EN 12506:2003
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
Characterization of waste - Analysis of eluates - Determination of pH, As, Ba, Cd, Cl-, Co, Cr, Cr Vl, Cu, Mo, Ni, NO2-, Pb, total S, SO42-, V and Zn
04-06-2003
01-11-2011
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Sample pre-treatment
5 Blank determination
6 Interference
7 Selection of the suitable test method
8 Expression of results
9 Test report
Annex A (informative) - Validation of EN 12506
A.1 - General
A.2 - Interlaboratory study
A.3 - Selection of laboratories
A.4 - Selection of samples
A.5 - Validation scope
A.6 - Results and statistics
A.7 - Conclusion
Bibliography
This European Standard specifies methods for the determination of the parameters pH, As, Ba, Cd, Cl-, Co, Cr, Cr VI, Cu, Mo, Ni, NO2-, Pb, total S, SO42-, V and Zn in aqueous eluates for the characterization of waste.
| Committee |
CEN/TC 292
|
| DevelopmentNote |
Supersedes ENV 12506. (06/2003)
|
| DocumentType |
Standard
|
| PublisherName |
Comite Europeen de Normalisation
|
| Status |
Superseded
|
| Standards | Relationship |
| NF EN 12506 : 2004 | Identical |
| BS EN 12506:2003 | Identical |
| NS EN 12506 : 1ED 2003 | Identical |
| NBN EN 12506 : 2003 | Identical |
| PN EN 12506 : 2007 | Identical |
| DIN EN 12506:2003-09 | Identical |
| NEN EN 12506 : 2003 | Identical |
| I.S. EN 12506:2003 | Identical |
| UNE-EN 12506:2004 | Identical |
| I.S. EN 62561-7:2012 | LIGHTNING PROTECTION SYSTEM COMPONENTS (LPSC) - PART 7: REQUIREMENTS FOR EARTHING ENHANCING COMPOUNDS (IEC 62561-7:2011 (MOD)) |
| PD CEN/TR 16376:2012 | Characterization of waste. Overall guidance document for characterization of waste from the extractive industries |
| 08/30185788 DC : DRAFT OCT 2008 | BS EN 15864 - CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH CONTINUOUS LEACHANT RENEWAL UNDER CONDITIONS RELEVANT FOR SPECIFIED SCENARIO(S) |
| DD CEN/TS 14997:2006 | Characterization of waste. Leaching behaviour tests. Influence of pH on leaching with continuous pH-control |
| EN 15192:2006 | Characterisation of waste and soil - Determination of Chromium(VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection |
| DIN EN 15192:2007-02 | Characterisation of waste and soil - Determination of Chromium(VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection |
| CEN/TR 16376:2012 | Characterization of waste - Overall guidance document for characterization of waste from the extractive industries |
| CEN/TS 16384:2012 | Synthetic sport systems - Leaching test |
| CEN/TR 16184:2011 | Characterization of Waste - State-of-the-art document - Analysis of eluates |
| CEN/TS 14405:2004 | Characterization of waste - Leaching behaviour tests - Up-flow percolation test (under specified conditions) |
| BS EN 50164-7:2008 | Lightning protection components (LPC) Requirements for earthing enhancing compounds |
| 04/30114861 DC : 0 | BS ISO 21268-2 - SOIL QUALITY - LEACHING - PART 2: BATCH TEST USING A LIQUID TO SOLID RATIO OF 10 L/KG DRY MATTER |
| 10/30233988 DC : 0 | BS EN 16192 - CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES |
| 04/30114859 DC : 0 | BS ISO 21268-1 - SOIL QUALITY - LEACHING - PART 1: BATCH TEST USING A LIQUID TO SOLID RATIO OF 2 L/KG DRY MATTER |
| BS EN 62561-7:2012 | Lightning Protection System Components (LPSC) Requirements for earthing enhancing compounds |
| DD CEN/TS 14429:2005 | Characterization of waste. Leaching behaviour tests. Influence of pH on leaching with initial acid/base addition |
| I.S. CEN TS 14429:2005 | CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - INFLUENCE OF PH ON LEACHING WITH INITIAL ACID/BASE ADDITION |
| ISO 15192:2010 | Soil quality — Determination of chromium(VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection |
| S.R. CEN/TR 16376:2012 | CHARACTERIZATION OF WASTE - OVERALL GUIDANCE DOCUMENT FOR CHARACTERIZATION OF WASTE FROM THE EXTRACTIVE INDUSTRIES |
