ASTM D 6886 : 2018
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
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Standard Test Method for Determination of the Weight Percent Individual Volatile Organic Compounds in Waterborne Air-Dry Coatings by Gas Chromatography
Hardcopy , PDF
24-11-2024
English
01-10-2018
This test method is for the determination of the weight percent of individual volatile organic compounds in waterborne air-dry coatings (Note 1).
Committee |
D 01
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DocumentType |
Test Method
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Pages |
11
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PublisherName |
American Society for Testing and Materials
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Status |
Superseded
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SupersededBy | |
Supersedes |
1.1This test method is for the determination of the weight percent of individual volatile organic compounds in waterborne air-dry coatings (Note 1).
1.2This method may be used for the analysis of coatings containing silanes, siloxanes, and silane-siloxane blends.
1.3This method is not suitable for the analysis of coatings that cure by chemical reaction (this includes two-component coatings and coatings which cure when heated) because the dilution herein required will impede the chemical reaction required for these types of coatings.
1.4Precision statistics for this method have been determined for waterborne coatings in which the volatile organic compound weight percent is below 5 percent. The method has been used successfully with higher organic content waterborne coatings and with solventborne coatings (Note 2).
1.5This method may also be used to measure the exempt volatile organic compound content (for example, acetone, methyl acetate, t-butyl acetate and p-chlorobenzotrifluoride) of waterborne and solvent-borne coatings. Check local regulations for a list of exempt compounds. The methodology is virtually identical to that used in Test Method D6133 which, as written, is specific for only exempt volatile compounds.
1.6Volatile compounds that are present at the 0.005 weight percent level (50 ppm) or greater can be determined. A procedure for doing so is given in Section 9.
1.7Volatile organic compound content of a coating can be calculated using data from Test Method D6886 but requires other data (see Appendix X2.)
Note 1:Data from this method will not always provide the volatile organic compound content of a paint film equivalent to EPA Method 24. Some compounds and some semi-volatile compounds may be considered volatile using the GC conditions specified but will not fully volatilize during the one hour at 110°C conditions of EPA Method 24. Some or all of these materials remain in the paint film and therefore are not considered volatile organic compounds according to EPA Method 24. In addition, some compounds may decompose at the high inlet temperature of the GC. However, note the EPA Method 24 has poor precision and accuracy at low levels of volatile organic compounds.
Note 2:This method measures volatile organic compound weight of air-dry coatings directly as opposed to other methods in Practice D3960 which measure the volatile organic compound weight percent indirectly. A direct measurement of the weight percent particularly in low volatile organic compound content waterborne coatings, generally gives better precision. California Polytechnic State University carried out an extensive study for the California Air Resources Board comparing the precision of the direct method with the indirect method (CARB Standard Agreement No. 04.329) Detailed results of this study may be found at http://www.arb.ca.gov/coatings/arch/Final_Report_6_11_09.pdf. This study may be used to decide if the present method or other methods in Practice D3960 are preferred for a specific coating.
