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EN 16192:2011

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by

Characterization of waste - Analysis of eluates

Superseded date

16-03-2022

Superseded by

CEN/TR 16192:2020

Published date

23-11-2011

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Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Sample pretreatment
5 Blank determination
6 Interference
7 Selection of the suitable test method
8 Expression of results
9 Test report
Annex A (informative) - Validation of EN 12506:2003 and
        EN 13370:2003
Annex B (informative) - Additional validation data
Bibliography

This European Standard specifies methods for the determination of the parameters pH, ammonium, AOX, As, Ba, Cd, Cl-, easily liberatable CN-, Co, Cr, Cr(VI), Cu, DOC/TOC, electrical conductivity, F-, Hg, Mo, Ni, NO2-, Pb, phenol index, total S, Sb, Se, SO42-, TDS, V and Zn in aqueous eluates for the characterization of waste.

Committee
CEN/TC 444
DevelopmentNote
Supersedes PREN 16192, EN 12506 & EN 13370. (12/2011)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Superseded
SupersededBy
Supersedes

Standards Relationship
NBN EN 16192 : 2012 Identical
SN EN 16192 : 2012 Identical
UNI EN 16192 : 2012 Identical
DIN EN 16192:2012-02 Identical
NEN EN 16192 : 2011 Identical
NF EN 16192 : 2012 Identical
NS EN 16192 : 2011 Identical
PN EN 16192 : 2012 Identical
UNE-EN 16192:2012 Identical
BS EN 16192:2011 Identical
I.S. EN 16192:2011 Identical

