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BS ISO 5725-1:1994

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

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Accuracy (trueness and precision) of measurement methods and results General principles and definitions

Amendment of

BS 5497-1:1987

Available format(s)

Hardcopy , PDF

Superseded date

24-07-2023

Superseded by

BS ISO 5725-1:2023

Language(s)

English

Published date

15-03-2000

€217.36
Excluding VAT

Committees responsible
National foreword
Foreword
Introduction
1 Scope
2 Normative references
3 Definitions
4 Practical implications of the definitions for
    accuracy experiments
    4.1 Standard measurement method
    4.2 Accuracy experiment
    4.3 Identical test items
    4.4 Short intervals of time
    4.5 Participating laboratories
    4.6 Observation conditions
5 Statistical model
    5.1 Basic model
    5.2 Relationship between the basic model and the
          precision
    5.3 Alternative models
6 Experimental design considerations when estimating
    accuracy
    6.1 Planning of an accuracy experiment
    6.2 Standard measurement method
    6.3 Selection of laboratories for the accuracy
          experiment
    6.4 Selection of materials to be used for an
          accuracy experiment
7 Utilization of accuracy data
    7.1 Publication of trueness and precision values
    7.2 Practical applications of trueness and
          precision values
Annex A (normative) Symbols and abbreviations used in
         ISO 5725
Annex B (normative) Charts of uncertainties for
         precision measures
Annex C (informative) Bibliography
Figure B.1 - The amount by which sr can be expected to
             differ from the true value within a
             probability level of 95 %
Figure B.2 - The amount by which sR can be expected to
             differ from the true value within a
             probability level of 95 %
Table 1 - Values showing the uncertainty of estimates
          of the repeatability and reproducibility
          standard deviations
Table 2 - Values of A, the uncertainty of an estimate
          of the bias of the measurement method
Table 3 - Values of AW, the uncertainty of the
          within-laboratory bias
Table 4 - Example of method of reporting standard
          deviations

Outlines the general principles to be understood when assessing accuracy of measurement methods and results. Concerned exclusively with measurement methods which yield measurements on a continuous scale and give a single value as the test result. Defines values which describe, in quantitative terms, the ability of a measurement method to give a correct result (trueness) or to replicate a given result (precision). Coverage includes: practical implications of the definitions for accuracy experiments; experimental design considerations when estimating accuracy; relationship between the basic model and the precision. Also gives definitions.

Committee
SS/6
DevelopmentNote
Together with BS ISO 5725-2, BS ISO 5725-3, BS ISO 5725-4, BS ISO 5725-5 and BS ISO 5725-6, supersedes BS 5497-1(1987) Supersedes 90/97778 DC (03/2002)
DocumentType
Standard
Pages
26
PublisherName
British Standards Institution
Status
Superseded
SupersededBy
Supersedes

1.1 The purpose of ISO5725 is as follows: to outline the general principles to be understood when assessing accuracy (trueness and precision) of measurement methods and results, and in applications, and to establish practical estimations of the various measures by experiment (ISO5725-1); to provide a basic method for estimating the two extreme measures of the precision of measurement methods by experiment (ISO5725-2); to provide a procedure for obtaining intermediate measures of precision, giving the circumstances in which they apply and methods for estimating them (ISO5725-3); to provide basic methods for the determination of the trueness of a measurement method (ISO5725-4); to provide some alternatives to the basic methods, given in ISO5725-2 and ISO5725-4, for determining the precision and trueness of measurement methods for use under certain circumstances (ISO5725-5); to present some practical applications of these measures of trueness and precision (ISO5725-6). 1.2 This part of ISO5725 is concerned exclusively with measurement methods which yield measurements on a continuous scale and give a single value as the test result, although this single value may be the outcome of a calculation from a set of observations. It defines values which describe, in quantitative terms, the ability of a measurement method to give a correct result (trueness) or to replicate a given result (precision). Thus there is an implication that exactly the same thing is being measured, in exactly the same way, and that the measurement process is under control. This part of ISO5725 may be applied to a very wide range of materials, including liquids, powders and solid objects, manufactured or naturally occurring, provided that due consideration is given to any heterogeneity of the material.