| DIN EN 13370:2003-09 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF AMMONIUM, AOX, CONDUCTIVITY, HG, PHENOL INDEX, TOC, CN[-] EASILY LIBERATABLE, F[-] |
| BS EN 16192:2011 | Characterization of waste. Analysis of eluates |
| I.S. CEN TS 14405:2004 | CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS) |
| 09/30179897 DC : 0 | BS ISO 15192 - SOIL QUALITY - DETERMINATION OF CHROMIUM(6) IN SOLID MATERIAL BY ALKALINE DIGESTION AND ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION |
| 15/30326969 DC : 0 | BS EN 62561-7 ED. 2 - LIGHTNING PROTECTION SYSTEM COMPONENTS (LPSC) - PART 7: REQUIREMENTS FOR EARTHING ENHANCING COMPOUNDS |
| I.S. EN 15192:2006 | CHARACTERISATION OF WASTE AND SOIL - DETERMINATION OF CHROMIUM(6) IN SOLID MATERIAL BY ALKALINE DIGESTION AND ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION |
| I.S. EN 16192:2011 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES |
| 99/109764 DC : DRAFT DEC 1999 | BS EN 12457-1 - CHARACTERIZATION OF WASTE - COMPLIANCE TEST FOR LEACHING OF GRANULAR WASTE MATERIAL AND SLUDGES - PART 1: ONE STAGE BATCH TEST AT A LIQUID TO SOLID RATIO OF 2 L/KG WITH PARTICLE SIZE BELOW 4 MM (WITH OR WITHOUT SIZE REDUCTION) |
| I.S. EN 13370:2003 | CHARACTERIZATION OF WASTE - ANALYSIS OF ELUATES - DETERMINATION OF AMMONIUM, AOX, CONDUCTIVITY, HG, PHENOL INDEX, TOC, EASILY LIBERATABLE CN[-], F[-] |
| PD CEN/TS 16384:2012 | Synthetic sport systems. Leaching test |
| DIN EN 16192:2012-02 | Characterization of waste - Analysis of eluates |
| 08/30185785 DC : DRAFT OCT 2008 | BS EN 15863 - CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH PERIODIC LEACHANT RENEWAL, UNDER FIXED TEST CONDITIONS |
| DD CEN/TS 14405:2004 | Characterization of waste. Leaching behaviour tests. Up-flow percolation test (under specified conditions) |
| I.S. EN 50164-7:2008 | LIGHTNING PROTECTION COMPONENTS (LPC) - PART 7: REQUIREMENTS FOR EARTHING ENHANCING COMPOUNDS |
| S.R. CEN/TR 16184:2011 | CHARACTERIZATION OF WASTE - STATE-OF-THE-ART DOCUMENT - ANALYSIS OF ELUATES |
| BS EN 15192:2006 | Characterisation of waste and soil. Determination of chromium (VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection |
| BS EN 13370:2003 | Characterization of waste. Analysis of eluates. Determination of Ammonium, AOX, conductivity, Hg, phenol index, TOC, easily liberatable CN<sup>-</sup>, F<sup>-</sup> |
| I.S. CEN TS 14997:2006 | CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - INFLUENCE OF PH ON LEACHING WITH CONTINUOUS PH-CONTROL |
| S.R. CEN/TS 16384:2012 | SYNTHETIC SPORT SYSTEMS - LEACHING TEST |
| 04/30116791 DC : DRAFT JUL 2004 | BS EN 15002 - CHARACTERISATION OF WASTE - PREPARATION OF TEST PORTIONS FROM LABORATORY SAMPLE |
| CEI EN 62561-7 : 2012 | LIGHTNING PROTECTION SYSTEM COMPONENTS (LPSC) - PART 7: REQUIREMENTS FOR EARTHING ENHANCING COMPOUNDS |
| 05/30133266 DC : DRAFT MAY 2005 | BS EN 15192 - CHARACTERISATION OF WASTE AND SOIL - DETERMINATION OF HEXAVALENT CHROMIUM IN SOLID MATERIAL BY ALKALINE DIGESTION AND ION CHROMATOGRAPHY WITH SPECTROPHOTOMETRIC DETECTION - COMPLEMENTARY ELEMENT |
| CEN/TS 14429:2005 | Characterization of waste - Leaching behaviour tests - Influence of pH on leaching with initial acid/base addition |
| CEN/TS 14997:2006 | Characterization of waste - Leaching behaviour tests - Influence of pH on leaching with continuous pH-control |
| EN 13370:2003 | Characterization of waste - Analysis of eluates - Determination of Ammonium, AOX, conductivity, Hg, phenol index, TOC, easily liberatable CN-, F- |
| EN 62561-7:2012 | Lightning Protection System Components (LPSC) - Part 7: Requirements for earthing enhancing compounds |
| EN 16192:2011 | Characterization of waste - Analysis of eluates |
| EN 50164-7:2008 | Lightning Protection Components (LPC) - Part 7: Requirements for earthing enhancing compounds |
