BS ISO 5725-1:1994
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
View Superseded by
Accuracy (trueness and precision) of measurement methods and results General principles and definitions
Hardcopy , PDF
24-07-2023
English
15-03-2000
Committees responsible
National foreword
Foreword
Introduction
1 Scope
2 Normative references
3 Definitions
4 Practical implications of the definitions for
accuracy experiments
4.1 Standard measurement method
4.2 Accuracy experiment
4.3 Identical test items
4.4 Short intervals of time
4.5 Participating laboratories
4.6 Observation conditions
5 Statistical model
5.1 Basic model
5.2 Relationship between the basic model and the
precision
5.3 Alternative models
6 Experimental design considerations when estimating
accuracy
6.1 Planning of an accuracy experiment
6.2 Standard measurement method
6.3 Selection of laboratories for the accuracy
experiment
6.4 Selection of materials to be used for an
accuracy experiment
7 Utilization of accuracy data
7.1 Publication of trueness and precision values
7.2 Practical applications of trueness and
precision values
Annex A (normative) Symbols and abbreviations used in
ISO 5725
Annex B (normative) Charts of uncertainties for
precision measures
Annex C (informative) Bibliography
Figure B.1 - The amount by which sr can be expected to
differ from the true value within a
probability level of 95 %
Figure B.2 - The amount by which sR can be expected to
differ from the true value within a
probability level of 95 %
Table 1 - Values showing the uncertainty of estimates
of the repeatability and reproducibility
standard deviations
Table 2 - Values of A, the uncertainty of an estimate
of the bias of the measurement method
Table 3 - Values of AW, the uncertainty of the
within-laboratory bias
Table 4 - Example of method of reporting standard
deviations
Outlines the general principles to be understood when assessing accuracy of measurement methods and results. Concerned exclusively with measurement methods which yield measurements on a continuous scale and give a single value as the test result. Defines values which describe, in quantitative terms, the ability of a measurement method to give a correct result (trueness) or to replicate a given result (precision). Coverage includes: practical implications of the definitions for accuracy experiments; experimental design considerations when estimating accuracy; relationship between the basic model and the precision. Also gives definitions.
Committee |
SS/6
|
DevelopmentNote |
Together with BS ISO 5725-2, BS ISO 5725-3, BS ISO 5725-4, BS ISO 5725-5 and BS ISO 5725-6, supersedes BS 5497-1(1987) Supersedes 90/97778 DC (03/2002)
|
DocumentType |
Standard
|
Pages |
26
|
PublisherName |
British Standards Institution
|
Status |
Superseded
|
SupersededBy | |
Supersedes |
1.1 The purpose of ISO5725 is as follows: to outline the general principles to be understood when assessing accuracy (trueness and precision) of measurement methods and results, and in applications, and to establish practical estimations of the various measures by experiment (ISO5725-1); to provide a basic method for estimating the two extreme measures of the precision of measurement methods by experiment (ISO5725-2); to provide a procedure for obtaining intermediate measures of precision, giving the circumstances in which they apply and methods for estimating them (ISO5725-3); to provide basic methods for the determination of the trueness of a measurement method (ISO5725-4); to provide some alternatives to the basic methods, given in ISO5725-2 and ISO5725-4, for determining the precision and trueness of measurement methods for use under certain circumstances (ISO5725-5); to present some practical applications of these measures of trueness and precision (ISO5725-6). 1.2 This part of ISO5725 is concerned exclusively with measurement methods which yield measurements on a continuous scale and give a single value as the test result, although this single value may be the outcome of a calculation from a set of observations. It defines values which describe, in quantitative terms, the ability of a measurement method to give a correct result (trueness) or to replicate a given result (precision). Thus there is an implication that exactly the same thing is being measured, in exactly the same way, and that the measurement process is under control. This part of ISO5725 may be applied to a very wide range of materials, including liquids, powders and solid objects, manufactured or naturally occurring, provided that due consideration is given to any heterogeneity of the material.
