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EN 1948-4:2010+A1:2013

Current

Current

The latest, up-to-date edition.

Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 4: Sampling and analysis of dioxin-like PCBs

Published date

04-12-2013

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Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Symbols and abbreviations
5 Principle of the measurement procedure
6 Device, materials and [13]C[12]-labelled
   standards
7 Safety measures
8 Measurement procedure
9 Method validation
10 Quality control requirements for the
   measurement
11 Quality assurance criteria for
   extraction/clean-up/quantification procedure
   blanks
12 Performance characteristics
13 Interferences (informative)
Annex A (informative) - Toxicity and toxic equivalency
Annex B (informative) - Examples of extraction and
        clean-up procedures
Annex C (informative) - Evaluation of the performance
        characteristics
Annex D (informative) - Recommendations for measuring
        high concentrations of dioxin-like PCBs
Annex E (informative) - Possible interferences in
        dioxin-like PCB analysis
Annex F (informative) - Measurement of the marker
        PCBs 28, 52, 101, 138, 153, and 180 in addition
        to the 12 dioxin-like PCBs
Annex G (informative) - Measurement of hexachlorobenzene
        (HCB)
Annex H (informative) - Significant technical changes
Annex ZA (informative) - Relationship between this
         European Standard and the essential requirements
         of EU Directives
Bibliography

This European Standard specifies sampling from stationary sources, extraction, clean-up, identification and quantification procedures of the dioxin-like PCBs. The procedure described lays down requirements to measure the PCB congeners given in Annex A (see Table A.1). It is applicable to the 12 non- and mono-ortho PCB designated by the WHO. It is optimised to measure PCB concentrations of about 0,01 ng WHO-TEQPCB/m3. In addition to the 12 non- and mono-ortho-PCB the present document is also applicable to measure further PCB-congeners like the "marker PCB" 28, 52, 101, 138, 153, 180 (see Annex F).This document specifies a framework of quality control requirements which should be fulfilled by any PCB sampling, extraction, clean-up, identification and quantification methods to be applied. As a result of their similar chemical behaviour PCBs, as shown in the validation campaign, can be sampled from stationary sources together with the PCDDs/PCDFs. Therefore, it is possible to measure PCBs together with PCDDs/PCDFs by applying EN 1948-1, -2, -3 and -4. The complete sampling procedure is described in EN 1948-1. Each of the three sampling methods of EN 1948-1 can be combined with the methods described in this document to complete the measurement procedure. EN 1948-1 is an integral part of the complete measurement procedure and is necessary for the determination of PCBs. The analyses of the following PCB congeners is described in this European Standard and is validated in the validation campaign:a)Non-ortho substituted PCBs1)3,3’,4,4’-TeCB(77)2)3,4,4’,5-TeCB (81)3)3,3’,4,4’,5-PeCB (126)4)3,3’,4,4’,5,5’-HxCB (169)b)Mono-ortho substituted PCBs1)2,3,3’,4,4’-PeCB (105)2)2,3,4,4’,5-PeCB (114)3)2,3’,4,4’,5-PeCB (118)4)2’,3,4,4’,5-PeCB (123)5)2,3,3’,4,4’,5-HxCB (156)6)2,3,3’,4,4’,5’-HxCB (157)7)2,3’,4,4’,5,5’-HxCB (167)8)2,3,3’,4,4’,5,5’-HpCB (189)c)Marker PCBs1)2,4,4'- TriCB (28)2)2,2',5,5'-TeCB (52)3)2,2',4,5,5'- PeCB

Committee
CEN/TC 264
DevelopmentNote
Supersedes CEN/TS 1948-4. (10/2010) Supersedes PREN 1948-4. (04/2011) 2010 Edition Re-Issued in December 2013 & incorporates AMD 1 2013. (01/2014)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Current
Supersedes

PD CEN/TS 1948-5:2015 Stationary source emissions. Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs Long-term sampling of PCDDs/PCDFs and PCBs
CEN/TS 1948-5:2015 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 5: Long-term sampling of PCDDs/PCDFs and PCBs
VDI 3890:2016-03 Emission control - Pet cremation facilities
VDI 3476 Blatt 1:2015-06 Waste gas cleaning - Methods of catalytic waste gas cleaning - Fundamentals
VDI 2578:2017-05 Emission control - Glassworks
VDI 2102 Blatt 2:2013-04 Emission control - Copper and copper alloy melting plants
07/30146333 DC : 0 BS ISO 16000-14 - INDOOR AIR - PART 14: DETERMINATION OF TOTAL (GAS AND PARTICLE-PHASE) POLYCHLORINATED DIOXIN-LIKE BIPHENYLS (PCBS) AND POLYCHLORINATED DIBENZO-P-DIOXINS/DIBENZOFURANS (PCDDS/PCDFS) - EXTRACTION, CLEAN-UP AND ANALYSIS BY HIGH-RESOLUTION GAS CHROMATOGRAPHY/MASS SPECTROMETRY
S.R. CEN/TS 1948-5:2015 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF PCDDS/PCDFS AND DIOXIN-LIKE PCBS - PART 5: LONG-TERM SAMPLING OF PCDDS/PCDFS AND PCBS

ISO 4793:1980 Laboratory sintered (fritted) filters — Porosity grading, classification and designation
EN 12766-1:2000 Petroleum products and used oils - Determination of PCBs and related products - Part 1: Separation and determination of selected PCB congeners by gas chromatography (GC) using an electron capture detector (ECD)
VDI 2310 Blatt 32:1995-11 Maximum immission values - Maximum immission values for PCBs to protect farm animals
EN 1948-2:2006 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 2: Extraction and clean-up of PCDDs/PCDFs
EN ISO 9169:2006 Air quality - Definition and determination of performance characteristics of an automatic measuring system (ISO 9169:2006)
EN ISO 16000-12:2008 Indoor air - Part 12: Sampling strategy for polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polycyclic aromatic hydrocarbons (PAHs) (ISO 16000-12:2008)
EN 13284-1:2017 Stationary source emissions - Determination of low range mass concentration of dust - Part 1: Manual gravimetric method
EN 1948-1:2006 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 1: Sampling of PCDDs/PCDFs
EN 1948-3:2006 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 3: Identification and quantification of PCDDs/PCDFs
EN 12766-2:2001 Petroleum products and used oils - Determination of PCBs and related products - Part 2: Calculation of polychlorinated biphenyl (PCB) content
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
ISO 16000-12:2008 Indoor air Part 12: Sampling strategy for polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polycyclic aromatic hydrocarbons (PAHs)
ISO 9169:2006 Air quality Definition and determination of performance characteristics of an automatic measuring system

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