1.8The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.9This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.10This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D 3960 : 2005 : R2018 | Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings |
ASTM D 7270 : 2007 : R2013 | Standard Guide for Environmental and Performance Verification of Factory-Applied Liquid Coatings |
ASTM D 6803 : 2013 | Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Paint Using Small Environmental Chambers |
ASTM D 8531 : 2023 | Standard Specification for Latex-Based Pavement Sealers Containing Mineral Aggregates |
ASTM D 6803 : 2019 | Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Architectural Coatings Using Small-Scale Environmental Chambers |
ASTM D 7270 : 2007 : R2021 | Standard Guide for Environmental and Performance Verification of Factory-Applied Liquid Coatings |
ASTM D 6577 : 2024 : REV A | Standard Guide for Testing Industrial Protective Coatings |
ASTM D 3960 : 2005 : R2018 | Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings |
ASTM D 4017 : 1996 : REV A | Standard Test Method for Water in Paints and Paint Materials by Karl Fischer Method |
ASTM D 1475 : 2013 | Standard Test Method For Density of Liquid Coatings, Inks, and Related Products |
ASTM E 177 : 1990 : REV A : R1996 | Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods |
ASTM D 1475 : 1998 : R2012 | Standard Test Method For Density of Liquid Coatings, Inks, and Related Products |
ASTM D 3960 : 2002 | Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings |
ASTM D 3960 : 2001 | Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings |
ASTM D 3925 : 1981 : R1985 | Standard Practice for Sampling Liquid and Related Pigmented Coatings |
ASTM D 3960 : 2005 | Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings |
ASTM D 1475 : 1985 | Standard Test Method for Density of Paint, Varnish, Lacquer, and Related Products |
ASTM D 2369 : 1998 | Standard Test Method for Volatile Content of Coatings |
ASTM D 4017 : 2002 : R2015 | Standard Test Method for Water in Paints and Paint Materials by Karl Fischer Method |
ASTM D 3925 : 1991 : R1996 | Standard Practice for Sampling Liquid Paints and Related Pigmented Coatings |
ASTM D 3792 : 1991 : EDT 1 | Standard Test Method for Water Content of Water-Reducible Paints by Direct Injection into a Gas Chromatography |
ASTM D 3960 : 2005 : R2013 | Standard Practice for Determining Volatile Organic Compound (VOC)Content of Paints and Related Coatings |
ASTM D 6133 : 2002 : R2014 | Standard Test Method for Acetone, <i>p</i>-Chlorobenzotrifluoride, Methyl Acetate or <i>t</i>-Butyl Acetate Content of Solventborne and Waterborne Paints, Coatings, Resins, and Raw Materials by Direct Injection Into a Gas Chromatograph |
ASTM D 4017 : 1981 : R1987 : EDT 1 | Standard Test Method for Water in Paints and Paint Materials by Karl Fischer Method |
ASTM E 691 : 2020 | Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method |
ASTM D 2369 : 1981 : EDT 1 | Standard Test Method for Volatile Content of Coatings |
ASTM D 2369 : 2001 | Standard Test Method for Volatile Content of Coatings |
ASTM D 3792 : 2005 : R2009 | Standard Test Method for Water Content of Coatings by Direct Injection Into a Gas Chromatograph |
ASTM D 1475 : 1998 : R2003 | Standard Test Method for Density of Liquid Coatings, Inks, and Related Products |
ASTM D 2369 : 2010 | Standard Test Method for Volatile Content of Coatings |
ASTM D 6133 : 2024 | Standard Test Method for Acetone, <emph type="ital">p</emph>-Chlorobenzotrifluoride, Methyl Acetate or <emph type="ital">t</emph>-Butyl Acetate Content of Solventborne and Waterborne Paints, Coatings, Resins, and Raw Materials by Direct Injection Into a Gas Chromatograph |
ASTM E 691 : 2019 : EDT 1 | Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method |
ASTM D 3792 : 1979 : EDT 2 | Standard Test Method for Water Content of Water-Reducible Paints by Direct Injection into a Gas Chromatography |
ASTM E 691 : 2023 | Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method |
ASTM D 6133:2002 | Standard Test Method for Acetone, <i>p</i>-Chlorobenzotrifluoride, Methyl Acetate or <i>t</i>-Butyl Acetate Content of Solventborne and Waterborne Paints, Coatings, Resins, and Raw Materials by Direct Injection Into a Gas Chromatograph |
ASTM D 2369 : 2020 | Standard Test Method for Volatile Content of Coatings |