Standards | Relationship |
ISO 5725-1:1994 | Identical |
DD ENV 12142:1997 | Method for determination of stable hydrogen isotope ratio (<sup>2</sup>H/<sup>1</sup>H) of water from fruit juices, using isotope ratio mass spectrometry |
BS EN 1528-1:1997 | Fatty food. Determination of pesticides and polychlorinated biphenyls (PCBs) General |
BS EN 1376:1997 | Foodstuffs. Determination of saccharin in table top sweetener preparations. Spectrometric method |
BS EN 12145:1997 | Fruit and vegetable juices. Determination of total dry matter. Gravimetric method with loss of mass on drying |
BS EN ISO 13468-1:1997 | Plastics. Determination of the total luminous transmittance of transparent materials Single-beam instrument |
BS 6200-5:1997 | Sampling and analysis of iron, steel and other ferrous metals Guidelines on statistical procedures |
DD ENV 12140:1997 | Method for determination of stable carbon isotope ratio (<sup>13</sup>C/<sup>12</sup>C) of sugars from fruit juices, using isotope ratio mass spectrometry |
BS 903-2:1997 | Physical testing of rubber Guide to the application of statistics to rubber testing |
BS 8496:2007 | Water quality. Enumeration of micro-organisms in water samples. Guidance on the estimation of variation of results with particular reference to the contribution of uncertainty of measurement |
BS EN 12146:1997 | Fruit and vegetable juices. Enzymatic determination of sucrose content. NADP spectrometric method |
BS EN 12148:1997 | Fruit and vegetable juices. Determination of hesperidin and naringin in citrus juices. Method using high performance liquid chromatography |
BS 6995:1997 | Method for evaluation of vulcanization characteristics of styrene-butadiene rubber (SBR, YSBR) (emulsion and solution-polymerized types) |
BS 4401-6:1996 | Methods of test for meat and meat products Determination of chloride content (Volhard method) |
BS 6043-2.11:1995 | Methods of sampling and test for carbonaceous materials used in aluminium manufacture. Electrode coke Determination of volatile matter content |
BS 4401-5:1996 | Methods of test for meat and meat products Determination of free fat content |
BS 1427:2009 | Guide to on-site test methods for the analysis of waters |
PD 6682-9:2003 | Aggregates Guidance on the use of European test method standards |
BS 2782-5.532A(1997) : 1997 | METHODS OF TESTING PLASTICS - OPTICAL AND COLOUR PROPERTIES, WEATHERING - PLASTICS - DETERMINATION OF THE TOTAL LUMINOUS TRANSMITTANCE OF TRANSPARENT MATERIALS - SINGLE-BEAM INSTRUMENT |
BS EN 12147:1997 | Method for determination of titratable acidity of fruit and vegetable juices |
BS EN 12143:1997 | Fruit and vegetable juices. Estimation of soluble solids content. Refractometric method |
BS EN 1378:1997 | Foodstuffs. Determination of aspartame in table top sweetener preparations. Method by high performance liquid chromatography |
BS 4325-12:1996 | Methods for analysis of oilseed residues Determination of glucosinolates content by high-performance liquid chromatography |
BS DD260(2003) : 2003 | WATER QUALITY - ENUMERATION OF MICRO-ORGANISMS IN WATER SAMPLES - GUIDANCE ON THE ESTIMATION OF VARIATION OF RESULTS WITH PARTICULAR REFERENCE TO THE CONTRIBUTION OF UNCERTAINTY OF MEASUREMENT |
DD ENV 12141:1997 | Method for determination of stable oxygen isotope ratio (<sup>18</sup>O/<sup>16</sup>O) of water from fruit juices, using isotope ratio mass spectrometry |
S.R. 24:2004 | GUIDANCE ON THE USE AND APPLICATION OF EUROPEAN TEST METHOD STANDARDS FOR AGGREGATES |
BS EN ISO 11214:1996 | Modified starch. Determination of carboxyl group content of oxidized starch |
BS EN 1379:1997 | Foodstuffs. Determination of cyclamate and saccharin in liquid table top sweetener preparations. Method by high performance liquid chromatography |
BS EN 1377:1997 | Foodstuffs. Determination of acesulfame K in table top sweetener preparations. Spectrometric method |
BS EN 12144:1997 | Fruit and vegetable juices. Determination of total alkalinity of ash. Titrimetric method |
ISO 5725-3:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 3: Intermediate measures of the precision of a standard measurement method |
ISO Guide 33:2015 | Reference materials — Good practice in using reference materials |
ISO 5725-6:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values |
ISO Guide 35:2017 | Reference materials — Guidance for characterization and assessment of homogeneity and stability |
ISO 5725-4:1994 | Accuracy (trueness and precision) of measurement methods and results Part 4: Basic methods for the determination of the trueness of a standard measurement method |
ISO 3534-2:2006 | Statistics — Vocabulary and symbols — Part 2: Applied statistics |
ISO 5725-2:1994 | Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method |
ISO 3534-3:2013 | Statistics — Vocabulary and symbols — Part 3: Design of experiments |
ISO 5725-5:1998 | Accuracy (trueness and precision) of measurement methods and results — Part 5: Alternative methods for the determination of the precision of a standard measurement method |
ISO 3534-1:2006 | Statistics — Vocabulary and symbols — Part 1: General statistical terms and terms used in probability |
Access your standards online with a subscription
Features
-
Simple online access to standards, technical information and regulations.
-
Critical updates of standards and customisable alerts and notifications.
-
Multi-user online standards collection: secure, flexible and cost effective.