg.

NOTE1 The microcoulometric method is capable of analysing light liquid hydrocarbons boiling in the range from 26°C to 274°C (for example, naphtha and MS samples) that undergo pyrolysis at 900°C to 1200°C. The combustion of high boiling components (for example, diesel) can result in the formation of carbonaceous deposits in the inlet portion of the combustion tube, which need to be removed frequently.

NOTE2 The results obtained using this International Standard on light and light-middle distillates generally approximate to those obtained using ISO4260.

NOTE3 For the purposes of this International Standard, the term “%(m/m)” is used to represent the mass fraction of a material.