ASTM D 1475 : 1960 : R1968 | Standard Method Of Test For Density Of Paint, Varnish, Lacquer, And Related Products |
ASTM D 3960 : 1998 | Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings |
ASTM E 691 : 2022 | Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method |
ASTM D 4017 : 2002 : R2008 : EDT 1 | Standard Test Method for Water in Paints and Paint Materials by Karl Fischer Method |
ASTM D 2369 : 2007 | Standard Test Method for Volatile Content of Coatings |
ASTM E 691 : 2009 | Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method |
ASTM D 1475 : 1998 : R2008 | Standard Test Method For Density of Liquid Coatings, Inks, and Related Products |
ASTM D 2369 : 2010 : EDT 1 | Standard Test Method for Volatile Content of Coatings |
ASTM D 2369 : 1993 | Standard Test Method for Volatile Content of Coatings |
ASTM D 2369 : 2024 | Standard Test Method for Volatile Content of Coatings |
ASTM D 6133 : 2002 : R2021 | Standard Test Method for Acetone, <emph type="ital">p</emph>-Chlorobenzotrifluoride, Methyl Acetate or <emph type="ital">t</emph>-Butyl Acetate Content of Solventborne and Waterborne Paints, Coatings, Resins, and Raw Materials by Direct Injection Into a Gas Chromatograph |
ASTM D 3925 : 2002 : R2022 | Standard Practice for Sampling Liquid Paints and Related Pigmented Coatings |
ASTM E 691 : 2021 | Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method |
ASTM D 6133 : 2002 : R2008 | Standard Test Method for Acetone, <i>p</i>-Chlorobenzotrifluoride, Methyl Acetate or <i>t</i>-Butyl Acetate Content of Solventborne and Waterborne Paints, Coatings, Resins, and Raw Materials by Direct Injection Into a Gas Chromatograph |
ASTM D 4017 : 1990 | Standard Test Method for Water in Paints and Paint Materials by Karl Fischer Method |
ASTM D 3792 : 2016 | Standard Test Method for Water Content of Coatings by Direct Injection Into a Gas Chromatograph |
ASTM D 7358 : 2007 : R2018 | Standard Test Method for Water Content of Paints by Quantitative Calcium Hydride Reaction Test Kit |
ASTM D 4017 : 2002 | Standard Test Method for Water in Paints and Paint Materials by Karl Fischer Method |
ASTM D 3792 : 2005 : R2015 | Standard Test Method for Water Content of Coatings by Direct Injection Into a Gas Chromatograph |
ASTM D 3792 : 2005 | Standard Test Method for Water Content of Coatings by Direct Injection Into a Gas Chromatograph |
ASTM D 3792 : 2016 : R2022 | Standard Test Method for Water Content of Coatings by Direct Injection Into a Gas Chromatograph |
ASTM D 2369 : 1995 | Standard Test Method for Volatile Content of Coatings |
ASTM D 2369 : 2004 | Standard Test Method for Volatile Content of Coatings |
ASTM D 6133 : 2000 | Test Method for Acetone, <i>p</i>-Chlorobenzotrifluoride, Methyl Acetate or <i>t</i>-Butyl Acetate Content of Solvent-Reducible and Water-Reducible Paints, Coatings, Resins, and Raw Materials by Direct Injection Into a Gas Chromatograph |
ASTM D 3960 : 2004 | Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings |
ASTM D 2369 : 1990 | Standard Test Method for Volatile Content of Coatings |
ASTM D 3925 : 2002 | Standard Practice for Sampling Liquid Paints and Related Pigmented Coatings |
ASTM D 7358 : 2007 | Standard Test Method for Water Content of Paints by Quantitative Calcium Hydride Reaction Test Kit |
ASTM D 2369 : 2003 | Standard Test Method for Volatile Content of Coatings |
ASTM D 4017 : 2022 | Standard Test Method for Water in Paints and Paint Materials by Karl Fischer Method |
ASTM D 3792 : 1999 | Standard Test Method for Water Content of Coatings by Direct Injection Into a Gas Chromatograph |
ASTM D 1475 : 1998 | Standard Test Method for Density of Liquid Coatings, Inks, and Related Products |
ASTM D 2369 : 2010 : R2015 : EDT 1 | Standard Test Method for Volatile Content of Coatings |
ASTM D 2369 : 1987 | Standard Test Method for Volatile Content of Coatings |
ASTM D 3925 : 2002 : R2015 | Standard Practice for Sampling Liquid Paints and Related Pigmented Coatings |
ASTM D 2369 : 2001 : EDT 1 | Standard Test Method for Volatile Content of Coatings |
ASTM D 7358 : 2007 : R2013 | Standard Test Method for Water Content of Paints by Quantitative Calcium Hydride Reaction Test Kit |
ASTM D 2369 : 1992 | Standard Test Method for Volatile Content of Coatings |
ASTM D 3925 : 2002 : R2010 | Standard Practice for Sampling Liquid Paints and Related Pigmented Coatings |
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