IEC 62561-7:2018 Lightning protection system components (LPSC) - Part 7: Requirements for earthing enhancing compounds
UNE-EN 14429:2015 Characterization of waste - Leaching behaviour test - Influence of pH on leaching with initial acid/base addition
BS EN 14405:2017 Characterization of waste - Leaching behaviour test - Up-flow percolation test (under specified conditions)
14/30304804 DC : 0 BS EN 14405 - CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS)
17/30354239 DC : 0 BS EN 13369 - COMMON RULES FOR PRECAST CONCRETE PRODUCTS
DIN EN 15863:2015-06 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH PERIODIC LEACHANT RENEWAL, UNDER FIXED CONDITIONS
UNE-EN 16123:2013 Characterization of waste - Guidance on selection and application of screening methods
EN 14997:2015 Characterization of waste - Leaching behaviour test - Influence of pH on leaching with continuous pH control
CEN/TS 15862:2012 Characterisation of waste - Compliance leaching test - One stage batch leaching test for monoliths at fixed liquid to surface area ratio (L/A) for test portions with fixed minimum dimensions
EN 14405:2017 Characterization of waste - Leaching behaviour test - Up-flow percolation test (under specified conditions)
CEN/TS 16637-3:2016 Construction products - Assessment of release of dangerous substances - Part 3: Horizontal up-flow percolation test
EN 15863:2015 Characterization of waste - Leaching behaviour test for basic characterization - Dynamic monolithic leaching test with periodic leachant renewal, under fixed conditions
CEN/TS 16637-2:2014 Construction products - Assessment of release of dangerous substances - Part 2: Horizontal dynamic surface leaching test
DIN EN 14997:2015-05 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - INFLUENCE OF PH ON LEACHING WITH CONTINUOUS PH CONTROL
UNI EN 16457 : 2014 CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
UNI EN 13369 : 2013 COMMON RULES FOR PRECAST CONCRETE PRODUCTS
PREN 14429 : DRAFT 2013 CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST - INFLUENCE OF PH ON LEACHING WITH INITIAL ACID/BASE ADDITION
EN IEC 62561-7:2018 Lightning protection system components (LPSC) - Part 7: Requirements for earthing enhancing compounds
BS EN 13369:2013 Common rules for precast concrete products
I.S. EN 16457:2014 CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
PREN 14405 : DRAFT 2014 CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS)
UNE-EN 14405:2017 Characterization of waste - Leaching behaviour test - Up-flow percolation test (under specified conditions)
I.S. EN 16123:2013 CHARACTERIZATION OF WASTE - GUIDANCE ON SELECTION AND APPLICATION OF SCREENING METHODS
UNI EN 16123 : 2013 CHARACTERIZATION OF WASTE - GUIDANCE ON SELECTION AND APPLICATION OF SCREENING METHODS
17/30348303 DC : 0 BS EN 17087 - CONSTRUCTION PRODUCTS - ASSESSMENT OF RELEASE OF DANGEROUS SUBSTANCES - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE FOR TESTING OF RELEASE AND ANALYSIS OF CONTENT
UNE-EN 15863:2015 Characterization of waste - Leaching behaviour test for basic characterization - Dynamic monolithic leaching test with periodic leachant renewal, under fixed conditions
UNE-EN 15002:2015 Characterization of waste - Preparation of test portions from the laboratory sample
S.R. CEN/TS 15863:2012 CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERISATION - DYNAMIC MONOLITHIC LEACHING TEST WITH PERIODIC LEACHANT RENEWAL, UNDER FIXED TEST CONDITIONS
I.S. EN 15002:2015 CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE
S.R. CEN/TS 15862:2012 CHARACTERISATION OF WASTE - COMPLIANCE LEACHING TEST - ONE STAGE BATCH LEACHING TEST FOR MONOLITHS AT FIXED LIQUID TO SURFACE AREA RATIO (L/A) FOR TEST PORTIONS WITH FIXED MINIMUM DIMENSIONS
DIN EN 16123:2013-05 Characterization of waste - Guidance on selection and application of screening methods
BS EN 16123:2013 Characterization of waste. Guidance on selection and application of screening methods
UNE-EN 14997:2015 Characterization of waste - Leaching behaviour test - Influence of pH on leaching with continuous pH control
UNE-EN 16457:2014 Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report
EN 16123:2013 Characterization of waste - Guidance on selection and application of screening methods
DIN EN 13369:2013-08 COMMON RULES FOR PRECAST CONCRETE PRODUCTS
I.S. EN 13369:2013 COMMON RULES FOR PRECAST CONCRETE PRODUCTS
UNI CEN/TS 15862 : 2012 CHARACTERISATION OF WASTE - COMPLIANCE LEACHING TEST - ONE STAGE BATCH LEACHING TEST FOR MONOLITHS AT FIXED LIQUID TO SURFACE AREA RATIO (L/A) FOR TEST PORTIONS WITH FIXED MINIMUM DIMENSIONS
DIN EN 14405:2017-05 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS)
PD CEN/TS 15864:2012 Characterisation of waste. Leaching behaviour test for basic characterisation. Dynamic monolithic leaching test with continuous leachant renewal under conditions relevant for specified scenario(s)
