BS ISO 16000-3:2011
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
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Indoor air Determination of formaldehyde and other carbonyl compounds in indoor air and test chamber air. Active sampling method
Hardcopy , PDF
28-10-2022
English
31-10-2011
Foreword
Introduction
1 Scope
2 Normative references
3 Principle
4 Limitations and interferences
5 Safety measures
6 Apparatus
7 Reagents and materials
8 Preparation of reagents and cartridges
9 Procedure
10 Calculations
11 Performance criteria and quality assurance
12 Precision and uncertainty
13 Test report
Annex A (informative) - Precision and uncertainty
Annex B (informative) - Melting points of DNPH-carbonyl
derivatives
Bibliography
Describes a determination of formaldehyde (HCHO) and other carbonyl compounds (aldehydes and ketones) in air.
Committee |
EH/2/3
|
DevelopmentNote |
Supersedes 99/565435 DC. (01/2002) Supersedes 09/30195924 DC. (11/2011)
|
DocumentType |
Standard
|
Pages |
38
|
PublisherName |
British Standards Institution
|
Status |
Superseded
|
SupersededBy | |
Supersedes |
This part of ISO16000 specifies a determination of formaldehyde (HCHO) and other carbonyl compounds (aldehydes and ketones)1) in air. The method is specific to formaldehyde but, with modification, at least 12 other aromatic as well as saturated and unsaturated aliphatic carbonyl compounds can be detected and quantified. It is suitable for determination of formaldehyde and other carbonyl compounds in the approximate concentration range 1µg/m3 to 1mg/m3. The sampling method gives a time-weighted average (TWA) sample. It can be used for long-term (1h to 24h) or short-term (5min to 60min) sampling of air for formaldehyde. This part of ISO16000 specifies a sampling and analysis procedure for formaldehyde and other carbonyl compounds that involves collection from air on to adsorbent cartridges coated with 2,4-dinitrophenylhydrazine (DNPH) and subsequent analysis of the hydrazones formed by high performance liquid chromatography (HPLC) with detection by ultraviolet absorption[12],[16]. The method is not suitable for longer chained or unsaturated carbonyl compounds. This part of ISO16000 applies to the determination of: acetaldehydeacetone benzaldehyde butyraldehyde capronaldehyde 2,5-dimethylbenzaldehydeformaldehyde isovaleraldehyde propionaldehyde m-tolualdehydeo-tolualdehyde p-tolualdehyde valeraldehyde
Standards | Relationship |
ISO 16000-3:2011 | Identical |
ISO/IEC 17025:2005 | General requirements for the competence of testing and calibration laboratories |
ISO 16017-1:2000 | Indoor, ambient and workplace air — Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography — Part 1: Pumped sampling |
ISO 12219-4:2013 | Interior air of road vehicles — Part 4: Method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials — Small chamber method |
ISO 16017-2:2003 | Indoor, ambient and workplace air — Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography — Part 2: Diffusive sampling |
VDI 3862 Blatt 2:2000-12 | Gaseous emission measurement - Measurement of aliphatic and aromatic aldeydes and ketones by DNPH method - Impinger method |
ISO 8655-2:2002 | Piston-operated volumetric apparatus Part 2: Piston pipettes |
ASTM D 5197 : 2016 : REDLINE | Standard Test Method for Determination of Formaldehyde and Other Carbonyl Compounds in Air (Active Sampler Methodology) |
EN 1232:1997 | Workplace atmospheres - Pumps for personal sampling of chemical agents - Requirements and test methods |
VDI 3862 Blatt 3:2000-12 | Gaseous emission measurement - Measurement of aliphatic and aromatic aldehydes and ketones by DNPH method - Cartridges method |
ISO 12219-5:2014 | Interior air of road vehicles — Part 5: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials — Static chamber method |
ISO/IEC Guide 98-3:2008 | Uncertainty of measurement — Part 3: Guide to the expression of uncertainty in measurement (GUM:1995) |
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