| UNE-EN 16192:2012 | Characterization of waste - Analysis of eluates |
| UNE-CEN/TR 16184:2011 IN | Characterization of Waste - State-of-the-art document - Analysis of eluates |
| UNE-EN 62561-7:2012 | Lightning Protection System Components (LPSC) - Part 7: Requirements for earthing enhancing compounds |
| ISO/IEC 17025:2005 | General requirements for the competence of testing and calibration laboratories |
| ISO 5725-1:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 1: General principles and definitions |
| EN 12457-2:2002 | Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 2: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 4 mm (without or with size reduction) |
| EN ISO 11885:2009 | Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885:2007) |
| ISO 11083:1994 | Water quality — Determination of chromium(VI) — Spectrometric method using 1,5-diphenylcarbazide |
| ISO/TR 13530:1997 | Water quality — Guide to analytical quality control for water analysis |
| EN 26777:1993 | Water quality - Determination of nitrite - Molecular absorption spectrometric method (ISO 6777:1984) |
| ISO 5725-3:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 3: Intermediate measures of the precision of a standard measurement method |
| ISO 5725-6:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values |
| EN 12457-4:2002 | Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 4: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 10 mm (without or with size reduction) |
| ISO 8288:1986 | Water quality — Determination of cobalt, nickel, copper, zinc, cadmium and lead — Flame atomic absorption spectrometric methods |
| ISO 5725-4:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 4: Basic methods for the determination of the trueness of a standard measurement method |
| ISO 9297:1989 | Water quality — Determination of chloride — Silver nitrate titration with chromate indicator (Mohr's method) |
| EN ISO 10304-2 : 1996 | WATER QUALITY - DETERMINATION OF DISSOLVED ANIONS BY LIQUID CHROMATOGRAPHY OF IONS - DETERMINATION OF BROMIDE, CHLORIDE, NITRATE, NITRITE, ORTHOPHOSPHATE AND SULFATE, IN WASTE WATER |
| ENV ISO 13530:1998 | Water quality - Guide to analytical quality control for water analysis (ISO/TR 13530:1997) |
| EN 13370:2003 | Characterization of waste - Analysis of eluates - Determination of Ammonium, AOX, conductivity, Hg, phenol index, TOC, easily liberatable CN-, F- |
| EN 12457-1:2002 | Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 1: One stage batch test at a liquid to solid ratio of 2 l/kg for materials with high solid content and with particle size below 4 mm (without or with size reduction) |
| ISO 5725-2:1994 | Accuracy (trueness and precision) of measurement methods and results — Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method |
| EN ISO 5667-3:2012 | Water quality - Sampling - Part 3: Preservation and handling of water samples (ISO 5667-3:2012) |
| EN 12457-3:2002 | Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 3: Two stage batch test at a liquid to solid ratio of 2 l/kg and 8 l/kg for materials with high solid content and with particle size below 4 mm (without or with size reduction) |
| ISO 10523:2008 | Water quality — Determination of pH |
| EN ISO 11969:1996 | Water quality - Determination of arsenic - Atomic absorption spectrometric method (hydride technique) (ISO 11969:1996) |
| ISO 5725-5:1998 | Accuracy (trueness and precision) of measurement methods and results — Part 5: Alternative methods for the determination of the precision of a standard measurement method |
| EN ISO 10304-1:2009 | Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (ISO 10304-1:2007) |
| EN ISO 13395:1996 | Water quality - Determination of nitrite nitrogen and nitrate nitrogen and the sum of both by flow analysis (CFA and FIA) and spectrometric detection (ISO 13395:1996) |
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