PD CEN/TS 16637-3:2016 Construction products. Assessment of release of dangerous substances Horizontal up-flow percolation test
I.S. EN 15863:2015 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH PERIODIC LEACHANT RENEWAL, UNDER FIXED CONDITIONS
PREN 13369 : DRAFT 2017 COMMON RULES FOR PRECAST CONCRETE PRODUCTS
I.S. EN 14405:2017 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS)
PD CEN/TS 16637-2:2014 Construction products. Assessment of release of dangerous substances Horizontal dynamic surface leaching test
DIN EN 14429:2015-05 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - INFLUENCE OF PH ON LEACHING WITH INITIAL ACID/BASE ADDITION
12/30263896 DC : 0 BS EN 16457 - CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
DIN EN 16457:2014-07 CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
S.R. CEN/TS 16637-2:2014 CONSTRUCTION PRODUCTS - ASSESSMENT OF RELEASE OF DANGEROUS SUBSTANCES - PART 2: HORIZONTAL DYNAMIC SURFACE LEACHING TEST
S.R. CEN/TS 16637-3:2016 CONSTRUCTION PRODUCTS - ASSESSMENT OF RELEASE OF DANGEROUS SUBSTANCES - PART 3: HORIZONTAL UP-FLOW PERCOLATION TEST
I.S. EN 14429:2015 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - INFLUENCE OF PH ON LEACHING WITH INITIAL ACID/BASE ADDITION
S.R. CEN/TS 15864:2015 CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH CONTINUOUS LEACHANT RENEWAL UNDER CONDITIONS RELEVANT FOR SPECIFIED SCENARIO(S)
PD CEN/TS 15862:2012 Characterisation of waste. Compliance leaching test. One stage batch leaching test for monoliths at fixed liquid to surface area ratio (L/A) for test portions with fixed minimum dimensions
PD CEN/TS 15863:2012 Characterisation of waste. Leaching behaviour test for basic characterisation. Dynamic monolithic leaching test with periodic leachant renewal, under fixed test conditions
13/30291099 DC : 0 BS EN 15002 - CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE
BS EN 15863:2015 Characterization of waste. Leaching behaviour test for basic characterization. Dynamic monolithic leaching test with periodic leachant renewal, under fixed conditions
DIN EN 15002:2015-07 CHARACTERIZATION OF WASTE - PREPARATION OF TEST PORTIONS FROM THE LABORATORY SAMPLE
EN 15002:2015 Characterization of waste - Preparation of test portions from the laboratory sample
EN 16457:2014 Characterization of waste - Framework for the preparation and application of a testing programme - Objectives, planning and report
BS EN 14997:2015 Characterization of waste. Leaching behaviour test. Influence of pH on leaching with continuous pH control
13/30286649 DC : 0 BS EN 14429 - CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST - INFLUENCE OF PH ON LEACHING WITH INITIAL ACID/BASE ADDITION
BS EN 14429:2015 Characterization of waste. Leaching behaviour test. Influence of pH on leaching with initial acid/base addition
DIN EN 16457 E : 2014 CHARACTERIZATION OF WASTE - FRAMEWORK FOR THE PREPARATION AND APPLICATION OF A TESTING PROGRAMME - OBJECTIVES, PLANNING AND REPORT
13/30286652 DC : 0 BS EN 14997 - CHARACTERISATION OF WASTE - LEACHING BEHAVIOUR TEST - INFLUENCE OF PH ON LEACHING WITH CONTINUOUS PH CONTROL
BS EN 16457:2014 Characterization of waste. Framework for the preparation and application of a testing programme. Objectives, planning and report
UNE-EN 13369:2013 Common rules for precast concrete products
I.S. EN IEC 62561-7:2018 LIGHTNING PROTECTION SYSTEM COMPONENTS (LPSC) - PART 7: REQUIREMENTS FOR EARTHING ENHANCING COMPOUNDS
I.S. EN 13369:2018 COMMON RULES FOR PRECAST CONCRETE PRODUCTS
I.S. EN 14997:2015 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST - INFLUENCE OF PH ON LEACHING WITH CONTINUOUS PH CONTROL
UNI CEN/TS 16637-2 : 2014 CONSTRUCTION PRODUCTS - ASSESSMENT OF RELEASE OF DANGEROUS SUBSTANCES - PART 2: HORIZONTAL DYNAMIC SURFACE LEACHING TEST
EN 13369:2018 Common rules for precast concrete products
13/30286655 DC : 0 BS EN 15863 - CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TEST FOR BASIC CHARACTERIZATION - DYNAMIC MONOLITHIC LEACHING TEST WITH PERIODIC LEACHANT RENEWAL, UNDER FIXED TEST CONDITIONS
BS EN 15002:2015 Characterization of waste. Preparation of test portions from the laboratory sample
CEN/TS 15864:2015 Characterization of waste - Leaching behaviour test for basic characterization - Dynamic monolithic leaching test with continuous leachant renewal under conditions relevant for specified scenario(s)
EN 14429:2015 Characterization of waste - Leaching behaviour test - Influence of pH on leaching with initial acid/base addition
CEN/TS 15863:2012 Characterisation of waste - Leaching behaviour test for basic characterisation - Dynamic monolithic leaching test with periodic leachant renewal, under fixed test conditions

