CEN/TS 16181:2013
Withdrawn
A Withdrawn Standard is one, which is removed from sale, and its unique number can no longer be used. The Standard can be withdrawn and not replaced, or it can be withdrawn and replaced by a Standard with a different number.
View Superseded by
Sludge, treated biowaste and soil - Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC)
11-03-2023
02-10-2013
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Principle
5 Interferences
6 Safety remarks
7 Reagents
8 Apparatus
9 Sample storage and preservation
10 Procedure
11 Performance characteristics
12 Precision
13 Test report
Annex A (informative) - Repeatability and
reproducibility data
Annex B (informative) - Examples of instrumental
conditions and chromatograms
Bibliography
This Technical Specification specifies the quantitative determination of 16 polycyclic aromatic hydrocarbons (PAH) (see Table 2) in sludge, soil and treated biowaste using GC-MS and HPLC-UV-DAD/FLD covering a wide range of PAH contamination levels (see also Annex B).When using fluorescence detection, acenaphthylene cannot be measured.The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.Typically, a lower limit of application of 0,01 mg/kg (expressed as dry matter) may be ensured for each individual PAH. This depends on instrument and sample.Sludge, soil and treated biowaste may differ in properties and also in the expected contamination levels of PAHs and presence of interfering substances. These differences make it impossible to describe one general procedure. This Technical Specification contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used. Two general lines are followed, an agitation procedure (shaking) or use of soxhlet/pressurised liquid extraction. NOTEOther PAH compounds can also be analysed with this method, provided suitability has been proven.
Committee |
CEN/TC 444
|
DocumentType |
Technical Specification
|
PublisherName |
Comite Europeen de Normalisation
|
Status |
Withdrawn
|
SupersededBy |
Standards | Relationship |
UNI CEN/TS 16181 : 2013 | Identical |
SIS-CEN/TS 16181:2016 | Identical |
DIN CEN/TS 16181;DIN SPEC 91243:2013-12 | Identical |
UNE-CEN/TS 16181:2013 | Identical |
XP CEN/TS 16181 : 2013 XP | Identical |
S.R. CEN/TS 16181:2013 | Identical |
DIN SPEC 91243 : 2013 | Identical |
PNE-prEN 16181 | Identical |
17/30364002 DC : 0 | BS EN 16167 - SOIL, TREATED BIOWASTE AND SLUDGE - DETERMINATION OF POLYCHLORINATED BIPHENYLS (PCB) BY GAS CHROMATOGRAPHY WITH MASS SELECTIVE DETECTION (GC-MS) AND GAS CHROMATOGRAPHY WITH ELECTRON-CAPTURE DETECTION (GC-ECD) |
PREN 16167 : DRAFT 2017 | SOIL, TREATED BIOWASTE AND SLUDGE - DETERMINATION OF POLYCHLORINATED BIPHENYLS (PCB) BY GAS CHROMATOGRAPHY WITH MASS SELECTIVE DETECTION (GC-MS) AND GAS CHROMATOGRAPHY WITH ELECTRON-CAPTURE DETECTION (GC-ECD) |
EN ISO 17993:2003 | Water quality - Determination of 15 polycyclic aromatic hydrocarbons (PAH) in water by HPLC with fluorescence detection after liquid-liquid extraction (ISO 17993:2002) |
DIN 38414-23:2002-02 | GERMAN STANDARD METHODS FOR THE EXAMINATION OF WATER, WASTE WATER AND SLUDGE - SLUDGE AND SEDIMENTS (GROUP S) - PART 23: DETERMINATION OF 15 POLYCYCLIC AROMATIC HYDROCARBONS (PAH) BY HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC) AND FLUORESCENCE DETECTION (S 23) |
ISO 22892:2006 | Soil quality Guidelines for the identification of target compounds by gas chromatography and mass spectrometry |
ISO 18287:2006 | Soil quality Determination of polycyclic aromatic hydrocarbons (PAH) Gas chromatographic method with mass spectrometric detection (GC-MS) |
EN 15308:2016 | Characterization of waste - Determination of selected polychlorinated biphenyls (PCB) in solid waste by gas chromatography with electron capture or mass spectrometric detection |
ISO 5667-15:2009 | Water quality — Sampling — Part 15: Guidance on the preservation and handling of sludge and sediment samples |
ISO 17993:2002 | Water quality — Determination of 15 polycyclic aromatic hydrocarbons (PAH) in water by HPLC with fluorescence detection after liquid-liquid extraction |
ISO 16720:2005 | Soil quality Pretreatment of samples by freeze-drying for subsequent analysis |
ISO 28540:2011 | Water quality — Determination of 16 polycyclic aromatic hydrocarbons (PAH) in water — Method using gas chromatography with mass spectrometric detection (GC-MS) |
EN ISO 16720:2007 | Soil quality - Pretreatment of samples by freeze-drying for subsequent analysis (ISO 16720:2005) |
ISO 5725-2:1994 | Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method |
ISO 8466-1:1990 | Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the linear calibration function |
EN ISO 22892:2011 | Soil quality - Guidelines for the identification of target compounds by gas chromatography and mass spectrometry (ISO 22892:2006) |
EN 15527:2008 | Characterization of waste - Determination of polycyclic aromatic hydrocarbons (PAH) in waste using gas chromatography mass spectrometry (GC/MS) |
EN ISO 5667-15:2009 | Water quality - Sampling - Part 15: Guidance on the preservation and handling of sludge and sediment samples (ISO 5667-15:2009) |
EN 15934:2012 | Sludge, treated biowaste, soil and waste - Calculation of dry matter fraction after determination of dry residue or water content |
EN 16179:2012 | Sludge, treated biowaste and soil - Guidance for sample pretreatment |
ISO 18512:2007 | Soil quality Guidance on long and short term storage of soil samples |
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