Standards Relationship
ISO 5725-1:1994 Identical

DD ENV 12142:1997 Method for determination of stable hydrogen isotope ratio (<sup>2</sup>H/<sup>1</sup>H) of water from fruit juices, using isotope ratio mass spectrometry
BS EN 1528-1:1997 Fatty food. Determination of pesticides and polychlorinated biphenyls (PCBs) General
BS EN 1376:1997 Foodstuffs. Determination of saccharin in table top sweetener preparations. Spectrometric method
BS EN 12145:1997 Fruit and vegetable juices. Determination of total dry matter. Gravimetric method with loss of mass on drying
BS EN ISO 13468-1:1997 Plastics. Determination of the total luminous transmittance of transparent materials Single-beam instrument
BS 6200-5:1997 Sampling and analysis of iron, steel and other ferrous metals Guidelines on statistical procedures
DD ENV 12140:1997 Method for determination of stable carbon isotope ratio (<sup>13</sup>C/<sup>12</sup>C) of sugars from fruit juices, using isotope ratio mass spectrometry
BS 903-2:1997 Physical testing of rubber Guide to the application of statistics to rubber testing
BS 8496:2007 Water quality. Enumeration of micro-organisms in water samples. Guidance on the estimation of variation of results with particular reference to the contribution of uncertainty of measurement
BS EN 12146:1997 Fruit and vegetable juices. Enzymatic determination of sucrose content. NADP spectrometric method
BS EN 12148:1997 Fruit and vegetable juices. Determination of hesperidin and naringin in citrus juices. Method using high performance liquid chromatography
BS 6995:1997 Method for evaluation of vulcanization characteristics of styrene-butadiene rubber (SBR, YSBR) (emulsion and solution-polymerized types)
BS 4401-6:1996 Methods of test for meat and meat products Determination of chloride content (Volhard method)
BS 6043-2.11:1995 Methods of sampling and test for carbonaceous materials used in aluminium manufacture. Electrode coke Determination of volatile matter content
BS 4401-5:1996 Methods of test for meat and meat products Determination of free fat content
BS 1427:2009 Guide to on-site test methods for the analysis of waters
PD 6682-9:2003 Aggregates Guidance on the use of European test method standards
BS 2782-5.532A(1997) : 1997 METHODS OF TESTING PLASTICS - OPTICAL AND COLOUR PROPERTIES, WEATHERING - PLASTICS - DETERMINATION OF THE TOTAL LUMINOUS TRANSMITTANCE OF TRANSPARENT MATERIALS - SINGLE-BEAM INSTRUMENT
BS EN 12147:1997 Method for determination of titratable acidity of fruit and vegetable juices
BS EN 12143:1997 Fruit and vegetable juices. Estimation of soluble solids content. Refractometric method
BS EN 1378:1997 Foodstuffs. Determination of aspartame in table top sweetener preparations. Method by high performance liquid chromatography
BS 4325-12:1996 Methods for analysis of oilseed residues Determination of glucosinolates content by high-performance liquid chromatography
BS DD260(2003) : 2003 WATER QUALITY - ENUMERATION OF MICRO-ORGANISMS IN WATER SAMPLES - GUIDANCE ON THE ESTIMATION OF VARIATION OF RESULTS WITH PARTICULAR REFERENCE TO THE CONTRIBUTION OF UNCERTAINTY OF MEASUREMENT
DD ENV 12141:1997 Method for determination of stable oxygen isotope ratio (<sup>18</sup>O/<sup>16</sup>O) of water from fruit juices, using isotope ratio mass spectrometry
S.R. 24:2004 GUIDANCE ON THE USE AND APPLICATION OF EUROPEAN TEST METHOD STANDARDS FOR AGGREGATES
BS EN ISO 11214:1996 Modified starch. Determination of carboxyl group content of oxidized starch
BS EN 1379:1997 Foodstuffs. Determination of cyclamate and saccharin in liquid table top sweetener preparations. Method by high performance liquid chromatography
BS EN 1377:1997 Foodstuffs. Determination of acesulfame K in table top sweetener preparations. Spectrometric method
BS EN 12144:1997 Fruit and vegetable juices. Determination of total alkalinity of ash. Titrimetric method

ISO 5725-3:1994 Accuracy (trueness and precision) of measurement methods and results — Part 3: Intermediate measures of the precision of a standard measurement method
ISO Guide 33:2015 Reference materials — Good practice in using reference materials
ISO 5725-6:1994 Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values
ISO Guide 35:2017 Reference materials — Guidance for characterization and assessment of homogeneity and stability
ISO 5725-4:1994 Accuracy (trueness and precision) of measurement methods and results Part 4: Basic methods for the determination of the trueness of a standard measurement method
ISO 3534-2:2006 Statistics — Vocabulary and symbols — Part 2: Applied statistics
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
ISO 3534-3:2013 Statistics — Vocabulary and symbols — Part 3: Design of experiments
ISO 5725-5:1998 Accuracy (trueness and precision) of measurement methods and results — Part 5: Alternative methods for the determination of the precision of a standard measurement method
ISO 3534-1:2006 Statistics — Vocabulary and symbols — Part 1: General statistical terms and terms used in probability

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