ISO 23913:2006 Water quality — Determination of chromium(VI) — Method using flow analysis (FIA and CFA) and spectrometric detection
ISO/IEC 17025:2005 General requirements for the competence of testing and calibration laboratories
ISO 5725-1:1994 Accuracy (trueness and precision) of measurement methods and results — Part 1: General principles and definitions
EN ISO 17294-1:2006 Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 1: General guidelines (ISO 17294-1:2004)
EN ISO 14403:2002 Water quality - Determination of total cyanide and free cyanide by continuous flow analysis (ISO 14403:2002)
ISO 14402:1999 Water quality Determination of phenol index by flow analysis (FIA and CFA)
EN 12457-2:2002 Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 2: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 4 mm (without or with size reduction)
EN 1483:2007 Water quality - Determination of mercury - Method using atomic absorption spectrometry
CEN/TS 14429:2005 Characterization of waste - Leaching behaviour tests - Influence of pH on leaching with initial acid/base addition
EN ISO 11885:2009 Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885:2007)
EN 27888:1993 Water quality - Determination of electrical conductivity (ISO 7888:1985)
ISO 11969:1996 Water quality Determination of arsenic Atomic absorption spectrometric method (hydride technique)
ISO 11083:1994 Water quality — Determination of chromium(VI) — Spectrometric method using 1,5-diphenylcarbazide
EN ISO 10304-3:1997 Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 3: Determination of chromate, iodide, sulfite, thiocyanate and thiosulfate (ISO 10304-3:1997)
EN ISO 11732:2005 Water quality - Determination of ammonium nitrogen - Method by flow analysis (CFA and FIA) and spectrometric detection (ISO 11732:2005)
EN ISO 15586:2003 Water quality - Determination of trace elements using atomic absorption spectrometry with graphite furnace (ISO 15586:2003)
ISO/TR 13530:1997 Water quality Guide to analytical quality control for water analysis
EN 26777:1993 Water quality - Determination of nitrite - Molecular absorption spectrometric method (ISO 6777:1984)
EN 1484:1997 Water analysis - Guidelines for the determination of total organic carbon (TOC) and dissolved organic carbon (DOC)
ISO 10304-3:1997 Water quality — Determination of dissolved anions by liquid chromatography of ions — Part 3: Determination of chromate, iodide, sulfite, thiocyanate and thiosulfate
ISO 11732:2005 Water quality — Determination of ammonium nitrogen — Method by flow analysis (CFA and FIA) and spectrometric detection
ISO 15682:2000 Water quality Determination of chloride by flow analysis (CFA and FIA) and photometric or potentiometric detection
ISO 17852:2006 Water quality Determination of mercury Method using atomic fluorescence spectrometry
ISO 5725-3:1994 Accuracy (trueness and precision) of measurement methods and results — Part 3: Intermediate measures of the precision of a standard measurement method
CEN/TS 14997:2006 Characterization of waste - Leaching behaviour tests - Influence of pH on leaching with continuous pH-control
ISO 9965:1993 Water quality Determination of selenium Atomic absorption spectrometric method (hydride technique)
ISO 5725-6:1994 Accuracy (trueness and precision) of measurement methods and results — Part 6: Use in practice of accuracy values
EN 12457-4:2002 Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 4: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 10 mm (without or with size reduction)
ISO 8288:1986 Water quality — Determination of cobalt, nickel, copper, zinc, cadmium and lead — Flame atomic absorption spectrometric methods
ISO 5725-4:1994 Accuracy (trueness and precision) of measurement methods and results Part 4: Basic methods for the determination of the trueness of a standard measurement method
ISO 9297:1989 Water quality Determination of chloride Silver nitrate titration with chromate indicator (Mohr's method)
EN ISO 17852:2008 Water quality - Determination of mercury - Method using atomic fluorescence spectrometry (ISO 17852:2006)
EN ISO 23913:2009 Water quality - Determination of chromium(VI) - Method using flow analysis (FIA and CFA) and spectrometric detection (ISO 23913:2006)
ISO 11885:2007 Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES)
ISO 17294-1:2004 Water quality — Application of inductively coupled plasma mass spectrometry (ICP-MS) — Part 1: General guidelines
ISO 10304-1:2007 Water quality Determination of dissolved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate
ISO 6703-2:1984 Water quality — Determination of cyanide — Part 2: Determination of easily liberatable cyanide
ISO 6439:1990 Water quality — Determination of phenol index — 4-Aminoantipyrine spectrometric methods after distillation
ISO 13395:1996 Water quality — Determination of nitrite nitrogen and nitrate nitrogen and the sum of both by flow analysis (CFA and FIA) and spectrometric detection
ISO 10359-1:1992 Water quality — Determination of fluoride — Part 1: Electrochemical probe method for potable and lightly polluted water
CEN/TR 16184:2011 Characterization of Waste - State-of-the-art document - Analysis of eluates
ENV ISO 13530:1998 Water quality - Guide to analytical quality control for water analysis (ISO/TR 13530:1997)
ISO 15586:2003 Water quality — Determination of trace elements using atomic absorption spectrometry with graphite furnace
NEN 6604 : 2007 WATER QUALITY - DETERMINATION OF AMMONIUM, NITRATE, NITRITE, CHLORIDE, ORTHO-PHOSPHATE, SULPHATE AND SILICATE BY A DISCRETE ANALYZER SYSTEM AND SPECTROPHOTOMETRIC DETECTION
ISO 7888:1985 Water quality — Determination of electrical conductivity
EN 12457-1:2002 Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 1: One stage batch test at a liquid to solid ratio of 2 l/kg for materials with high solid content and with particle size below 4 mm (without or with size reduction)
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
ISO 14403:2002 Water quality Determination of total cyanide and free cyanide by continuous flow analysis
ISO 9562:2004 Water quality — Determination of adsorbable organically bound halogens (AOX)
ISO 22743:2006 Water quality Determination of sulfates Method by continuous flow analysis (CFA)
EN 12920:2006+A1:2008 Characterization of waste - Methodology for the determination of the leaching behaviour of waste under specified conditions
EN 15002:2015 Characterization of waste - Preparation of test portions from the laboratory sample
EN ISO 15682:2001 Water quality - Determination of chloride by flow analysis (CFA and FIA) and photometric or potentiometric detection (ISO 15682:2000)
EN 12457-3:2002 Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 3: Two stage batch test at a liquid to solid ratio of 2 l/kg and 8 l/kg for materials with high solid content and with particle size below 4 mm (without or with size reduction)
EN 12506:2003 Characterization of waste - Analysis of eluates - Determination of pH, As, Ba, Cd, Cl-, Co, Cr, Cr Vl, Cu, Mo, Ni, NO2-, Pb, total S, SO42-, V and Zn
EN ISO 9562:2004 Water quality - Determination of adsorbable organically bound halogens (AOX) (ISO 9562:2004)
ISO 7150-1:1984 Water quality — Determination of ammonium — Part 1: Manual spectrometric method
CEN/TS 14405 : 2004 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS)
ISO 10523:2008 Water quality — Determination of pH
EN 15216:2007 Characterization of waste - Determination of total dissolved solids (TDS) in water and eluates
EN ISO 11969:1996 Water quality - Determination of arsenic - Atomic absorption spectrometric method (hydride technique) (ISO 11969:1996)
ISO 5725-5:1998 Accuracy (trueness and precision) of measurement methods and results — Part 5: Alternative methods for the determination of the precision of a standard measurement method
EN ISO 14402:1999 Water quality - Determination of phenol index by flow analysis (FIA and CFA)(ISO 14402:1999)
EN ISO 10304-1:2009 Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (ISO 10304-1:2007)
ISO 17294-2:2016 Water quality — Application of inductively coupled plasma mass spectrometry (ICP-MS) — Part 2: Determination of selected elements including uranium isotopes
EN ISO 14911:1999 Water quality - Determination of dissolved Li+, Na+, NH4+, K+, Mn2+, Ca2+, Mg2+, Sr2+ and Ba2+ using ion chromatography - Method for water and waste water (ISO 14911:1998)
EN ISO 17294-2:2016 Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 2: Determination of selected elements including uranium isotopes (ISO 17294-2:2016)
ISO 14911:1998 Water quality — Determination of dissolved Li+, Na+, NH4+, K+, Mn2+, Ca2+, Mg2+, Sr2+ and Ba2+ using ion chromatography — Method for water and waste water
EN ISO 13395:1996 Water quality - Determination of nitrite nitrogen and nitrate nitrogen and the sum of both by flow analysis (CFA and FIA) and spectrometric detection (ISO 13395:1996)

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